全文获取类型
收费全文 | 871篇 |
免费 | 14篇 |
国内免费 | 2篇 |
专业分类
化学 | 641篇 |
晶体学 | 6篇 |
力学 | 9篇 |
数学 | 67篇 |
物理学 | 164篇 |
出版年
2023年 | 10篇 |
2022年 | 10篇 |
2021年 | 11篇 |
2020年 | 9篇 |
2019年 | 17篇 |
2018年 | 10篇 |
2017年 | 9篇 |
2016年 | 13篇 |
2015年 | 20篇 |
2014年 | 19篇 |
2013年 | 30篇 |
2012年 | 58篇 |
2011年 | 81篇 |
2010年 | 25篇 |
2009年 | 39篇 |
2008年 | 44篇 |
2007年 | 51篇 |
2006年 | 69篇 |
2005年 | 46篇 |
2004年 | 67篇 |
2003年 | 44篇 |
2002年 | 37篇 |
2001年 | 12篇 |
2000年 | 7篇 |
1999年 | 7篇 |
1998年 | 7篇 |
1997年 | 8篇 |
1996年 | 12篇 |
1995年 | 2篇 |
1994年 | 6篇 |
1993年 | 6篇 |
1992年 | 2篇 |
1991年 | 4篇 |
1988年 | 3篇 |
1987年 | 6篇 |
1986年 | 5篇 |
1985年 | 13篇 |
1984年 | 7篇 |
1982年 | 11篇 |
1981年 | 9篇 |
1980年 | 6篇 |
1979年 | 9篇 |
1978年 | 4篇 |
1977年 | 6篇 |
1976年 | 5篇 |
1975年 | 2篇 |
1971年 | 3篇 |
1969年 | 1篇 |
1968年 | 1篇 |
1959年 | 1篇 |
排序方式: 共有887条查询结果,搜索用时 15 毫秒
141.
Shin-ichi Matsumura 《Mathematische Annalen》2016,364(3-4):1451-1468
142.
Yuanlin Li Tianfang Zheng Yanxiang Liu Prof. Georgiy G. Levchenko Prof. Wei Han Prof. Aleksey V. Pashchenko Prof. Shin-ichi Sasaki Prof. Hitoshi Tamiaki Prof. Xiao-Feng Wang 《Chemistry (Weinheim an der Bergstrasse, Germany)》2022,28(56):e202201855
Hydrogen energy is an abundant, clean, sustainable and environmentally friendly renewable energy source. Therefore, the production of hydrogen by photocatalytically splitting water on semiconductors has been considered in recent years as a promising and sustainable strategy for converting solar energy into chemical energy to replace conventional energy sources and to solve the growing problem of environmental pollution and the global energy crisis. However, highly efficient solar-driven photocatalytic hydrogen production remains a huge challenge due to the poor visible light response of available photocatalytic materials and the low efficiency of separation and transfer of photogenerated electron-hole pairs. In the present work, organic heterojunction structures based on bacteriochlorophyll (BChl) and chlorophyll (Chl) molecules were introduced and used for solar-driven photocatalytic hydrogen production from water under visible light. Also, noble metal-free photocatalyst was successfully constructed on Ti3C2Tx nanosheets by simple successive deposition of Chl and BChl, which was used for the photocatalytic splitting water to hydrogen evolution reaction (HER). The results show that the optimal BChl@Chl@Ti3C2Tx composite has a high HER performance with 114 μmol/h/gcat, which is much higher than the BChl@Ti3C2Tx and Chl@Ti3C2Tx composites. 相似文献
143.
Low-temperature growth of ZnO epitaxial films by metal organic chemical vapor deposition 总被引:3,自引:0,他引:3
B.P.?ZhangEmail author N.T.?Binh K.?Wakatsuki N.?Usami Y.?Segawa 《Applied Physics A: Materials Science & Processing》2004,78(1):25-28
ZnO films were grown on Al2O3 (0001) substrates by metal organic chemical vapor deposition at temperatures of Tg=150300 °C. Epitaxial growth was obtained for Tg200 °C. The in-plane orientation of the ZnO unit cells was found to change from a no-twist one with respect to that of the substrate at Tg=200 °C to a 30°-twist one at Tg=300 °C. Absorption and photoluminescence were observed from the film grown at 150 °C, although there was no evidence of epitaxial growth. Films grown at Tg200 °C exhibited smoother surfaces. Moreover, all the films grown at Tg=150300 °C revealed acceptor-related emission peaks, indicating the incorporation of acceptors into the films. PACS 81.15.Gh; 78.55.Et; 78.66.Hf 相似文献
144.
Preparation and characterization of single-phase SiC nanotubes and C-SiC coaxial nanotubes 总被引:2,自引:0,他引:2
Tomitsugu Taguchi Naoki Igawa Hiroyuki Yamamoto Shin-ichi Shamoto Shiro Jitsukawa 《Physica E: Low-dimensional Systems and Nanostructures》2005,28(4):431-438
Preparation conditions of single-phase SiC nanotubes and C-SiC coaxial nanotubes were investigated. The characterization of single-phase SiC nanotubes and C-SiC coaxial nanotubes were carried out. The SiC nanowires, which were made of the catenated SiC grains of 50–200 nm in diameter, were obtained in carbon nanotubes reacted at 1450 °C. The only C-SiC coaxial nanotubes were formed at 1300 °C. A few single-phase SiC nantoubes were synthesized at 1200 °C for 100 h. More than half number of nanotubes reacted at 1200 °C for 100 h were altered to single-phase SiC nantoubes by heat treatment of 600 °C for 1 h in air since the remained carbon was removed. The energy dispersive X-ray spectroscopy analysis revealed that the atomic ratio of Si to C in single-phase SiC nanotubes was almost 1; these single-phase SiC nanotubes consisted of near-stoichiometric SiC grains. 相似文献
145.
Naofumi Nishida Yuki Hori Akane Yamauchi Hazuki Fujiwara Makoto Sakurai Yuya Fujiwara Shin-ichi Honda Shunjiro Fujii Hiroyuki A. Sakaue Daiji Kato Tomohiro Yamaguchi Koji Ishibashi Toshifumi Terui Kuei-Yi Lee 《X射线光谱测定》2020,49(1):99-103
Interaction of highly charged ions (HCIs) with surfaces produce various specific phenomena as a consequence of the potential energy that HCI possesses. In the present study, we have observed photon emission, structural, magnetic, and electronic modification on various carbon-based materials such as carbon nanotube by the impact of HCIs using an electron beam ion source named Kobe EBIS installed at the Kobe University. In order to study the potential effect, HCIs of Arq+ (q = 6–16) with the intensity of 0.1–1 nA are projected on the surface with a constant kinetic energy (16 keV). For photon emission measurements, we observed spatial and spectral distribution of visible light emission from the surface during irradiation with HCIs. On the other hand, the structural modification of multi-walled carbon nanotubes (MWCNTs) irradiated with HCIs has been analyzed using a transmission electron microscopy and Raman spectroscopy. Irradiation effects on the resistivity of single MWCNT supported on micrometer scale bridge pattern were also measured. We have also measured magnetic structure of highly oriented pyrolytic graphite irradiated with HCIs using electron spin resonance at low temperature. At the present paper, we will review our recent experimental results on the interaction of HCI with various carbon-based materials. 相似文献
146.
Dr. Kwan Yin Cheung Prof. Yasutomo Segawa Prof. Kenichiro Itami 《Chemistry (Weinheim an der Bergstrasse, Germany)》2020,26(65):14791-14801
The development of carbon nanobelts and related belt-shaped polycyclic aromatic hydrocarbons has gained momentum in recent years. This Minireview focuses on the synthetic strategies used in constructing these aesthetically appealing molecular nanocarbons. Examples of carbon nanobelts and related belt-shaped polycyclic aromatic hydrocarbons reported in recent years as well as some representative synthetic attempts in earlier times are discussed. 相似文献
147.
Shin-ichi Hirashima 《Tetrahedron letters》2009,50(30):4328-543
Carbon tetrabromide enables us to carry out oxidative cleavage of the C-C double bonds of styrenes under aerobic photo-irradiation conditions. Oxidative cleavage of the various β-substituted styrenes produced benzoic acid in good yields. Since this reaction is found to be applicable to the α- or β-substituted styrenes, which showed very low reactivity under our previous cleavage reaction condition with FSM-16 and I2, this reaction can be used complementarily. 相似文献
148.
Anion recognition by 1,3-disiloxane-1,1,3,3-tetraols has been elucidated by 1H NMR titrations and ESI-MS in organic solvents. The association constants of the receptors for halide anions are larger than those of silanediol and 1,3-disiloxane-1,3-diol due to the cooperative hydrogen bonds by four silanol hydroxy groups of 1,3-disiloxane-1,1,3,3-tetraols. 相似文献
149.
150.
Yoshihiko Nishimori Katsuhiko Kanaizuka Dr. Tomochika Kurita Toshiaki Nagatsu Yu Segawa Fumiyuki Toshimitsu Satoshi Muratsugu Dr. Mitsuya Utsuno Dr. Shoko Kume Dr. Masaki Murata Dr. Hiroshi Nishihara Prof. 《化学:亚洲杂志》2009,4(8):1361-1367
Electronic conductivity of molecular wires is a critical fundamental issue in molecular electronics. π‐Conjugated redox molecular wires with the superior long‐range electron‐transport ability could be constructed on a gold surface through the stepwise ligand–metal coordination method. The βd value, indicating the degree of decrease in the electron‐transfer rate constant with distance along the molecular wire between the electrode and the redox active species at the terminal of the wire, were 0.008–0.07 Å?1 and 0.002–0.004 Å?1 for molecular wires of bis(terpyridine)iron and bis(terpyridine)cobalt complex oligomers, respectively. The influences on βd by the chemical structure of molecular wires and the terminal redox units, temperature, electric field, and electrolyte concentration were clarified. The results indicate that facile sequential electron hopping between neighboring metal–complex units within the wire is responsible for the high electron‐transport ability. 相似文献