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排序方式: 共有698条查询结果,搜索用时 31 毫秒
691.
Kiyoshi Ogura Kiyohiko Itoh Shin-Ichi Isogai Shuji Kondo Kazuichi Tsuda 《高分子科学杂志,A辑:纯化学与应用化学》2013,50(9):1371-1381
Methyl-4-vinylphenylsulfoxide (1) was prepared by the selective oxidation of 4-methylthiostyrene with sodium metaperiodate in 87% yield. This monomer was readily homopolymerized in DMSO by AIBN at 60°C. The polymer obtained is soluble in ethanol, chloroform, DMSO, and DMF, but insoluble in water, benzene, and petroleum ether. The inherent viscosity of this polymer was 0.33 dL/g in DMSO. This sulfoxide monomer (1) was copolymerized with styrene, methyl methacrylate, acrylo-nitrile, and acrylamide under radical conditions. From the copolymerization with styrene, copolymerization parameters were obtained as follows; r1 = 0.56, rSt, = 0.26, and Q1 = 1.19, e1 = 0.58. Similarly, methyl-4-vinylbenzylsulfoxide (2) was prepared, and the polymerizability of (2) was also investigated. 相似文献
692.
Liliana Esquivel Nakao Hayashi Elena I. Kaikina 《Journal of Differential Equations》2019,266(2-3):1121-1152
We consider the inhomogeneous Dirichlet-boundary value problem for the cubic nonlinear Schrödinger equations on the half line. We present sufficient conditions of initial and boundary data which ensure asymptotic behavior of small solutions to equations by using the classical energy method and factorization techniques 相似文献
693.
9,10-Phenanthrenequinone (PQ) is harmful environmental pollutant that is detected in airborne particulates. The measurement of PQ in the air should be necessary to evaluate the potential adverse effects of PQ on human health. We have recently developed a determination method for PQ based on the fluorescence derivatization of PQ using benzaldehyde and ammonium acetate as a reagent. In this study, in order to obtain more sensitive and selective fluorescence derivatization reaction, we measured the fluorescence of the reaction mixture of PQ with 21 kinds of aromatic aldehydes in the presence of ammonium acetate. Among the tested aldehydes, 4-carbomethoxybenzaldehyde was found to be the best reagent in regard to fluorescence intensity and emission wavelength maximum. Based on the fluorescence derivatization with 4-carbomethoxybenzaldehyde, a highly sensitive chromatographic method was developed for the determination of PQ with the detection limit (S/N=3) of 1.2 fmol/injection. 相似文献
694.
Iwabuchi M Nakao M Adachi I Arinstein K Aulchenko V Aushev T Bakich AM Balagura V Barberio E Bay A Belous K Bhardwaj V Bitenc U Bozek A Bracko M Browder TE Chen A Chen WT Cheon BG Cho IS Choi Y Dalseno J Dash M Drutskoy A Eidelman S Fujikawa M Gabyshev N Ha H Haba J Hayasaka K Hazumi M Heffernan D Horii Y Hoshi Y Hou WS Hyun HJ Inami K Ishikawa A Ishino H Itoh R Iwasaki M Kah DH Kaji H Kang JH Kawai H Kawasaki T Kichimi H Kim HJ Kim HO Kim YI Kim YJ Kinoshita K Korpar S Krizan P Krokovny P 《Physical review letters》2008,101(4):041601
We report on a search for the doubly Cabibbo suppressed decay B+-->D*+pi0, based on a data sample of 657x10(6) BB pairs collected at the Upsilon(4S) resonance with the Belle detector at the KEKB asymmetric-energy e+e- collider. We find no significant signal and set an upper limit of B(B+-->D*+pi0)<3.6x10(-6) at the 90% confidence level. This limit can be used to constrain the ratio between suppressed and favored B-->D*pi decay amplitudes, r<0.051, at the 90% confidence level. 相似文献
695.
Yoshiaki Kokubo Itsuki Igarashi Kenichi Nakao Wataru Hachiya Shinichi Kugimiya Tomohiro Ozawa Hideki Masuda Yuji Kajita 《Molecules (Basel, Switzerland)》2022,27(18)
The reactions of newly designed lithiated triamidoamines Li3LR (R = iPr, Pen, and Cy2) with VCl3(THF)3 under N2 yielded dinitrogen–divanadium complexes with a μ-N2 between vanadium atoms [{V(LR)}2(μ-N2)] (R = iPr (1) and Pen (2)) for the former two, while not dinitrogen–divanadium complexes but a mononuclear vanadium complex with a vacant site, [V(LCy2)] (R = Cy2 (3)), were obtained for the third ligand. The V–NN2 and N–N distances were 1.7655(18) and 1.219(4) Å for 1 and 1.7935(14) and 1.226(3) Å for 2, respectively. The ν(14N–14N) stretching vibrations of 1 and 2, as measured using resonance Raman spectroscopy, were detected at 1436 and 1412 cm–1, respectively. Complex 3 reacted with potassium metal in the presence of 18-crown-6-ether under N2 to give a hetero-dinuclear vanadium complex with μ-N2 between vanadium and potassium, [VK(LCy2)(μ-N2)(18-crown-6)] (4). The N–N distance and ν(14N–14N) stretching for 4 were 1.152(3) Å and 1818 cm−1, respectively, suggesting that 4 is more activated than complexes 1 and 2. The complexes 1, 2, 3, and 4 reacted with HOTf and K[C10H8] to give NH3 and N2H4. The yields of NH3 and N2H4 (per V atom) were 47 and 11% for 1, 38 and 16% for 2, 77 and 7% for 3, and 80 and 5% for 4, respectively, and 3 and 4, which have a ligand LCy2, showed higher reactivity than 1 and 2. 相似文献
696.
Naoya Ieda Masato Sawada Runa Oguchi Masato Itoh Seina Hirakata Daisuke Saitoh Akito Nakao Mitsuyasu Kawaguchi Prof. Kazunobu Sawamoto Prof. Toshitada Yoshihara Prof. Yasuo Mori Prof. Hidehiko Nakagawa 《Angewandte Chemie (International ed. in English)》2023,62(20):e202217585
We present an optochemical O2 scavenging system that enables precise spatiotemporal control of the level of hypoxia in living cells simply by adjusting the light intensity in the illuminated region. The system employs rhodamine containing a selenium or tellurium atom as an optochemical oxygen scavenger that rapidly consumes O2 by photochemical reaction with glutathione as a coreductant upon visible light irradiation (560–590 nm) and has a rapid response time, within a few minutes. The glutathione-consuming quantum yields of the system were calculated as about 5 %. The spatiotemporal O2 consuming in cultured cells was visualized with a hypoxia-responsive fluorescence probe, MAR. Phosphorescence lifetime imaging was applied to confirmed that different light intensities could generate different levels of hypoxia. To illustrate the potential utility of this system for hypoxia research, we show that it can spatiotemporally control calcium ion (Ca2+) influx into HEK293T cells expressing the hypoxia-responsive Ca2+ channel TRPA1. 相似文献
697.
Dr. Yusuke Kuroda Dr. Kyungho Park Yuto Shimazaki Dr. Rong-Lin Zhong Prof. Dr. Shigeyoshi Sakaki Prof. Dr. Yoshiaki Nakao 《Angewandte Chemie (International ed. in English)》2023,62(23):e202300704
Despite the widespread success in the functionalization of C(sp2)−H bonds, the deliberate functionalization of C(sp3)−H bonds in a highly site- and stereoselective manner remains a longstanding challenge. Herein, we report an iridium/aluminum cooperative catalytic system that enables the β-selective C−H borylation of saturated cyclic amines and lactams. Furthermore, we have accomplished an enantioselective variant using binaphthol-derived chiral aluminum catalysts to forge C−B bonds with high levels of stereocontrol. Computational studies suggest that the formation of a Lewis pair with the substrates is crucial to lower the energy of the transition state for the rate-determining reductive elimination step. 相似文献
698.
The relation between stereoregularity of active centers on a MgCl2/TiCl4 catalyst and functions of inside donor (ID) and outside donor (OD) was investigated in the case of ethyl benzoate (EB)/methyl p-toluate (MPT) as an ID/OD pair. The results indicate that stereregularity depends merely on the amount of MPT supported on the catalyst. On the other hand, regioregularity of active centers was investigated with a MgCl2/TiCl4/dioctyl phthalate(DOP)-Et3Al/diphenyldimethoxysilane(DPDMS) catalyst system. Regio-irregular inserted units were detected only in end groups of PP. It indicates that regio-irregular insertion leads to dormant centers with respect to propene insertion, though such centers are active for hydrogen transfer. 相似文献