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61.
Hyun Chul Choi Min Kyu Lee Hyun Joon Shin Seung Bin Kim 《Journal of Electron Spectroscopy and Related Phenomena》2003,130(1-3):85-96
To investigate the formation of a solid electrolyte interface (SEI) on the Li1+xV3O8 electrode surface in the thermodynamic stability range of the organic electrolyte, we applied scanning photoelectron microscopy (SPEM) to a pristine electrode and to an electrode after ten cycles. The F K-edge absorption spectrum of the cycled electrode showed that LiF forms on the electrode surface during the lithium insertion–extraction process in the Li1+xV3O8/Li cell. The photoelectron spectrum for the cycled electrode showed intense spectral features corresponding to Li 1s, F 2s, F 2p, and P 2p electron signals, whereas these spectral features were of negligible intensity for the pristine electrode. The above results give strong support for the formation of an SEI that consists of LiF and compounds containing phosphorus during operation of the battery. The SPEM images also revealed that the fluorine distribution on the surface of the cycled electrode was inhomogeneous. 相似文献
62.
The structure of the title adduct comprises a phenanthroline derivative 2-phenyl-imidazo[4,5-f]1,10-phenanthroline and a methanol.The composition of the crystalline adduct was characterized as C19H12N4.CH3OH.It belongs to orthorhombic system,space group Pna21 with a=1.3693(4)nm,b=2.2988(7)nm,c=0.51338(15)nm,V=1.6160(8)nm^3.Z=4,and final R1=0.0423.wR2=0.1012 .Crystal structure shows that all the 19 carbon atoms and 4 nitrogen atoms are coplanar.The bond length data indicated that a very extensive conjugation system was formed.This conjugation makes the compound being a potentially excellent energy transformer used for luminescent materials. 相似文献
63.
Discrete global descent method for discrete global optimization and nonlinear integer programming 总被引:2,自引:0,他引:2
A novel method, entitled the discrete global descent method, is developed in this paper to solve discrete global optimization
problems and nonlinear integer programming problems. This method moves from one discrete minimizer of the objective function
f to another better one at each iteration with the help of an auxiliary function, entitled the discrete global descent function.
The discrete global descent function guarantees that its discrete minimizers coincide with the better discrete minimizers
of f under some standard assumptions. This property also ensures that a better discrete minimizer of f can be found by some classical local search methods. Numerical experiments on several test problems with up to 100 integer
variables and up to 1.38 × 10104 feasible points have demonstrated the applicability and efficiency of the proposed method. 相似文献
64.
李辉 《宁波大学学报(理工版)》1995,(1)
本文对低叠合面钢筋破简支在合梁二阶段受力的斜截面抗剪性能进行了试验研究,并运用非线性有限元分析和试验实测数据,得出了一个适合于集中荷载下高低叠合面叠合梁的抗剪强度计算公式. 相似文献
65.
复Finsler流形上的Koppelman-Leray-Norguet公式 总被引:1,自引:1,他引:0
利用不变积分核(Berndtsson核),复Finsler度量和联系于Chern-Finsler联络的非线性联络,研究复Finsler流形上具有逐块光滑C~((1))边界的有界域上(p,q)型微分形式的积分表示,得到了(p,q)型微分形式的Koppelman-Leray-Norguet公式和■-方程的解.作为应用,利用复Finsler度量和联系于Chern-Finsler联络的非线性联络,给出了Stein流形上具有逐块光滑C~((1))边界的有界域上(p,q)型微分形式的Koppelman- Leray-Norguet公式以及■-方程的解,并且得到了Stein流形上实非退化强拟凸多面体上(p,q)型微分形式的积分表示式和■-方程的解. 相似文献
66.
本文对星载光学系统遮光罩消杂光结构的优化设计做了初步探讨。提出了遮光罩和挡光环消杂光设计的基本原则。给出了一种二级遮光罩结构寸的优化设计方法和一种遮光罩内壁上挡光环位置优化设计方法,并对一级和二级遮光罩进行了初步的分析比较。 相似文献
67.
本应用自己合成的联萘20-冠-6作为活性载体,进行了五羟色胺分子选择性电极研究。电极在10^-^5-10^-^2mol/L浓度范围内对五羟色胺具有稳定的线性响应,平均斜率为63mV/PC,检测下限为2.7×10^-^6mol/L。 相似文献
68.
字节全加器及其在无线电测控系统中的应用 总被引:1,自引:1,他引:0
对全加器概念进行了推广,并在此基础上给出了使用字节全加器网络的无线电抗干扰算法。通过在实际的无线电测控系统中的应用,结果表明该算法具有良好的无线电抗干扰效果。 相似文献
69.
Shin Ichi Aihara 《Acta Appl Math》1994,35(1-2):131-151
The purpose of this paper is to study the identification problem of a spatially varying discontinuous parameter in stochastic hyperbolic equations. In previous works, the consistency property of the maximum likelihood estimate (MLE) was explored and the generating algorithm for MLE proposed under the condition that an unknown parameter is in a sufficiently regular space with respect to spatial variables.In order to show the consistency property of the MLE for a discontinuous coefficient, we use the method of sieves, i.e. the admissible class of unknown parameters is projected into a finite-dimensional space. For hyperbolic systems, we cannot obtain a regularity property of the solution with respect to a parameter. So in this paper, the parabolic regularization technique is used. The convergence of the derived finite-dimensional MLE to the infinite-dimensional MLE is justified under some conditions. 相似文献
70.
The purpose of the present study was to describe the effects ofacute laryngitis on some aerodynamic, acoustic, and perceptual measures. Eleven subjects with diagnosed acute laryngitis due to upper respiratory infection were recorded during a laryngitic episode and 1 week to 10 days after amelioration of the laryngitic condition. Fundamental frequency values, collapsed across the five vowels, were significantly reduced in the laryngitic compared with the normal speaking condition. The decrease in fundamental frequency associated with acute laryngitis suggests an increase in the mass of the vocal folds. In addition, aerodynamic values differed significantly for the laryngitic condition compared with the normal speaking condition, suggesting the presence of laryngeal hypofunction. Perceptual data indicated that speakers in the laryngitic condition were judged to have a hoarse voice when compared with the normal speaking condition. 相似文献