钶铁矿型MnNb2O6的熔盐法合成、钒掺杂与磁性研究

采用了熔盐法新工艺制备了纯相与掺钒的MnNb₂O₆粉晶,利用X射线衍射仪(XRD),扫描电子显微镜(SEM),能谱分析(EDX),透射电子显微镜(TEM)、高分辨透射电镜(HRTEM)和电子衍射(SAED)分析了其物相、形貌及微结构.结果表明合成产物为正交晶系钶铁矿型MnNb₂O₆;在不同的熔盐中合成出了棒状、片状与长方体形貌的纯相产物.讨论了温度与掺杂对结构与形貌的影响,HRTEM与SAED分析表明了产物的各向异性生 关键词： 熔盐法 结构与形貌 掺杂 反铁磁性     

受扰统一混沌系统基于RBF网络的主动滑模控制

针对受外扰影响的统一混沌系统,提出一种基于径向基函数(RBF)神经网络的主动滑模自适应控制方法.将被控系统分解为受控子系统和自由子系统,利用主动控制思想,建立受控子系统在目标点处的状态误差的可控标准型,设计出一个结构简单的基于滑模趋近率在线参数整定的RBF函数神经网络控制器,并且基于Lyapunov稳定性理论分析了系统的稳定性.仿真结果表明该控制器对系统参数突变和外部干扰具有鲁棒性,同时抑制了抖振. 关键词： 统一混沌系统 主动控制 滑模控制 RBF网络     

Fe离子注入ZnO生成超顺磁纳米颗粒

过渡族元素掺杂ZnO生成稀磁半导体, 成为近期国际材料科学研究的热点. 在本文中, 研究Fe离子注入ZnO单晶的结构和磁性变化, 目标是建立磁性和结构的对应关系, 澄清铁磁性的来源. 采用卢瑟福背散射/沟道技术 (RBS/Channelling)、同步辐射X射线衍射 (SR-XRD)和超导量子干涉仪 (SQUID), 研究注入温度和退火对样品的晶格损伤、结构及磁性的影响. 研究表明: 样品注入区损伤随注入温度升高而降低; 低温253 K注入样品中, SR-XRD未检测到新相, Fe离子分布于Zn位, ZnO (0002) 峰右侧肩峰可能属于Zn_1-xFe_xO, 5 K下测试样品不具有铁磁性; 623 K注入和823 K真空退火 (253 K注入) 样品中形成α和γ相金属Fe, 5 K下样品具有明显的剩磁和矫顽力, 零场冷却和场冷却 (ZFC/FC) 曲线和300 K下的磁滞回线显示纳米Fe颗粒具有超顺磁性. Fe离子注入ZnO的磁性源于第二相α-Fe和γ-Fe. 关键词： 离子注入 ZnO 同步辐射X射线衍射 超顺磁性     

中子探测晶体Li6Gd(BO3)3:Ce的光谱特性研究

文章用提拉法生长出Li₆Gd(BO₃)₃:Ce晶体,并对其光谱性能与发光过程进行了探索. 借助于真空紫外-紫外透过光谱测试,发现晶体的透过光谱中存在Ce³⁺离子和Gd³⁺的特征吸收峰,同时还存在与Ce⁴⁺离子相关的电荷迁移带. 对晶体的真空紫外-紫外激发发射光谱进行研究发现,在晶体存在着Ce³⁺离子的5d→4f辐射跃迁发光与Gd³⁺离子的4f→4f辐射跃迁发光,而且存在着Gd³⁺→Ce³⁺之间的能量传递. 对Li₆Gd(BO₃)₃:Ce晶体的X射线与γ射线激发发射光谱研究可知,晶体在高能射线激发下的闪烁光主要是Ce³⁺离子的发光. 关键词： 6Gd(BO₃)₃:Ce晶体')" href="#">Li₆Gd(BO₃)₃:Ce晶体 真空紫外-紫外透过光谱 真空紫外-紫外激发发射光谱 能量传递     

Structural and optical properties of porous iron oxide

The structural and optical properties of the novel porous iron oxide fabricated by wood template have been investigated. The obtained porous iron oxide was characterized to be α- Fe₂O₃ by Fourier transform infrared and Raman spectroscopy. X-ray absorption fine structure measurement revealed that the bond length of Fe-O₁ of the porous iron oxide has good agreement with that reported for the α- Fe₂O₃ crystal structure while the bond lengths for Fe-O₂ and Fe-Fe deviate slightly from those of the α- Fe₂O₃ crystal structure. Photoluminescence from the porous iron oxide exhibited broad emission bands around 760 and 890 nm, which are believed to be due to the unique nanoscale structure of the porous iron oxide.     

Film thickness dependence of electro-optic effect in epitaxial BaTiO3 thin films

Based on the phenomenological Landau-Devonshire theory, we investigate the film thickness dependence of ferroelectric and electro-optic properties of epitaxial BaTiO₃ thin films grown on SrTiO₃ and MgO substrates. By using the effective substrate lattice parameter concept, the film thickness dependence of misfit strain is incorporated into the theory. Therefore, the film thickness dependence of ferroelectric and electro-optic properties in epitaxial BaTiO₃ thin films can be explained. Moreover, a large quadratic electro-optic effect was obtained in the BaTiO₃ thin films, which is in good agreement with the experimental result of BaTiO₃ thin films on the MgO substrate.     

Examining surface and bulk structures using combined nonlinear vibrational spectroscopies

We combined sum-frequency generation (SFG) vibrational spectroscopy with coherent anti-Stokes Raman scattering (CARS) spectroscopy in one system to examine both surface and bulk structures of materials with the same geometry and without the need to move the sample. Poly(methyl methacrylate) (PMMA) and polystyrene (PS) thin films were tested before and after plasma treatment. The sensitivities of SFG and CARS were tested by varying polymer film thickness and using a lipid monolayer.     

Higher-order cross-correlation-based Doppler optical coherence tomography

A method based on higher-order cross-correlation is proposed to fetch the Doppler information on flow velocity within areas under low signal-to-noise ratio (SNR) by spectral domain optical coherence tomography. The proposed method is theoretically developed and validated by measurement of a moving mirror with known velocities. Standard deviations of flow velocities of the mirror under different SNRs are determined by the proposed method and compared with those by the modified phase-resolved method. Measurement of flowing particles within a glass capillary is also conducted, and Doppler flow velocity maps of the glass capillary are reconstructed by both methods. All experimental results demonstrate that the proposed method can significantly suppress noise, thus rendering it suitable for flow measurement under low SNR cases.     

Dissipative soliton resonance in a passively mode-locked fiber laser

The phenomenon of dissipative soliton resonance (DSR) predicts that an increase of pulse energy by orders of magnitude can be obtained in laser oscillators. Here, we prove that DSR is achievable in a realistic ring laser cavity using nonlinear polarization evolution as the mode-locking mechanism, whose nonlinear transmission function is adjusted through a set of waveplates and a passive polarizer. The governing model accounts explicitly for the arbitrary orientations of the waveplates and the polarizer, as well as the gain saturation in the amplifying medium. It is shown that DSR is achievable with realistic laser settings. Our findings provide an excellent design tool for optimizing the mode-locking performance and the enhancement of energy delivered per pulse by orders of magnitude.     

Dielectric shielded nanoscale patch laser resonators

Dielectric shielded nanoscale patch laser resonators are introduced. Low-index dielectric shield layers surrounding a high-index core are shown to significantly reduce both metal and radiation losses. Structures suitable for both optical and electrical pumping and smaller than the vacuum wavelength in all three dimensions are shown to have a low enough threshold gain to lase at room temperature. Shifting the gain medium core provides control over the radiation pattern of the resonator and enables coupling of the laser light into a waveguide, opening opportunities for chipscale integration.