首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   9137篇
  免费   1672篇
  国内免费   940篇
化学   6038篇
晶体学   93篇
力学   749篇
综合类   66篇
数学   1146篇
物理学   3657篇
  2024年   38篇
  2023年   184篇
  2022年   312篇
  2021年   350篇
  2020年   353篇
  2019年   327篇
  2018年   298篇
  2017年   296篇
  2016年   436篇
  2015年   427篇
  2014年   469篇
  2013年   660篇
  2012年   767篇
  2011年   841篇
  2010年   567篇
  2009年   542篇
  2008年   618篇
  2007年   484篇
  2006年   525篇
  2005年   387篇
  2004年   319篇
  2003年   257篇
  2002年   237篇
  2001年   209篇
  2000年   197篇
  1999年   196篇
  1998年   189篇
  1997年   179篇
  1996年   180篇
  1995年   145篇
  1994年   131篇
  1993年   117篇
  1992年   94篇
  1991年   71篇
  1990年   80篇
  1989年   65篇
  1988年   44篇
  1987年   37篇
  1986年   35篇
  1985年   23篇
  1984年   18篇
  1983年   14篇
  1982年   15篇
  1981年   3篇
  1980年   7篇
  1979年   3篇
  1975年   1篇
  1957年   2篇
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
171.
Inappropriate development and overexploitation have seriously degraded aquatic resources in China. Stakeholders identified three fish stock enhancement and biodiversity conservation scenarios for the Beijiang River: S1, increased fish restocking; S2, no fishing season and habitat conservation; and S3, strict pollution control. Potential impacts of these actions on the livelihoods of fishers were evaluated using applied economic modeling. Baseline costs and benefits came from logbooks from 30 fishers and a survey of 90 households in three villages. The financial net benefit for a household was US$1583 (¥11,160) annually, representing a 142% and 387% return on capital and operating costs, respectively. Larger catches associated with S1 and S2 generated a net benefit of US$1651 and US$1822, respectively. Strict pollution control resulting in higher catches (+20%) and lower operating costs (?20%) would increase the net benefit by 15.9% to US$1835 annually. Pollution control would benefit other resource users and is a prerequisite for ecological restoration. Recommendations for Resource Managers
  • Stringent pollution control measures are essential to conserve aquatic biodiversity and enhance the livelihoods of fishers but will require considerable public and private sector investment.
  • Enhanced fish stocks in the Beijiang River could benefit poor livelihoods but may not be sufficient to lift households out of poverty, aged fishers require government assistance to diversify their livelihoods, access alternative urban employment, and survive with dignity.
  • Adopting the economic modeling approach presented here could enable responsible authorities to simultaneously evaluate fish stock enhancement and biodiversity conservation options.
  • Broader application of the approach presented here could help ensure small‐scale inland fisheries are managed sustainably and aquatic ecosystems are restored and protected by 2020, in line with Target 6 of the United Nations’ Convention on Biological Diversity Strategic Plan for Biodiversity.
  相似文献   
172.
Given a planar continuum Gaussian free field h𝒰 in a domain 𝒰 with Dirichlet boundary condition and any δ > 0, we let be a real-valued smooth Gaussian process where is the average of h𝒰 along a circle of radius δ with center v. For γ > 0, we study the Liouville first-passage percolation (in scale δ), i.e., the shortest path distance in 𝒰 where the weight of each path P is given by . We show that the distance between two typical points is for all sufficiently small but fixed γ > 0 and some constant c* > 0. In addition, we obtain similar upper bounds on the Liouville first-passage percolation for discrete Gaussian free fields, as well as the Liouville graph distance, which roughly speaking is the minimal number of euclidean balls with comparable Liouville quantum gravity measure whose union contains a continuous path between two endpoints. Our results contradict some reasonable interpretations of Watabiki's prediction (1993) on the random distance of Liouville quantum gravity at high temperatures.© 2019 Wiley Periodicals, Inc.  相似文献   
173.
Heusler phases, including the full‐ and half‐Heusler families, represent an outstanding class of multifunctional materials on account of their great tunability in compositions, valence electron counts (VEC), and properties. Here we demonstrate a systematic design of a series of new compounds with a 2×2×2 superstructure of the half‐Heusler unit cell in X–Y–Z (X=Fe, Ru, Co, Rh, Ir; Y=Zn, Mn; Z=Sn, Sb) systems. Their structures were solved by using both powder and single‐crystal X‐ray diffraction, and also directly observed by using high‐angle annular dark‐field imaging in a scanning transmission electron microscope (HAADF‐STEM). The VEC values of these new compounds span a wide and continuous range comparable to those for the full‐ and half‐Heusler families, thereby implying tunability in compositions and physical properties in the superstructure. In fact, we observed abnormal electrical properties and a ferromagnetic semiconductor‐like behavior with a high and tunable Curie temperature in these superstructures.  相似文献   
174.
The present paper investigates the convergence of the Galerkin method for the dynamic response of an elastic beam resting on a nonlinear foundation with viscous damping subjected to a moving concentrated load. It also studies the effect of different boundary conditions and span length on the convergence and dynamic response. A train–track or vehicle–pavement system is modeled as a force moving along a finite length Euler–Bernoulli beam on a nonlinear foundation. Nonlinear foundation is assumed to be cubic. The Galerkin method is utilized in order to discretize the nonlinear partial differential governing equation of the forced vibration. The dynamic response of the beam is obtained via the fourth-order Runge–Kutta method. Three types of the conventional boundary conditions are investigated. The railway tracks on stiff soil foundation running the train and the asphalt pavement on soft soil foundation moving the vehicle are treated as examples. The dependence of the convergence of the Galerkin method on boundary conditions, span length and other system parameters are studied.  相似文献   
175.
Two new diterpenoids, loxocalyxin A ( 1 ) and 13‐epiloxocalyxin A ( 2 ), and two new sesquiterpenoids, loxocalyxins B and C ( 3 and 4 , resp.), together with three known compounds, were isolated from the MeOH extract of the whole plant of Loxocalyx urticifolius Hemsl . The structures of the new compounds were established by means of spectroscopic analysis including one‐ and two‐dimensional NMR spectroscopy. All new structures were confirmed by X‐ray crystallographic analysis. Their absolute configurations were established.  相似文献   
176.
177.
Brewster’s angle method was adopted to measure the absorption coefficient of a set of high-resistivity germanium samples at 2.52 THz in this paper. Numerical simulations were firstly carried out to evaluate the errors during measurement. The experimental setup was improved, and measurement was carried out based on a CW THz laser at 2.52 THz.  相似文献   
178.
Pomponlike La2(MoO4)3 microstructures assembled with single-crystalline nanoflakes have been facilely fabricated via a surfactant-assisted ultrasound route for the first time. Various synthesis conditions were examined, such as the surfactant concentration, the molecular structure of surfactants, and the pH value. The obtained pomponlike microstructures were characterized by X-ray diffraction (XRD), (field-emission) scanning electron microscopy [(FE)SEM], transmission electron microscopy (TEM), and nitrogen adsorption/desorption isotherms. It has been revealed that a minimum concentration of sodium dodecylsulfate (SDS) was required for the formation of pomponlike La2(MoO4)3 microstructures. When the SDS concentration is above 0.02 mol L−1, the pomponlike microstructures become more perfect, and the size is also increased with the increasing SDS concentration. Under the same sonication, similar pomponlike microstructures were obtained when a cationic surfactant, cetyltrimethyl ammonium bromide (CTAB), was used instead of the anionic surfactant SDS, indicating that the hydrophobic alkyl chains are an important factor for the formation of the pomponlike La2(MoO4)3 microstructures. It is also found that the pomponlike La2(MoO4)3 microstructures can only be obtained within an optimal pH range of 8.0–9.0 under sonication. Based on TEM, Fourier transform infrared spectroscopy (FT-IR) and solubilization experiment, a formation mechanism of pomponlike La2(MoO4)3 microstructures was proposed, in which the collaborative action of surfactants and sonication plays a key role. Furthermore, the porosity of the pomponlike La2(MoO4)3 microstructures were discussed.  相似文献   
179.
180.

The isothiocyanates 2, obtained from aza-Wittig reactions of vinyliminophosphoranes 1 with CS 2 , reacted with hydrazine to give 3-amino-2-thioxo-4-imidazolidinones 4. One-pot reactions of 4, aromatic isocyanates, Ph 3 P, C 2 Cl 6 , and Et 3 N generated imidazo[2,1-b]-1,3,4-thiadiazol-5(6H)-ones 7. Compound 7 exhibited good fungicidal activities, especially against Sclerotinia sclerotiorum de Bary and Botrytis Cinerea Pers.  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号