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121.
A reliable Pd-catalyzed amination protocol is described for the synthesis of N-alkyltacrines and analogs. The Josiphos ligand CyPFtBu was found to provide optimum yields: 16 examples are given. Compared to the typical high-temperature nucleophilic aromatic substitution (NAS) routes, Pd-catalyzed aminations proceed at significantly lower reaction temperatures, and enable the synthesis of otherwise inaccessible products. 相似文献
122.
Anil Kumar Sharma Abhilasha Singh R. K. Mehta Sudhanshu Sharma S. P. Bansal K. S. Gupta 《国际化学动力学杂志》2011,43(7):379-392
To understand the chemistry of Cu(II)–NH3–S(IV)–O2 system, the kinetics of the oxidation of sulfur(IV) catalyzed by amminecopper(II) complexes has been studied in the ammonia‐buffered solutions. Sulfur(IV) is oxidized to sulfate. The complexes, Cu(NH3)2+, Cu(NH3)22+, and Cu(NH3)2+3 appear to be equally reactive and Cu(NH3)42+ appears to be unreactive. The kinetics obey the rate law: where α1 and γ1 are the rate constants for O2‐dependent and O2‐independent pathways, respectively, for Cu(NH3)2+, Cu(NH3)2+2, and Cu(N H3)32+ complexes, which appear to be equally reactive. The values of α1 and γ1 were found to be (1.32 ± 0.21) × 106 L2 mol?2 s?1 (1.74 ± 0.40) × 109 L3 mol?3 s?1respectively at 30°C. The reaction rate is not influenced by the presence of ethanol—a free radical scavenger, so a nonradical mechanism has been proposed. The results of this study are useful in understanding the atmospheric chemistry of aqueous phase autoxidation of dissolved sulfur dioxide in copper(II)–ammonia–sulfur(IV)–oxygen system at high pH. © 2011 Wiley Peiodicals, Inc. Int J Chem Kinet 43: 379–392, 2011 相似文献
123.
Goverdhan Mehta Raja MohanraoSreenivas Katukojvala Yannick LandaisSaikat Sen 《Tetrahedron letters》2011,52(22):2893-2897
A stereocontrolled synthesis of nine-membered aminocarbasugar analogs (amino-cyclononanoses) from a rigid bicyclo[4.3.1]deca-2,4-dien-10-one platform, harboring a latent functionalized cyclononane ring, is described. 相似文献
124.
Monodispersed PEG-coated ZnS (P-ZnS) nanoparticles (NPs) were synthesized by facile microwave process and utilized as efficient electron mediators for the fabrication of highly sensitive hydrazine chemical sensor. The detailed morphological and structural properties revealed the monodispersity and good crystallinity for synthesized P-ZnS NPs. A high-sensitivity of ∼89.3 μA cm−2 μM and low limit of detection of 1.07 μM, based on S/N ratio, were obtained for the fabrication of hydrazine chemical sensor based on P-ZnS NPs. To the best of our knowledge, this is the first report which demonstrates the utilization of P-ZnS NPs for the fabrication of efficient hydrazine chemical sensor. By this work, it could be concluded that simply synthesized ZnS NPs can be used as efficient electron mediators for the fabrication of effective hydrazine chemical sensors. 相似文献
125.
Mehta VP Sharma Ak Modha SG Sharma S Meganathan T Parmar VS Van der Eycken E 《The Journal of organic chemistry》2011,76(8):2920-2925
The N-heterocyclic carbene catalyzed chemoselective C3-aroylation of 3,5-dichloro-2(1H)-pyrazinones with various aldehydes is reported. We herein describe results of this remarkable mild and efficient procedure. 相似文献
126.
127.
Hanane El Hajaji Nadya Lachkar Katim Alaoui Yahya Cherrah Abdellah Farah Abdesslam Ennabili Brahim El Bali Mohammed Lachkar 《Arabian Journal of Chemistry》2011,4(3):321-324
We evaluated the in vitro antioxidant property and phytochemical constituents of the crude ethyl acetate and methanol extract of the three genders of carob tree barks (spontaneous male, spontaneous female, and grafted female). The scavenging activity on DPPH (1,1-diphenyl-2-picrylhydrazyl) was determined, as well as the phenolic contents (Folin–Ciocalteu method) of both the extracts. The highest antioxidant activity and the higher amounts of total phenols were shown in methanol crude bark extract for the three genders. Variety significantly affected the phenol content and the antioxidant activity, with the spontaneous male variety globally showed a higher polyphenol concentration and antioxidant activity than the grafted female and spontaneous female. 相似文献
128.
In this paper, we have investigated Bianchi type I inflationary universe in the presence of massless scalar field with a flat
potential. To get an inflationary solution, we have considered a flat region in which potential V is constant. The inflationary scenario of the model is discussed in detail. 相似文献
129.
K. Singh S. Sihotra S. S. Malik J. Goswamy D. Mehta N. Singh R. Kumar R. P. Singh S. Muralithar E. S. Paul J. A. Sheikh C. R. Praharaj 《The European Physical Journal A - Hadrons and Nuclei》2006,27(3):321-324
The collective band structures of the 125Cs nucleus have been investigated by in-beam γ-ray spectroscopic techniques following the 110Pd ( 19F, 4n) reaction at 75MeV. The previously known level scheme, with rotational bands built on πg7/2, πg9/2 and πh11/2 orbitals, has been extended and evolves into bands involving rotationally aligned ν(h11/2)2 and π(h11/2)2 quasiparticles. A strongly coupled band has been reassigned a high-K πh11/2 ⊗ νg7/2 ⊗ νh11/2 three-quasiparticle configuration and a new side band likely to be its chiral partner has been identified. Configurations
assigned to various bands are discussed in the framework of Principal/Tilted Axis Cranking (PAC/TAC) model calculations. 相似文献
130.
Various Bishop type decompositions for vector function spaces are introduced and discussed. Conditions are given under which some of them coincide. Several examples and counter examples are also given. 相似文献