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71.
72.
Sandeep Mohanty Amrendra Kumar Roy Vinay K.P. Kumar Sandeep G. Reddy Arun Chandra Karmakar 《Tetrahedron letters》2014
We describe a simple and efficient one-pot method for condensing bisulfite adducts of aromatic aldehydes directly with 2,4-thiazolidinedione catalyzed by acetic anhydride. The two main highlights of this study are the one-pot condensation of bisulfite adducts with 2,4-thiazolidinedione in non-aqueous media and the use of Design of Experiment to understand and optimize the reaction conditions. This methodology was then generalized using other active methylene compounds, such as malononitrile. 相似文献
73.
Subhasis Mallick Biplab K. Bera Parnajyoti Karmakar Subala Mondal Arup Mandal Alak K. Ghosh 《Journal of solution chemistry》2011,40(3):532-544
The interaction of di-μ-hydroxobis(bipyridyl)dipalladium(II) with the selected bio-relevant ligands: thioglycolic acid (HL1), glutathione(HL2) and DL-penicillamine(HL3) has been studied spectrophotometrically in aqueous medium as a function of complex and ligand concentrations, pH, and temperature
at constant ionic strength. Two consecutive reaction steps are observed: the first step is dependent on the incoming ligand
concentration and the second step which is independent, is assigned to ring closure. The activation parameters, conductivity
data and IR data obtained also support the proposed mechanism. 相似文献
74.
75.
Samiran Karmakar Asoke Kumar Bhunia 《The Journal of the Operational Research Society》2014,65(1):73-87
This paper deals with an interval-oriented approach to solve general interval constrained optimization problems. Generally, this type of problems has infinitely many compromise solutions. The aim of this approach is to obtain one of such solutions with higher accuracy and lower computational cost. The proposed algorithm is nothing but a different kind of branch and bound algorithm with multi-section division criterion of the search region (or box). In the proposed technique, the prescribed/accepted region is divided into several distinct subregions and in each feasible subregion the interval objective function value is computed. Then the subregion containing the best objective value is found by applying a specific interval ranking rule defined with respect to the pessimistic decision makers’ point of view. The process is continued until the interval width for each variable in the accepted subregion is negligible. Finally, the algorithm converges to a compromise solution in interval form. To illustrate the method and also to test the efficiency as well as the effectiveness of the proposed algorithm, we have solved some numerical examples. 相似文献
76.
Shilpi Sinha Sanjula Baboota Mushir Ali Anil Kumar 《Journal of Dispersion Science and Technology》2013,34(10):1458-1473
Formulation of solid dispersion in water-soluble carriers has been widely researched over the past four decades for solubility and related bioavailability enhancement. Despite 40 years of active research, there has not been much products in market based on this technique. The main reason for this being stability and scale up problems associated with this method, as reported by several authors. Strategies used for overcoming these problems and factors affecting formation of solid dispersion such as glass transition temperature and interaction of drug with polymer have been dealt conceptually in this review. The advent of surface-active carriers such as Gelucires, Poloxamers, and lipid-based carriers has given a new dimension for the successful development of solid dispersions by combating the problems associated with stability and also giving products with enhanced dissolution rate. Therefore, the article also discusses properties of such carriers that are being unraveled lately for formulation of solid dispersion. Characterization of solid dispersion to detect the change from crystalline to amorphous states and vice versa is an important tool for its formulation and determination of stability; thus, all the methods that are available for characterizations are discussed in this article with emphasis on the principle of the technique and its application. 相似文献
77.
Anirban Karmakar 《Supramolecular chemistry》2013,25(7):667-674
Different hydrates of the receptor, N-[2-(4-methoxy-phenyl)-ethyl]-2-(quinolin-8-yloxy)acetamide (I), and its co-crystals with acetic acid and l(+)α-hydroxy-phenylacetic acid are synthesised and their structures are studied. The acids such as acetic acid, l(+)α-hydroxy-phenylacetic acid quench fluorescence of I. The receptor I shows a fluorescence quenching on interaction with perchloric acid in benzene, whereas in methanol the solution of I results in the generation of a new fluorescence emission at higher wavelengths. The crystal structure of the perchlorate salt is determined to explain the protonation behaviour of the receptor I and the perchlorate salt in methanol leads to fluorescence emission at a place different from that of the parent compound. 相似文献
78.
A previously unknown class of highly substituted benzoquinoline–spirooxindole are easily prepared by a novel application of a mild and efficient catalyst SbCl3 for carbon–carbon and carbon–nitrogen bond formation reaction involving isatin, alkyne (dialkyl but-2-ynedioate) with aromatic amine (2-naphthylamine) in a one-pot three-component reaction. This protocol of one-pot synthesis afforded a library of dialkyl 2′-oxo-4H-spiro[benzo[f]quinoline-3,3′-indoline]-1,2-dicarboxylate derivatives, a potential bioactive compound in very good to excellent yields. 相似文献
79.
The current work is a study of the conformational space of the non-ionic N-formylmethionine molecule around its seven structurally significant internal backbone torsional angles at B3LYP/6-31++G(d,p) levels of theory in the gaseous phase. The potential energy surface exploration reveals that a total of 432 different conformers would result if all the possible combinations of the internal rotations were to be considered. A set of twelve conformers of the N-formylmethionine molecule are then further analysed in terms of their relative stabilities, theoretically predicted harmonic vibrational frequencies, HOMO-LUMO energy gaps, ESP charges, rotational constants and dipole moments calculated using MP2/6-31++G(d,p) and B3LYP/6-311++G(d,p) levels. The calculated relative energy-range of the conformers at the MP2 level is 11.08 kcal mol?1 (1 kcal = 4.1868 kJ), whereas the same obtained at the B3LYP level is 10.02 kcal mol?1. The results of this study provide a good account of the role of four types of intramolecular H-bonds, namely O…H—O, O…H—N, O…H—C and N…H—C, in influencing the energies of the conformers as well as their conformational and vibrational spectroscopic aspects. The relative stability order of the conformers appears to depend on the level of theory used while the vibrational frequencies calculated at the B3LYP level are in better agreement with the experimental values. 相似文献
80.
S. BhattacharjeeP. Karmakar A.K. SinhaA. Charkrabarti 《Applied Surface Science》2011,257(15):6775-6778
We have investigated the formation and growth of nano sized ripple topography on ZnO thin films by 10 keV O1+ bombardment at impact angles of 80° and 60°, varying the ion fluence from 5 × 1016 to 1 × 1018 ions/cm2. At 80° the ripples are oriented along the ion beam direction whereas at 60° it is perpendicular to the ion beam direction. The developed ion induced structures are characterized by atomic force microscopy (AFM) and the alignment, variation of rms roughness, wavelength and correlation length of the structures are discussed with the existing model and basic concept of ion surface interaction. 相似文献