甲醛还原 Ag(S0）3以沉析银的研究

本文在绘制出Ag-SO_3~(2-)-H_2O系电势—pH图,且对各种还原剂还原Ag(SO_3)_2~(3-)进行热力学分析的基础上,采用静态法测试了甲醛、联氨、连二亚硫酸钠、抗坏血酸及硼氢化钾与Ag(SO_3)_2~(3-)溶液等当量混合以还原沉析银的得率,获得甲醛是最有效的还原剂。通过正交试验,得知甲醛和Ag(SO_3)_2~(3-)等当量反应沉析银的最佳条件是:pH=12.00,T=35℃±0.2,Ag~+∶SO_3~(2-)=1∶4(摩尔比)。经综合试验获得银的还原沉析率在98.5％以上。     

A two-dimensional position-sensitive detector for small-angle light scattering

A device has been developed for the rapid detection of intensity in two-dimensional small-angle light-scattering patterns. The device utilizes a vidicon detector and a microprocessor. Examples of applications of the device for small-angle light scattering from thin polymer films are presented.     

阿尔芬波加热托卡马克等离子体的能量平衡问题

本文用“剖面不变性”确定等效电子热导系数,研究了TCA装置上阿尔芬波加热的能量平衡,结果与实验符合很好。证明本文所用的方法对不同装置、不同加热方式都适用。     

Bitter型环向场线圈电流分布的研究

本文简述了用数值方法研究Ｂｉｔｔｅｒ型环向场线圈中电流分布情况，给出了不同时刻线圈中电流分布的形式以及线圈电感、电阻随时间的变化，也对电磁力的分布作了分析。     

偶氮氯膦Ⅲ与稀土元素显色反应的量子化学研究

本文用INDO/F方法,通过大量计算得到稀土离子 La~(3+)、Ce~(3+)、Pr~(3+)、Nd~(3+)、Sm~(3+)、Gd~(3+)与偶氮氯膦Ⅲ(CPAⅢ)的络合位置和 CPAⅢ的配位原子,并对其稳定性及电子结构进行了研究,最大波长吸收峰对应的跃迁是电荷迁移光谱.计算结果与实验有很好的一致性.     

Effects of solvent goodness and polymer concentration on rejection of polystyrene from small pores

Solutions of polystyrene of molecular weight 4.5 × 10⁶ and 8.4 × 10⁶ in mixed solvents of carbon tetrachloride/methanol were filtered through track-etched mica membranes at low membrane velocities. The unperturbed hydrodynamic radius of the polymer was always larger than the pore radius. The reflection coefficient σ, defined as the fraction of polymer held back by the membrane, was determined from material balances as a function of solvent flow rate per pore q, volume percent CCl₄ of the solvent, and polymer concentration C₀. In the dilute region (C₀ < C^*) σ was found to depend primarily on q and was essentially independent of chain size (or solvent goodness), molecular weight, and pore radius. In the semidilute region (C₀ > C^*) σ decreased significantly as C₀ was increased.     

The solubility of oxygen in aqueous fluorocarbon emulsions

The solubility of oxygen in aqueous fluorocarbon emulsions has been measured directly for several perfluorocarbons and monobromo or monoiodo-perfluorocarbons. The measured oxygen solubilities are consistent with results for the solubility of oxygen in neat liquid perfluorinated organic compounds.     

Chemical reactions following the IRMPD of C2F3Cl

C₂F₃Cl is photolyzed with a TEA-CO₂ laser at 1050.44 cm^–1 with focussed fluences up to 280 J/cm². The stable products in the IRMPD of C₂F₃Cl are determined for up to 10 Torr of C₂F₃Cl being photolyzed both neat and with added O₂. C₂F₄ and trans-C₂F₂Cl₂ are found to occur in the greatest yield though C₃F₅Cl, C₃F₄Cl₂, C₄F₇Cl, and C₂F₃Cl₃ also appear to be primary products. When O₂ is present F₂CO, FClCO, and CF₂ClCOF are the exclusive products. The formation of these products are for the most part consistent with a carbene formation dissociation mechanism for C₂F₃Cl IRMPD. C₂F₃Cl₃ may best be explained by another mechanism competitive with carbene formation. Many products attributed to secondary photolysis mechanisms are observed for long photolysis times.This work was performed at Department of Chemistry and chemical Engineering, Michigan Technological University, Houghton, MI 49931, USA