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991.
Yoshida K Nakashima T Yamaguchi S Osuka A Shinokubo H 《Dalton transactions (Cambridge, England : 2003)》2011,40(35):8773-8775
Two types of novel iridium pincer complexes bearing a porphyrin backbone were synthesized and characterized from dipyridylporphyrin. One of the complexes has a Lewis acidic site on the iridium center in the mer-coordination mode. The other complex takes the fac-coordination, which is rarely observed in benzene-based pincer complexes. 相似文献
992.
Heavy metal immobilization in aqueous solution using calcium phosphate and calcium hydrogen phosphates 总被引:1,自引:0,他引:1
Sugiyama S Ichii T Fujisawa M Kawashiro K Tomida T Shigemoto N Hayashi H 《Journal of colloid and interface science》2003,259(2):408-410
This study examines the possibilities for removing heavy metal cations from water with calcium phosphate, calcium hydrogen phosphate, and calcium dihydrogen phosphate at 293 K. It was reported that immobilization of aqueous heavy metal cations, which is known to be one of the characteristic properties of calcium hydroxyapatite, proceeded favorably with these phosphates. Calcium phosphate, calcium hydrogen phosphate, and calcium dihydrogen phosphate could favorably remove Pb2+ from aqueous solution. Calcium hydrogen phosphate also removed aqueous Cu2+, Co2+, and Cd2+, whereas these cations were not immobilized by calcium phosphate and calcium dihydrogen phosphate. A contribution of the dissolution-precipitation mechanism to immobilization with these phosphates is suggested. 相似文献
993.
A stereoregular and Bernoullian copolymer of styrene and ethylene was produced by the catalyst system of rac-[isopropylidenebis(1-indenyl)]zirconium dichloride and MAO. This catalyst system yields a high molecular weight copolymer with good activity at 50°C. The copolymer consists of Et-Et, St-Et, and head to tail St-St sequences and has a highly isotactic Et-St alternating sequence. This copolymer shows a melting point (80 – 110°C), due to the isotactic alternating sequence. 相似文献
994.
Dr. Eiichi Kayahara Kei Fukayama Prof. Tohru Nishinaga Prof. Dr. Shigeru Yamago 《化学:亚洲杂志》2016,11(12):1793-1797
The oxidation processes of [n]cycloparaphenylenes ([n]CPPs) (n=5–12) were systematically investigated by cyclic and rotating disk electrode voltammetry. All CPPs underwent pseudo‐reversible two‐electron oxidation irrespective of ring size, forming the corresponding radical cations and then dications. The results were in sharp contrast to those observed for linear oligoparaphenylenes, which only undergo one‐electron oxidation. The difference in the first and second oxidation potentials in the CPP oxidation was affected by the ring size and became more significant as the decrease of CPP size. In other words, while the first oxidation from neutral CPP to the radical cation occurred faster as the size of CPP becomes smaller, the second oxidation from the radical cation to dication exhibited opposite size dependence. 相似文献
995.
Regioselective Cage Opening of La2@D2(10611)‐C72 with 5,6‐Diphenyl‐3‐(2‐pyridyl)‐1,2,4‐triazine
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Prof. Dr. Michio Yamada Yasuhiro Muto Dr. Hiroki Kurihara Dr. Zdenek Slanina Dr. Mitsuaki Suzuki Prof. Dr. Yutaka Maeda Prof. Dr. Yves Rubin Prof. Dr. Marilyn M. Olmstead Prof. Dr. Alan L. Balch Prof. Dr. Shigeru Nagase Prof. Dr. Xing Lu Prof. Dr. Takeshi Akasaka 《Angewandte Chemie (International ed. in English)》2015,54(7):2232-2235
The thermal reaction of the endohedral metallofullerene La2@D2(10611)‐C72, which contains two pentalene units at opposite ends of the cage, with 5,6‐diphenyl‐3‐(2‐pyridyl)‐1,2,4‐triazine proceeded selectively to afford only two bisfulleroid isomers. The molecular structure of one isomer was determined using single‐crystal X‐ray crystallography. The results suggest that the [4+2] cycloaddition was initiated in a highly regioselective manner at the C? C bond connecting two pentagon rings of C72. Subsequent intramolecular electrocyclization followed by cycloreversion resulted in the formation of an open‐cage derivative having three seven‐membered ring orifices on the cage and a significantly elongated cage geometry. The reduction potentials of the open‐cage derivatives were similar to those of La2@D2‐C72 whereas the oxidation potentials were shifted more negative than those of La2@D2‐C72. These results point out that further oxidation could occur easily in the derivatives. 相似文献
996.
Dimetallic sulfide endohedral metallofullerene Sc2S@C76: Density functional theory characterization
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Pei Zhao Tao Yang Yi‐Jun Guo Jing‐Shuang Dang Xiang Zhao Shigeru Nagase 《Journal of computational chemistry》2014,35(22):1657-1663
In terms of density functional theory combined with statistic mechanics computations, we investigated a dimetallic sulfide endohedral fullerene Sc2S@C76 which has been synthesized without any characterization in experiments. Our theoretical study reveals that Sc2S@Td(19151)‐C76 which satisfies the isolated‐pentagon rule (IPR) possesses the lowest energy, followed by three non‐IPR structures (Sc2S@C2v(19138)‐C76, Sc2S@Cs (17490)‐C76, and Sc2S@C1(17459)‐C76). To clarify the relative stabilities of those isomers at high temperatures, enthalpy–entropy interplay has been taken into consideration. Calculation results indicate that three species Sc2S@Td(19151)‐C76, Sc2S@C2v(19138)‐C76, and Sc2S@C1(17459)‐C76 have noticeable molar fractions at the fullerene‐formation temperature region (500–3000K), and the Sc2S@C1(17459)‐C76 with one pentagon pair becomes the most predominant isomer above 1800 K, suggesting that the unexpected non‐IPR structure is thermodynamically favorable at elevated temperatures. In addition, the structural characteristics, electron features, UV‐vis‐NIR adsorptions, and 13C NMR spectra of those three stable structures are introduced to assist experimental identification and characterization in future. © 2014 Wiley Periodicals, Inc. 相似文献
997.
We demonstrate wavelength division multiplexing with chaotic subcarriers in two pairs of one-way-coupled Nd:YVO4 microchip lasers. Two individual digital messages are encoded on two chaotic carriers with different wavelengths in two transmitters by the chaotic masking method, and the mixed signals are sent to two receivers. Dual synchronization of chaos is used to obtain the original chaotic waveforms in the receivers. Two messages are decoded by filtering the difference of the laser outputs between the transmitter and the receiver by use of a low-pass filter for each pair of lasers. The message recovery can be achieved more easily when messages with small amplitude and low frequency are used. 相似文献
998.
999.
Fast Calculation of Computer-Generated Fresnel Hologram Utilizing Distributed Parallel Processing and Array Operation 总被引:1,自引:0,他引:1
Shogo Nishi Kojiro Shiba Kunihiko Mori Shigeru Nakayama Sadayuki Murashima 《Optical Review》2005,12(4):287-292
Fresnel CGH for a three-dimensional (3-D) object is generated by calculating the Fresnel diffraction, but it requires a huge amount of calculation. This is one reason for the difficulty in realizing real-time holography. We propose fast calculation method of computer-generated Fresnel hologram (Fresnel CGH) utilizing distributed parallel processing and array operation. In our method, a projected image with depth information of the 3-D object is prepared to calculate the Fresnel diffraction. The Fresnel diffraction of the projected image is then calculated with depth information by array operation and distributed parallel processing. Parallel processing is realized using JavaSpaces and many standard computers. In our array operation, calculation error in phase distribution on a hologram occurs more than the strict Fresnel diffraction. However, it was confirmed by experiments that the influence of an error can be controlled and ignored. In this paper, our proposed method and some experimental results are shown. 相似文献
1000.
Shigeru SakamotoKentaro Yamaguchi 《Tetrahedron letters》2003,44(16):3341-3344
Double-stranded oligodeoxynucleotides (6- to 14-mer) were observed by using CSI-MS. This method made it possible to observe very unstable species such as low Tm DNA duplexes which can not be detectable by conventional ESI-MS. 相似文献