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151.
Tolerance bioaccumulation and biotransformation of arsenic compounds by a freshwater prawn (Macrobrachium rosenbergii) were investigated. M. rosenbergii was exposed to 10, 20, 30 and 35 μg As cm−3 of disodium arsenate [abbreviated as As(V)], 25, 50, 100 and 120 μg As cm−3 of methylarsonic acid (MMAA), or 100,200, 300 and 350 μg As cm−3 of dimethylarsinic acid (DMAA). Tolerances (50% lethal concentration: LC50) of the prawn against As(V), MMAA, and DMAA were 30, 100, and 300 μg As cm−3, respectively. The prawn accumulated arsenic compounds directly from aqueous phase and biotransformed them in part. Both methylation and demethylation of the arsenicals were observed in vivo. Highly methylated and less toxic arsenicals were less accumulated in M. rosenbergii. 相似文献
152.
Treatment of 2,2,4,4-tetramethyl-1,5-diphenyl-6,7-dithiabicyclo[3.1.1]heptane 6-endo-oxide ( 2 ) with Montmorillonitc K 10 in dichloromethane gave 2,2,-4,4-tetramethyl-1,5-diphenyl-7,8-dithia-6-oxabicyclo-[3.2.1]octane ( 6 ) (11%) with recovery of 2 (87%). Under similar reaction conditions, the 6-exo-oxide 7 and the sulfenate 6 gave a mixture of 6 (21%), 2 (67%), and 7 (9%) and a mixture of 2 (89%) and 6 (9%), respectively. These results indicate the relative thermodynamic stabilities of the three compounds to be 2 > 6 > 7 . PM3 calculations on these compounds showed the heats of formation (kcal/mol) to be in the following order: 6 (44.12783), 2 (57.46721), and 7 (59.37918). The driving force of this unusual 1,2-rearrangement of 2 and 7 to 6 would be the release of the ring strain of the bicyclo[3.1.1]heptane system of 2 and 7 by ring expansion. 相似文献
153.
Yuzuru Uchida Katsumi Onoue Nobuaki Tada Fumio Nagao Hideaki Kozawa Shigeru Oae 《Heteroatom Chemistry》1990,1(4):295-306
Phosphine oxides bearing two or three 2-pyridyl groups react with organometallic reagents affording 2,2′-bipyridyl, 2-substituted pyridines and pyridine in good yields. Phosphonium salts and phosphine oxides, bearing at least two 2-pyridyl or substituted 2-pyridyl groups also give the corresponding 2,2′-bipyridyls and pyridines upon treatment with acid or neutral solvents such as water and alcohols in substantial yields. The 2,2′-bipyridyls are considered to be formed by ligand coupling within the pentacoordinated phosphorus intermediate formed incipiently during the reaction. 相似文献
154.
155.
Shigeru Wada 《Macromolecular Symposia》1992,57(1):327-329
The degradation of the physical properties of polypropylene (PP) used for automotive outer trims for several years is unexpectedly small. It, therefore, can be fully anticipated that PP so used can be recycled for the same purpose or for other applications. 相似文献
156.
Wei Song Ming Ni Jing Lu Zhengxiang Gao Shigeru Nagase Dapeng Yu Hengqiang Ye Xinwei Zhang 《Journal of Molecular Structure》2005,730(1-3):121-124
Possibility of encapsulations of metallofullerenes inside single-walled boron nitride nanotubes (BNNTs) is studied by using first-principles calculations. We find that both La@C82 and La2@C80 can be exothermically encapsulated inside the (17, 0) and (14, 7) BNNTs. The minimum diameters of exothermically encapsulating both La@C82 and La2@C80 inside BNNTs are predicated to be about 13.4 Å. 相似文献
157.
Computed Relative Populations of D2(22)‐C84 Endohedrals with Encapsulated Monomeric and Dimeric Water 下载免费PDF全文
Prof. Zdeněk Slanina Prof. Filip Uhlík Prof. Shigeru Nagase Prof. Xing Lu Prof. Takeshi Akasaka Prof. Ludwik Adamowicz 《Chemphyschem》2016,17(8):1109-1111
Water monomer and dimer encapsulations into D2(22)‐C84 fullerene are evaluated. The encapsulation energy is computed at the M06‐2X/6‐31++G** level, and it is found that the monomer and dimer storage in C84 yields an energy gain of 10.7 and 17.4 kcal mol?1, respectively. Encapsulation equilibrium constants are computed by using partition functions based on the M06‐2X/6‐31G** and M06‐2X/6‐31++G** molecular data. Under high‐temperature/high‐pressure conditions, similar to that for the encapsulation of rare gases in fullerenes, the computed (H2O)2@C84‐to‐H2O@C84 ratio is close to 1:2. 相似文献
158.
159.
Masahiro Ishii 《Optical Review》2009,16(4):449-451
The slant from horizontal size disparity is geometrically predictable. The apparent slant, however, is usually not equivalent
to the prediction as numerous visual factors affect it. The aim of this study is to examine whether the vertical angular subtense
of a stimulus with horizontal size disparity alters the magnitude of perceived slant for a given horizontal angular subtense.
The results indicate that a smaller angular subtense of display produces a smaller magnitude of slant perception. 相似文献
160.
The reactions of carbon dioxide, primary or secondary aliphatic amines and oxetanes at a CO2 pressure of 40 atm at 100–120°C without any catalysts afforded new monocarbamates of 1,3-propanediols, with concomitant formation of amino alcohols from oxetanes and amines. 相似文献