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31.
The transformation of aldehydes, ketones and esters to the next higher homologous aldehydes was accomplished by utilizing electroreductive 1,2-elimination as a key step. 相似文献
32.
Yuko Uchio Yukio Isozaki Tsutomu Ota Atsushi Utsunomiya Mikhail M. Buslov Shigenori Maruyama 《Proceedings of the Japan Academy. Series B, Physical and biological sciences》2004,80(9):422
The Baratal limestone in the Gorny Altai Mountains, southern Siberia, occurs as large allochthonous blocks within a Cambrian accretionary complex that developed around the Siberia craton. Before the final accretion to Siberia in the Cambrian, the terrigenous clastic-free Baratal limestone was deposited directly upon a basaltic basement with a geochemical signature identical to that of modern oceanic plateau. The Baratal limestone with 598 ± 25 Ma (Early Vendian) Pb-Pb isochron age consists of three distinct facies; 1) massive lime mudstone with ooids and stromatolites, 2) bedded lime mudstone, and 3) limestone conglomerate/breccia dominated by ooid-bearing lime mudstone clasts. The first represents a shallow marine environment on top of an ancient oceanic plateau, while the latter two represent the deeper slope to bottom-of-slope facies of a plateau. The Vendian Baratal limestone provides the oldest example of a reconstructed shallow marine carbonate buildup complex developed on a plateau/seamount in a mid-ocean. 相似文献
33.
M. Mihara T. Izumikawa H. Ueno K. Matsuta D. Nishimura T. Nagatomo T. Moriguchi Y. Ito D. Nagae M. Fukuda A. Yoshimi K. Yamada M. Takechi Y. Ichikawa S. Momota Y. Hirayama T. Ohtsubo S. Suzuki T. Kubo Y. Namiki A. Ozawa Y. Ishibashi H. Oishi K. Suzuki I. Hachiuma K. Namihira D. Horikawa T. Minamisono T. Yamaguchi T. Kuboki T. Suzuki K. Satoh Y. Kobayashi K. Asahi K. Matsukawa K. Shirai 《Hyperfine Interactions》2010,197(1-3):143-147
The β-NMR study of short-lived nucleus 58Cu (I π ?=?1?+?, T 1/2?=?3.2 s) in Si has been performed. Spin polarization of 58Cu induced by the charge exchange reaction of 58Ni was observed in Si at 15 K. The 58Cu magnetic moment $|\upmu[^{58}\mbox{Cu}]| = (0.46 \pm 0.03)\upmu_{\rm N}$ deduced from the β-NMR spectrum is consistent with the previous results on the laser spectroscopy. The present result shows that the 58Cu nucleus is promising as a new nuclear probe for the microscopic study of Cu impurities in Si. 相似文献
34.
T. Nagatomo H. Ueno M. Mihara K. Matsuta A. Yoshimi Y. Ichikawa K. Yamada H. Kawamura A. Ozawa T. Moriguchi Y. Ishibashi K. Asahi M. Uchida K. Suzuki T. Inoue Y. Hasama H. Iijima T. Sumikama M. Fukuda T. Minamisono 《Hyperfine Interactions》2010,198(1-3):103-107
Electric quadrupole coupling constant eqQ/h of the extremely proton-rich 23Al (I π ?=?5/2?+?, T 1/2?=?0.47 s) nucleus implanted into an Al2O3 single crystal has been measured for the first time, using the β-ray detecting nuclear quadrupole resonance method (β-NQR) in a high magnetic field. As a preliminary result, the quadrupole coupling constant was determined as |eqQ/h(23Al) |?=?2.66±0.77 MHz. Using the quadrupole coupling constant of 27Al in Al2O3 as a reference, the Q moment of the ground state of 23Al was extracted as |Q(23Al)|?~?160 mb, which is well explained by the shell model calculation in the sd-shell model space with the USD interaction. 相似文献
35.
36.
K. Matsuta T. Minamisono M. Mihara M. Fukuda Shengyun Zhu Y. Masuda K. Hatanaka Daqing Yuan Yongnan Zheng Yi Zuo Ping Fang Dongmei Zhou T. Ohtsubo T. Izumikawa S. Momota D. Nishimura R. Matsumiya A. Kitagawa S. Sato M. Kanazawa M. Torikoshi T. Nagatomo Y. Nojiri T. Suzuki Xizhen Zhang J. R. Alonso T. J. M. Symons S. Kawasaki S. C. Jeong Y. Watanabe K. Minamisono 《Hyperfine Interactions》2013,220(1-3):21-28
We report our studies in various fields of Physics through nuclear moments utilizing the β-NMR technique, including material sciences, nuclear structures and fundamental symmetries. Especially, we focus on the recent progress in the studies on the electronic structure in Pt through Knight shifts of various impurities, lattice locations of impurities, electric field gradients, the analysis of nuclear spin in terms of its components, anomaly in the spin expectation value for 9C-9Li mirror pair, the G-parity conservation law, and the Ramsey resonance on UCN for future neutron EDM measurements. 相似文献
37.
The behavior and mechanism of background signals during depth profiling of atmospheric elements using dual-beam time-of-flight secondary ion mass spectrometry (TOF-SIMS) have been experimentally investigated for silicon wafers. The background signals of atmospheric elements were found to be inversely proportional to the sputtering rate. Most of the background signals are largely attributable to the accumulation of components through adsorption and ion bombardment in the pre-equilibrium state. On the other hand, the contribution of real-time adsorption during the instant after the last sputtering in the equilibrium state is negligible under the present experimental conditions. H2O is dominant in the background formation process of hydrogen and oxygen, which is supported by the higher adsorption coefficients. The background levels of carbon and nitrogen are lower than those of hydrogen and oxygen. Furthermore, the background signal of carbon with respect to the sputtering rate shows a different trend than the other elements. This could be attributed to accumulation in the pre-equilibrium state. These results indicate that the background levels can be lowered close to those of dynamic-SIMS by using an extremely high sputtering rate in dual-beam TOF-SIMS. 相似文献
38.
39.
Dry ball milling of graphite with cellulose and related polysaccharides was found effective for exfoliation-dispersion of graphene-like carbon. The exfoliation behavior was found to depend strongly on the polymer species; namely, polysaccharides are much more effective than thermoplastic polymers. The compression-molded slabs from co-milled powder with cellulose and carboxymethylcellulose showed an electrical percolation threshold of 1.0 % (w/w) or lower. The carbon fraction isolated from milling with carboxymethylcellulose was water-dispersible, containing single- to few-layer graphenes. This method can provide facile and solventless graphene exfoliation and mechanical alloying with polymers. 相似文献
40.
Analysis of Cu segregation to oxide–metal interface of Ni‐based alloy in a metal‐dusting environment
Takashi Doi Kazuyuki Kitamura Yoshitaka Nishiyama Nobuo Otsuka Takeo Kudo Masugu Sato Eiji Ikenaga Shigenori Ueda Keisuke Kobayashi 《Surface and interface analysis : SIA》2008,40(10):1374-1381
Hard X‐ray photoelectron spectroscopy (HX‐PES) has been realized using high‐brilliance synchrotron radiation. High‐energy photon excitation enables us to probe photoelectrons with larger escape depth compared to conventional PES. This allows us to conduct, without destruction, a study of the embedded interface of materials as the oxide‐ metal interface. We apply HX‐PES to investigate for Cu segregation in the oxide–metal interface during metal‐dusting corrosion. The effective concentration of Cu in the segregation was estimated a few times higher than the bulk concentration. These results on the interface layer can explain the variation in the corrosion resistance. Copyright © 2008 John Wiley & Sons, Ltd. 相似文献