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101.
102.
Miyoshi K Aoki Y Kunitake T Fujikawa S 《Langmuir : the ACS journal of surfaces and colloids》2008,24(8):4205-4208
The fabrication of metallic nanostructures is one of the main issues in nanotechnology. This article describes the fabrication of a silver nanofin array by combining microlithography, electroless plating, and an etching technique. Fabricated Ag nanofins have a high aspect ratio (height/width = 10, width = 60 nm, height = 600 nm), and their widths and heights can be controlled by the period of electroless plating and the height of the original line pattern. An isolated Ag nanofin was proven to show metallic electrical conductivity. The current process provides a rapid and shape-designable fabrication method of metallic nanostructures. 相似文献
103.
Catechins are the principle polyphenolic compounds in green tea; the four major compounds identified are epicatechin (EC), epigallocatechin (EGC), epicatechin gallate (ECg) and epigallocatechin gallate (EGCg). Tea catechins tend to attach externally to their targets, such as viral envelopes, cell membranes, or the surface of low-density lipoproteins. In order to further our understanding of the molecular mobility of these compounds in cells, we examined the interaction of tea catechins with lipid membranes using solid-state NMR techniques. Our previous work indicated that the EGCg molecule is incorporated into lipid bilayers in a unique orientation. However, the detailed configuration, orientation, and dynamics of EGCg in lipid bilayers have not been well-characterized. Here, we investigated the orientation and dynamics of EGCg incorporated into multi-lamellar vesicles (MLVs) and bicelles using solid-state NMR spectroscopy. 相似文献
104.
VanSchouwen BM Gordon HL Rothstein SM Komeiji Y Fukuzawa K Tanaka S 《Computational Biology and Chemistry》2008,32(3):149-158
The cyclic AMP receptor protein (CRP) of Escherichia coli binds preferentially to DNA sequences possessing a T:A base pair at position 6 (at which the DNA becomes kinked), but with which it does not form any direct interactions. It has been proposed that indirect readout is involved in CRP-DNA binding, in which specificity for this base pair is primarily related to sequence effects on the energetic susceptibility of the DNA to kink formation. In the current study, the possibility of contributions to indirect readout by water-mediated hydrogen bonding of CRP with the T:A base pair was investigated. A 1.0 ns molecular dynamics simulation of the CRP-cAMP-DNA complex in explicit solvent was performed, and assessed for water-mediated CRP-DNA hydrogen bonds; results were compared to several X-ray crystal structures of comparable complexes. While several water-mediated CRP-DNA hydrogen bonds were identified, none of these involved the T:A base pair at position 6. Therefore, the sequence specificity for this base pair is not likely enhanced by water-mediated hydrogen bonding with the CRP. 相似文献
105.
Yang-Shin Liu Akira Yamaguchi Yue Yang An Niza El Aisnada Sho Uchida Hideki Abe Shigenori Ueda Kenji Yamaguchi Toyokazu Tanabe Masahiro Miyauchi 《Angewandte Chemie (International ed. in English)》2023,62(17):e202300640
An unexplored tin oxide crystal phase (Sn3O4) was experimentally synthesized via a facile hydrothermal method. After tuning the often-neglected parameters for the hydrothermal synthesis, namely the degree of filling of the precursor solution and the gas composition in the reactor head space, an unreported X-ray diffraction pattern was discovered. Through various characterization studies, such as Rietveld analysis, energy dispersive X-ray spectroscopy, and first-principles calculations, this novel material was characterized as orthorhombic mixed-valence tin oxide with the composition SnII2SnIVO4. This orthorhombic tin oxide is a new polymorph of Sn3O4, which differs from the reported conventional monoclinic structure. Computational and experimental analyses showed that orthorhombic Sn3O4 has a smaller band gap (2.0 eV), enabling greater absorption of visible light. This study is expected to improve the accuracy of hydrothermal synthesis and aid the discovery of new oxide materials. 相似文献
106.
Unified Total Synthesis of 3‐epi‐Ryanodol,Cinnzeylanol, Cinncassiols A and B,and Structural Revision of Natural Ryanodol and Cinnacasol
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Masaki Koshimizu Dr. Masanori Nagatomo Prof. Dr. Masayuki Inoue 《Angewandte Chemie (International ed. in English)》2016,55(7):2493-2497
Ryanodane diterpenoids structurally share an extremely complex fused ring system, but differ in the substitution patterns of the hydroxy groups. Since these congeners exhibit various biologically important functions, their efficient chemical constructions have been greatly anticipated. We previously accomplished the total synthesis of ryanodine ( 1 ) using pentacycle 8 as the advanced intermediate. Here, we report the unified total syntheses of four distinct diterpenoids, 3‐epi‐ryanodol ( 3 ), cinnzeylanol ( 4 ), cinncassiols B ( 5 ), and A ( 6 ), from 8 , all within 10 steps. A series of highly optimized chemo‐ and stereoselective reactions and protecting‐group manipulations enabled assembly of the densely oxygenated structures of 3 – 6 . Furthermore, the present synthetic studies established the C13S stereochemisty of 5 – 7 and revised the proposed structures of natural ryanodol ( 2 ) and cinnacasol ( 7 ) to be those of 3 and 6 , respectively. 相似文献
107.
M. Mihara K. Matsuta D. Nishimura T. Nagatomo R. Matsumiya S. Momota T. Ohtsubo T. Izumikawa D. M. Zhou Y. N. Zheng M. Ogura H. Akai J. Komurasaki M. Fukuda D. Ishikawa Y. Nojiri H. Hirano S. Takahashi R. Watanabe T. Kubo S. Y. Zhu A. Kitagawa M. Kanazawa S. Sato M. Torikoshi T. Sumikama T. Minamisono J. R. Alonso G. F. Krebs T. J. M. Symons 《Hyperfine Interactions》2007,178(1-3):83-86
The spin-lattice relaxation times T 1 for short-lived β emitters 25Al(I?=?5/2, T 1/2?= 7.2 s) and 28P(I?=?3, T 1/2?= 270 ms) in Pt were measured by means of the β-NMR technique. As a result, T 1[25Al in Pt] = (1.1 $^{+\ 0.7}_{-\ 0.3})$ s and T 1[28P in Pt] >0.5 s were obtained at temperatures of 17 and 20 K, respectively. The Knight shifts were estimated from the Korringa relation, which were evaluated by comparing to the first principle calculations. 相似文献
108.
109.
H. Ueno D. Kameda D. Nagae M. Takemura K. Asahi K. Shimada K. Takase T. Sugimoto T. Nagatomo M. Uchida T. Arai T. Inoue A. Yoshimi T. Kawamura K. Narita 《The European physical journal. Special topics》2007,150(1):185-186
Ground-state magnetic-dipole moments (μ) of 30-32Al and
electric quadrupole moments (Q) of 31,32Al have been measured
with the β-NMR method using spin-polarized radioactive-isotope
beams produced in projectile-fragmentation reactions. Beams of
30-32Al were obtained by using RIKEN projectile-fragment
separator RIPS after the fragmentation of 40Ar projectiles at an
energy of E = 95A MeV on a 93Nb target. The obtained
μexp[30-32Al] and
values agree well with shell-model calculations within the sd
shell using the USD interaction. Also, Qexp[31Al]
was found to be small. Thus, we can conclude that these aluminum
isotopes are located outside the island of inversion. 相似文献
110.
Noriyuki Isobe Masahiro Sekine Satoshi Kimura Masahisa Wada Shigenori Kuga 《Cellulose (London, England)》2011,18(2):327-333
Cellulose-synthetic polymer nanocomposite films were prepared by immersion of cellulose gel in polymer solutions followed
by dry casting. The cellulose hydrogel was prepared from aqueous alkali-urea solution. As the synthetic polymer, polystyrene
(PS) and poly(methyl methacrylate) (PMMA) were used. The polymer content could be changed between 10 and 80% by changing polymer
concentration of immersing solution. While the mechanical properties of the cellulose-PMMA composite films showed a nearly
linear dependence on PMMA content, those of cellulose-PS composites showed an anomalous behavior; both tensile strength and
Young’s modulus showed prominent maxima at 15–30 wt% PS contents. This anomaly may have resulted from the specific interaction
between the aromatic ring of PS and the hydrophobic plane of the glucopyranoside. Both PMMA and PS composite films showed
significant improvements in dimensional thermal stability; up to 25 wt% synthetic polymer content, the coefficient of thermal
expansion (CTE) was as low as ca. 30 ppm/K, about 1/3 of the pure polymers. This indicates that the regenerated cellulose
network is effective in suppressing thermal expansion of the synthetic polymers. 相似文献