Nonlinear optical characteristics of CdS and ZnS nanoparticles implanted into zirconium oxide thin films

The nonlinear refractive indices γ and nonlinear absorption coefficients of ZrO₂ films doped with CdS or ZnS nanoparticles, as well as with various metals, are measured. The effects of semiconductor and metal nanoparticles and annealing on the nonlinear optical properties of films are studied. The structural parameters of films, determined by electron microscopy and x-ray dispersion spectroscopy, are compared to the optical and nonlinear optical characteristics of these media. The high magnitude of γ of the films ((3±0.6)×10^?11 cm² W^{? 1}) is attributed to the surface enhancement effect in semiconductor nanoparticles. On the basis of Z-scan data obtained at different intensities of radiation, it is shown that the variations in γ of the ZrO₂:CdS(Cr) and ZrO₂:ZnS(Mn) films are related to the generation of free carriers.     

Nonlinear optical characteristics of a pseudoisocyanine solution

The saturated nonlinear absorption and Kerr nonlinearities of an aqueous pseudoisocyanine solution are investigated at the wavelengths of 532 and 529 nm with the use of pulsed laser radiation of different duration (8 ns and 475 fs). The measured values of the nonlinear refractive indices amount to ?6×10^?12 (t=8 ns) and ?8×10^?14 cm²W^?1 (t=475 fs). The change in self-action effects in pseudoisocyanine from self-defocusing to self-focusing revealed in the case of increasing intensity of femtosecond laser pulses is attributed to the effect of a fifth-order nonlinear optical process. The nonlinear refractive index responsible for this process amounts to 4×10^?24 cm⁴ W^?2. The imaginary part of the third-order nonlinear susceptibility, responsible for the induced transparency of the pseudoisocyanine solution, is Imχ ⁽³⁾=?2×10^?12 esu. Temporal changes in the shape of nanosecond laser pulses due to the nonlinear refraction induced by a thermal process are analyzed.     

Ruthenium-catalyzed hydrogenation of alkynylstannanes with migration of the stannyl group

Molecular hydrogen adds to aliphatic and aromatic alkynylstannanes in the presence of a ruthenium catalyst, pushing the stannyl group to the adjacent carbon atom to give alpha-substituted vinylstannanes. This is the first achievement of hydrogenation of alkynylstannanes, which is applicable also to the deuteration affording precursors for an important class of deuterium-labeled compounds.     

The first bowl-shaped stable neutral radical with a corannulene system: synthesis and characterization of the electronic structure

[structure: see text] A bowl-shaped neutral radical with a corannulene system has been designed and synthesized for the first time as a stable solid in air. An unequivocal characterization of the electronic properties of the radical shows that an appreciable amount of spin delocalization extends onto the corannulene unit's curved surface.     

Beam-polarization asymmetries for the p(gamma-->, K+)Lambda and p(gamma-->, K+)Sigma(0) reactions for E(gamma)=1.5-2.4 GeV

Beam polarization asymmetries for the p(gamma-->,K+)Lambda and p(gamma-->,K+)Sigma(0) reactions are measured for the first time for E(gamma)=1.5-2.4 GeV and 0.6相似文献   

Vortex glass transition and quantum vortex liquid at low temperature in a thick a- MoxSi1-x film

We present measurements of ac complex resistivity, as well as dc resistivity, for a thick amorphous MoxSi1-x film at low temperatures ( T>0.04 K) in various constant fields B. We find that the vortex glass transition (VGT) persists down to T approximately 0.04Tc0 up to B approximately 0.9Bc2(0), where Tc0 and Bc2(0) are the mean-field transition temperature and upper critical field at T = 0, respectively. In the limit T-->0, the VGT line Bg(T) extrapolates to a field below Bc2(0), while the dc resistivity rho(T) tends to the finite nonzero value in fields just above Bg(0). These results indicate the presence of a metallic quantum vortex liquid at T = 0 in the regime Bg(0)相似文献   

Reduction of ion thermal diffusivity associated with the transition of the radial electric field in neutral-beam-heated plasmas in the large helical device

Recent large helical device experiments revealed that the transition from ion root to electron root occurred for the first time in neutral-beam-heated discharges, where no nonthermal electrons exist. The measured values of the radial electric field were found to be in qualitative agreement with those estimated by neoclassical theory. A clear reduction of ion thermal diffusivity was observed after the mode transition from ion root to electron root as predicted by neoclassical theory when the neoclassical ion loss is more dominant than the anomalous ion loss.     

Observation of the "self-healing" of an error field island in the large helical device

It was observed that the vacuum magnetic island produced by an external error magnetic field in the large helical device shrank in the presence of plasma. This was evidenced by the disappearance of flat regions in the electron temperature profile obtained by Thomson scattering. This island behavior depended on the magnetic configuration in which the plasmas were produced.     

A cylindrical micro-ultrasonic motor (stator transducer size: 1.4 mm in diameter and 5.0 mm long)

Ultrasonic motors are suitable for a micro-actuator because of a direct drive, no brake and their simple construction. In order to fabricate micro-ultrasonic motors, a piezoelectric thin film is essential. In this study, a hydrothermal method was adopted to deposit a PZT thin film. The dimensions of the stator transducer were: outer diameter, 1.4 mm; inner diameter, 1.2 mm; and length, 5.0 mm. The resonance frequency of the stator transducer was 227 kHz, and the vibration amplitude was 58 nmp-p at an input voltage of 4.0 Vp-p. The maximum revolution speed was 680 rpm, and the maximum starting torque was 0.67 microNm. The experimental conditions were 20 Vp-p and 5.3 mN pre-load. The motor property versus scale was investigated using an equivalent circuit. The calculated results indicated that the output torque of the 100 microns diameter motor was 27 nNm.