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131.
Poly (n-butylisocyanate)-benzene solutions prepared by solubilization at 45°C, followed by aging at room temperature were found to be metastable for months, although, eventually, they separated into a birefringent polymer-rich phase and an isotropic solution. These metastable solutions, as well as isothermally phase-separated biphasic samples, flowed and exhibited dynamic moduli indicative of low polymer connectivity. By contrast samples prepared by a freeze-thaw cycle were uniformly and highly birefringent and showed network (gel) behavior at room temperature. The mechanism of gel formation is most likely the exclusion of the polymer from the benzene crystal during crystallization, forcing the polymer to align and exist at grain boundaries. Films formed from solutions have different moduli than those formed from gels, and are consistent with the proposed mechanism. 相似文献
132.
A. G. Akopyan 《Journal of Applied Mechanics and Technical Physics》1991,32(5):808-813
Translated from Zhurnal Prikladnoi Mekhaniki i Tekhnicheskoi Fiziki, No. 5, pp. 159–163, September–October, 1991. 相似文献
133.
In this study we report the levels of 3-methoxy-4-hydroxyphenylglycol, 3,4-dihydroxyphenylacetic acid, homovallinic acid, tryptophan, 5-hydroxyindole-3-acetic acid and serotonin in lumbar cerebrospinal fluid (CSF) from patients with multiple sclerosis, cerebrovascular disease and muscular tension headache the later, as healthy controls. The separation of these substances was performed on a reversed phase column by ion pair high performance liquid chromatography and detection was made by a glassy carbon electrode set at +900 mV vs Ag+/AgCl. The whole separation was achieved within 25 min. Concentrations of all substances (10-1000 pmole/L) were linearly proportional to areas obtained. The system is sensitive, stable and reproducible. The significance of CSF levels of these metabolites from patients groups compared with healthy controls are discussed. 相似文献
134.
V. I. Khromov V. V. Kharlamov A. M. Chekmarev G. A. Andropova B. A. Mamet A. S. Plachinda 《Hyperfine Interactions》1991,67(1-4):565-567
The iron containing corrosion products from water heat-carrier and deposits of the second circuit of the nuclear power plant were investigated by means of absorption Mössbauer spectroscopy. The nonstoichiometric magnetite and paramagnetic (superparamagnetic) iron oxide particles were found to be the main corrosion products. The fraction of the magnetically ordered phase varied in the range 0–100% depending on the location in the second circuit. 相似文献
135.
A method of identifying low-energy nuclei from the readings of an ionizational mass spectrometer is considered. The identification principles for particles recorded by a multilayer detector are discussed, together with the fundamentals of a probabilistic approach to the solution of this problem. The method permits correct analysis of the experimental data obtained. The determination of the charge and isotopic composition of radiation consisting of a mixture of different nuclei is considered. The results of calculations by the given method which permit the determination of the optimal detector parameters for the solution of the specific physical problem are outlined. This approach is also applicable for the analysis of data from other types of measuring apparatus.Translated from Izvestiya Vysshikh Uchebnykh Zavedenii, Fizika, No. 7, pp. 84–88, July, 1991. 相似文献
136.
G. M. Luke L. P. Le B. J. Sternlieb Y. J. Uemura J. H. Brewer R. Kadono R. F. Kiefl S. R. Kreitzman T. M. Riseman C. L. Seaman Y. Dalichaouch M. B. Maple J. D. Garrett 《Hyperfine Interactions》1991,64(1-4):517-522
We have performed both zero field and high transverse field measurements at dilution refrigerator temperatures on a number of heavy electron systems, examining the superconducting and magnetic properties of these interesting materials. Among the materials studied to date are UBe13, URu2Si2 and U6Fe. The magnetic field penetration depth in the superconducting state of UBe13 is greater than 10000 Å, as no increase in the transverse field relaxation rate is observed belowT c . A sharp increase in the precession frequency is seen, starting atT c . This frequency shift shows little temperature dependence at low temperature; we found no clear evidence for unconventional superconductivity in this material. Zero field measurements in URu2Si2 show the weak antiferromagnetic transition at 17.5 K. Finally, we we found no clear evidence for unconventional superconductivity in this material. Zero field measurements in URu2Si2 show the weak antiferromagnetic transition at 17.5 K. Finally, we have observed relaxation in high transverse field due to the formation of a flux lattice in U6Fe, a material where the electron effective mass is rather lighter than in other heavy fermion systems. The relaxation exhibits a sharp onset atT c=3.9 K, and is flat at low temperatures as expected for a conventional superconductor. 相似文献
137.
S K Deshpande S M Chaudhari Ashok Pimpale A S Nigavekar S B Ogale V G Bhide 《Pramana》1991,37(4):373-385
An automated linear laboratory EXAFS spectrometer of the Johansson type has been indigenously developed. Only two translational
motions are required to achieve the necessary Rowland circle configuration for the (fixed) X-ray source, the dispersing and
focusing bent crystal and the receiving slit. With the available crystals the spectral region from 5 to 25 keV can be scanned.
The linear motions of the crystal and receiving slit including the detector assembly are achieved by employing software-controlled
DC motors and utilizing optical encoders for position sensing. The appropriate rotation of the crystal is achieved by the
geometry of the instrument. There is a facility to place the sample alternately in the path of the X-ray beam and out of the
path to record both the incident X-ray intensityI
0 and the transmitted intensityI employing the scintillation detector. An arrangement with a two-window proportional detector before the sample to measureI
0 and the scintillation detector to recordI is also developed; in this case it is not necessary to oscillate the sample. Fast electronic circuits are employed to minimize
counting errors. The instrument is user-friendly and it is operated through a menu-driven IBM compatible PC. EXAFS spectra
of high resolution have been recorded using the spectrometer and employing the Si(111) reflecting planes; the X-ray source
being a Rigaku 12 kW rotating anode with Cu target. We describe the spectrometer and discuss its performance with a few representative
spectra. 相似文献
138.
Recent studies have established that side chain polymeric liquid crystals composed of mesogenic and non-mesogenic side groups keep their liquid-crystalline properties even for a low proportion of mesogens. We show that the detailed structures of three kinds of new diluted liquid crystal polysiloxanes depend on the nature of the co-substituent as well as on the proportion of the silicon sites occupied by the mesogenic groups. Mixtures of these systems with low molar mass liquid crystals were also investigated in terms of compatibility and/or stabilization of smectic A phases. 相似文献
139.
140.
A potential of mean torque is derived for a solute at infinite dilution in a uniaxial liquid crystal solvent, which contains terms originating from the dispersion interaction, and the electrostatic interaction between quadrupole moments on both molecules. It is shown that the electrostatic term is non-zero only if the solute-solvent vectors are distributed with lower than spherical symmetry. If this distribution has cylindrical symmetry then both the electrostatic and dispersion terms in the potential of mean torque are shown to depend on order parameters for the orientational distribution of the solute-solvent vectors, as well as on the order parameters of the solvent molecules. 相似文献