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Harald Müller Anna Puig Molina B. Zh. Narymbetov L. V. Zorina S. S. Khasanov R. P. Shibaeva 《无机化学与普通化学杂志》1998,624(9):1492-1496
The title compounds were prepared from 1,3,4,6-tetrathiapentalene-2,5-dione ( 1 ) in one step via the in situ generated intermediate 2-oxo-1,3-dithiole-4,5-dithiolate (dmid; 2 ). The X-ray single crystal structure of (Et4N)2[Zn(dmid)2] ( 3 a ) gave the tetragonal space group P43212 with a = b = 13.810(2) Å, c = 16.480(3) Å, and Z = 4. (n-Bu4N)2[Zn(dmid)2] ( 3 b ) gave the triclinic space group P 1 with a = 11.947(4) Å, b = 14.665(5) Å, c = 16.662(8) Å, α = 100.21(3)°, β = 104.46(3)°, γ = 110.73(3)°, and Z = 2. 相似文献
57.
A. A. Bumber O. D. Lalakulich N. V. Shibaeva M. E. Kletskii A. I. Pyshchev 《Chemistry of Heterocyclic Compounds》1999,35(1):68-71
It is shown that reduction of the 6-methyl-1-(p-tolyl)-2,4-diphenylpyrimidinium cation proceeds in two one-electron stages. In the first stage, an unstable radical is formed, and in the second stage, an unstable anion. As a result of dehydrogenation of the radical, the anhydro base 6-methylene-1-p-tolyl-2,4-diphenyl-6H-pyrimidine is formed. Oxidation of this compound in a single one-electron stage forms an unstable cation radical, the hydrogenation of which leads to the original pyrimidinium cation. Data obtained by cyclic voltametry and electrosynthesis with subsequent identification of the products have shown that, the same as in the reaction with the hydroxide anion, the methyl-substituted pyrimidinium cation acts as a CH-acid.Rostov State University, Rostov-on-Don 344101, Russia. Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 1, pp. 71–75, January, 1999. 相似文献
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O. N. Lygo T. D. Nekipelova E. N. Khodot V. A. Kuzmin V. V. Shakhmatov V. A. Volnukhin V. V. Vargin A. B. Shevelev A. V. Shibaeva 《High Energy Chemistry》2012,46(3):171-176
Spectral, luminescent, and photochemical properties of 7,7,9-trimethyl-6,7-dihydrofuro[3,2-f]quinoline (FDHQ) have been studied in hexane, alcohols, and water. Unlike 1,2-dihydroquinolines without the furo substituent, the fluorescence
quantum yields for FDHQ in water and methanol are high (0.4 and 0.2, respectively), thereby indicating a difference in routes
of excitation energy degradation in these compounds. The regularities in the FDHQ phototransformations have been studied by
steady-state photolysis. The composition and the yield of final products depend on the presence or absence of oxygen in the
system to a higher extent than on the solvent nature. This indicates the participation of the triplet excited state in the
photo-chemical reactions in oxygen-free systems. 相似文献
59.
Sapozhnikov D. A. Chuchalov A. V. Bayminov B. A. Shibaeva P. A. Chaika E. M. Buzin M. I. Kosolapov A. F. Semjonov S. L. Vygodskii Ya. S. 《Russian Chemical Bulletin》2020,69(8):1486-1491
Russian Chemical Bulletin - Organosoluble polyimides with tetramethyldisiloxane fragments in the main chain were synthesized by one-step high-temperature polycondensation and their properties were... 相似文献
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