Effect of the Si/Ce molar ratio on the textural properties of rare earth element cerium incorporated mesoporous molecular sieves obtained room temperature

Rare earth Ce-incorporated MCM-41 mesoporous molecular sieves (CeMCM-41) were synthesized via a direct and nonhydrothermal method at room temperature from sodium silicate and ammonium cerium (IV) nitrate as raw materials. Cetyltrimethyl ammonium bromide (CTAB) was used as a template. The resultant samples were characterized by means of powder X-ray diffraction (XRD), transmission electron microscope (TEM), Fourier transform infrared spectroscopy (FT-IR), diffuse reflectance ultraviolet–visible spectroscopy (UV–vis) and N₂ physical adsorption, respectively. The effect of the Si/Ce molar ratio on the crystalline structure and textural properties of CeMCM-41 was also investigated. The experimental results show that ordered CeMCM-41 mesoporous molecular sieves were successfully synthesized at room temperature and the resultant mesoporous materials have specific surface areas in the range of 594–1369 m²/g and average pore sizes in the range of ca. 2.5–2.8 nm. It has been found that the structural properties are strongly related to the amounts of cerium incorporation. When the cerium content increased in the samples, the intensity of the peak (1 0 0) was gradually reduced, and the surface area and structural regularity were diminished.     

Electroluminescent block copolymers containing oxadiazole and thiophene via ATRP

Block copolymers containing thiophene units in one block and oxadiazole (OXD) units in the other were prepared. Atom transfer radical polymerization method was used to obtain the thiophene‐containing mesogen‐jacketed polymers, and the kinetic study indicated that the polymerization was controllable and the polymers could be used to initiate the polymerization of the OXD‐containing monomers. Photoluminescent spectra indicated that the fluorescence quantum yields of the polymers increased with increasing content of OXD. And, more OXD domains, that is, more interfaces between the hole‐transport parts and electron‐transport parts, resulting in the higher probability of exciplex formation. The electroluminescent devices containing the block copolymer with 64 mol % OXD as the emissive layer had a maximum brightness of 127 cd/m² and an extremely low onset voltage of 7.7 V, which indicated that the injection and transport of charge carriers were facilitated and the number of charge carriers was sufficiently high in early time after the voltage was turned on. © 2010 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem, 2010     

稳定受迫振动中的能量转换

将强迫分解成超前位移π／２和位移相同或反相的两个分量，通过对两分力作功的定量计算，可以方便地讨论受迫振动中的能量转换，并能对共振作出较的物理解释。     

Special complex open-cavity and low-magnetic-field high-powergyrotron

A theory is proposed for the special complex cavity; it is in the form of a single resonant circuit having a TE_0n&lrarr2;TE_0,n+p mode converter and it features excellent mode selectivity, high power capability, and an asymmetric triangle profile of the RF field that is favourable to efficient operation for a 35-GHz second-harmonic gyromonotron employing this complex cavity with TE₀₃ mode output are numerically illustrated and experimentally demonstrated. Power as high as 200 kW and efficiency as high as 30% have been obtained. These experimental results are record values for a gyrotron operating at the second-harmonic millimeter wavelength. Implications of the single-resonant complex cavity for the fundamental harmonic and third-harmonic high-average-power gyrotron design are discussed     

Temperature overshoots for a 4-velocity unidimensional discrete Boltzmann model

We propose a 4-velocity unidimensional discrete Boltzmann model with two different speeds 2, 1 and two different masses 1, 2. With the three conservation laws of mass, momentum, and energy satisfied, we can introduce a nontrivial temperature. First, we determine the similarity shock waves satisfying physical properties: positivity, shock stability, inequalities of the subsonic and supersonic flows, increase or decrease of both mass and temperature across the shock. It results that either the speed of the shock front is higher than the speed 1 of the slow particles and the shocks are compressive or less than 1 and the shocks are rarefactive. We observe overshoots of the temperature, across the shock, with bumps higher and higher as the shock front speed increases. Second, we study the (1+1)-dimensional shock waves. They represent the superposition and collision of two compressive shocks traveling in opposite directions and we observe temperature overshoots for not too large times.     

对"坚持时代性与基础性相结合原则"的思考与认识--高中物理改革教材编写中的一些体会

2003年8月开始，我应邀参加了物理通报教材研究中心组织的高中物理改革教材的编写工作．在编写过程中，如何领会与掌握“坚持时代性与基础性相结合原则”一直是大家关注的一个热点问题．本文介绍一下我对这一问题的思考与认识以及在教材编写中的一些具体做法．抛砖引玉，希望更多同志参与探讨．     

Syndiotactic polymerization of styrene catalyzed by alkenyl‐substituted cyclopentadienyltitanium trichlorides

CH₂?CHCH₂CpTiCl₃ (1), CH₂?CHCH₂CH₂CpTiCl₃ (2) and CH₃CH₂CH₃CpTiCl₃ (3) have been synthesized and characterized. The influence of the alkenyl substituent groups on the catalyst activities in the syndiotactic polymerization of styrene was investigated. The catalyst activities decreased in the order CH₂?CHCH₂CH₂CpTiCl₃ > CH₃CH₂CH₂CH₂CpTiCl₃ > CH₃CH₂CH₂CpTiCl₃ > CH₂?CHCH₂CpTiCl₃ (Cp?C₅H₄). By using complex 1, the dependence of the activity on the concentration of methylaluminoxane, triisobutylaluminum and diisobutylaluminum hydride was investigated. Copyright © 2003 John Wiley & Sons, Ltd.