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101.
102.
A new electroactive polynuclear inorganic compound of rare earth metal, gadolinium hexacyanoferrate (GdHCF), was prepared and characterized using the techniques of FTIR spectroscopy, thermogravimetric analysis (TG), UV-Vis spectrometry, X-ray photoelectron spectroscopy (XPS), ICP atomic emission spectroscopy, and EDX. The results of ICP atomic emission spectroscopy, EDX, and TGA indicated that the prepared GdHCF sample had a stoichiometry of NaGdFe(CN)6·12H2O (when GdHCF was prepared in NaCl solution). The FTIR spectrum of GdHCF showed that there were two types of water molecules in the structure of GdHCF: one was the interstitial water (5 H2O), which resulted from the association of water due to H-bonding, and the other was water coordinated with Gd (7 H2O). The results obtained using XPS showed that the oxidation state of Fe and Gd in the GdHCF sample was +2 and +3, respectively. GdHCF was immobilized on the surface of spectroscopically pure graphite (SG) electrode forming the GdHCF/SG electrode, and the solid-state electrochemistry of the resultant electrode was studied using cyclic voltammetry. The cyclic voltammetric results indicated that the GdHCF/SG electrode exhibited a pair of well-defined and stable redox peaks with the formal potential of E0′=(197±3) mV. The effects of the concentration of the supporting electrolyte on the electrochemical characteristics of GdHCF were studied, and the results showed that the value of E0′ increased linearly with the activity of the cationic ion of the supporting electrolyte (lgaNa+), with a slope of 54.1 mV, which may become a novel method for determining the activity of Na+ in solution. Further experimental results indicated that GdHCF had electrocatalytic activities toward the oxidation of dopamine (DA) and ascorbic acid (AA), and the electrocatalytic current increased linearly with the concentration of DA (or AA) in the range of 1.0–10.0 mmol·L?1 (for DA) or 0.5–20.0 mmol·L?1 (for AA). 相似文献
103.
Song LI Guo Mao WANG Zhi Song LIU 《数学学报(英文版)》2005,21(6):1475-1486
The purpose of this paper is to investigate the mean size formula of wavelet packets in Lp for 0 〈 p ≤ ∞. We generalize a mean size formula of wavelet packets given in terms of the p-norm joint spectral radius and we also give some asymptotic formulas for the Lp-norm or quasi-norm on the subdivision trees. All results will be given in the general setting, 相似文献
104.
陈海珍 《宁波大学学报(理工版)》2004,17(4):444-448
选用了钛酸丁酯、硬脂酸和乙二醇作为表面活性剂,采用表面化学修饰和表面物理修饰2种方法修饰纳米氧化钛,然后分散在乙二醇溶剂中形成溶胶溶液.并通过红外光谱仪、紫外分光计、原子力显微镜,分析了表面化学修饰后的纳米氧化钛表面化学结构的变化,观测了纳米氧化钛溶胶在乙二醇溶剂中稳定性.试验结果表明表面活性剂与纳米氧化钛的表面的不饱和键之间形成了新的化学结构,粒子表面可能接枝上有机长链,提高了纳米粒子在溶剂中的相容性.表面化学修饰后的纳米氧化钛与乙二醇溶剂形成了较稳定的溶胶体系,而且纳米溶胶粒径较小.表面活性剂添加量与纳米粒子添加量控制在(1~1.2):1时,可以获得纳米溶胶粒径较小,同时溶胶稳定性较好的纳米氧化钛-乙二醇溶胶体系. 相似文献
105.
本文报道了在硫酸性介质中 ,以吐温 - 80为增溶剂 ,溴酸钾氧化姜黄催化光度法测定痕量钒 ( )的新体系。方法的检出限为 2 .6× 10 -3mg· L-1;相对标准偏差为 2 .7% (n=9) ,线性范围为 0 .0 12— 0 .0 4 0mg· L-1。可用于测定水样中痕量钒 ( ) ,结果满意 相似文献
106.
Nanograins are characterized by a typical grain size from lto 100 nm.Mclecular dynamics aimubations have been carried out for the nanograin sphere with the diameters from 1.45 to 10.12 nm.We study the influence of grain size on structure and diffusion properties of the nanograins.The results reveal that as the grain size is reduced,the fraction of grain surface increases significantly,and the surface width is approximately constant;the diffusicn coefficlent is increased sharply,and the relation of the diffusion coefficient and the grain size is close to exponential relation below 10nm. 相似文献
107.
车前子中多糖含量的测定 总被引:12,自引:1,他引:11
采用蒽酮-硫酸法比色测定,用精制车前子多糖测得车前子多糖对葡萄糖的换算因子,对我国同属不同品种的车前子不同采集时间及炮制前后其多糖含量进行了比较研究。结果表明:此测定方法简便可行。供试液在8h内显色稳定,重现性较好,平均回收率为97.8%,RSD=1.41%(n=5)。江西吉安产大粒车前子生品多糖含量在9.15%~9.83%之间,炮制后其多糖含量在6.29%~6.81%之间;南昌新祺周车前GAP标准基地的大粒车前子生品多糖含量为7.85%~8.38%,炮制后其多糖含量为6.01%~6.64%;东北产的小粒车前子生品多糖含量为6.61%,炮制后其多糖含量为6.45%。 相似文献
108.
线性泛函方程解的振动性的新结果 总被引:1,自引:0,他引:1
本文研究高阶泛函方程x(g(t))=P(t)x(t)+Q1(t)x(g2(t))+…+Qk(t)x(gk+1(t))解的振动性,得到了一些新的振动条件.改进和推广了已有结果. 相似文献
109.
A new prediction technique is proposed for chaotic time series. The usefulness of the technique is thatit can kick off some false neighbor points which are not suitable for the local estimation of the dynamics systems. Atime-delayed embedding is used to reconstruct the underlying attractor, and the prediction model is based on the timeevolution of the topological neighboring in the phase space. We use a feedforward neural network to approximate thelocal dominant Lyapunov exponent, and choose the spatial neighbors by the Lyapunov exponent. The model is testedfor the Mackey-Glass equation and the convection amplitude of lorenz systems. The results indicate that this predictiontechnique can improve the prediction of chaotic time series. 相似文献
110.
A rigorous finite element analysis procedure is developed to study the effect of the inner structures on the acoustic absorption of multi-layer absorbers. To do this, four types of basic inner structure compartments adopted in the multi-layer absorbers are selected for analysis. These compartments are composed of porous materials inlaid with perforated plates of various shapes, say, triangle, semicircle, convex rectangle and plate shapes. As it is different from the conventional finite element analysis for the acoustic system in the literature, the perforated plates are simulated by appropriate equivalent boundary conditions, depending on their thickness, hole radius, hole pitch and porosity and the air contained in the holes. A large number of total degrees of freedom generated from meshing the air in the holes of perforated plates are thus avoided. The results reveal that the inner structures of the multi-layer absorbers will influence the acoustic absorption at some frequency bands significantly. Based on those features, the multi-layer absorber with a novel inner structure is then designed and manufactured. Both the finite element and experimental results show that its acoustic absorption would be distinctly promoted. 相似文献