Water‐Soluble Monolayer Molybdenum Disulfide Quantum Dots with Upconversion Fluorescence

Uniform water‐soluble monolayer MoS₂ quantum dots (MQDs) with lateral sizes of ≈2.1 nm, a clearly zigzag‐terminated edge, and a hexagonal lattice structure are achieved using ammonium molybdate, thiourea, and N‐acetyl‐l ‐cysteine (NAC) as precursors and the capping reagent in a facile one‐pot hydrothermal approach. MQDs have good dispersity and high stability in aqueous suspension and exhibit a significantly larger direct bandgap (3.96 eV) compared to monolayer MoS₂ nanosheets (1.89 eV). Pronounced blue‐shifts in the wavelengths of both the excitonic absorption and intrinsic state emission with activated strong luminescence at room temperature beyond monolayer MoS₂ nanosheets is demonstrated. Unusual upconversion photoluminescence is also observed and is caused by two successive transfers of energy from the near‐infrared (NIR) absorption generated by the NAC capping reagent to the hexagonal structure of MQDs. Additional optical properties of MQDs may provide numerous exciting technological applications. Here, MQDs are demonstrated as a highly selective fluorescent reagent for detecting tetracycline hydrochloride under UV and NIR irradiation.     

大散射角散斑场中有关相位奇异新特性的研究

利用散斑场和参考光的干涉提取散斑场复振幅和相位, 研究了不同散射角下散斑场相位的分布规律以及相位奇异处光波复振幅实部零值线和虚部零值线夹角、光强等值线离心率的统计特性. 在大散射角散斑中发现了一种新的相位奇异现象, 即相位奇异线; 研究了相位在跨越奇异线时的突变规律及涡旋状相位的分布特征, 发现在相位奇异线处存在着呈双曲线或抛物线状的光强等值线.     

光学薄膜诱导偏振像差对大数值孔径光学系统聚焦特性的影响

大数值孔径光学系统表面光线的入射角较大, 会导致薄膜的偏振分离, 诱发偏振像差, 影响光学系统的聚焦特性. 本文利用矢量光衍射理论, 建立了光学薄膜各参量与光学系统聚焦光场的模型. 利用该模型分析了线偏振光入射时, 光学薄膜对光学系统聚焦光斑的扰动. 在此基础上, 探讨了应用了不同约束条件下得到的光学薄膜对最终聚焦光场的影响, 确定了减小薄膜扰动光学系统光斑的设计方法, 即额外添加透射率差和位相差的约束条件, 并且适当增加位相差约束的权重. 利用该方法优化设计的薄膜, 相比于普通减反膜而言, 对系统聚焦光场中心强度的提升可达约12.5%.     

基于LabVIEW的砝码自动检定系统设计与实现

针对目前砝码检定工作操作过程复杂、检定效率低等问题,设计了一种基于LabVIEW的砝码自动检定系统。在符合砝码检定规程的情况下,系统实现了检定数据实时采集、数据处理、生成原始记录、管理标准器、查询历史数据和衡器控制等功能。相对现有的砝码检定方法有操作简单、高效、程序移植性好等优点。系统由主控计算机、串口转无线扩展卡、多台衡器设备及相应的标准砝码装置组成。通过使用串口转Wi-Fi模块,系统可实现控制多台衡器设备的需求。实验结果证明,系统运行稳定可靠,采集数据准确,容易扩展,且大幅度减轻了检定人员的劳动强度,在计量检定工作中具有一定的实用和推广价值。     

基于ZigBee的煤矿井下预警防爆监测系统设计

针对矿山井下的特殊环境,提出了一种基于ZigBee技术的煤矿井下预警防爆监测系统,实现煤矿井下环境信息和人员位置的实时监测,以减少事故发生率;井下系统采用CC2530+CC2401芯片作为ZigBee节点的核心,井下主控制器通过CAN总线实现与井上上位机的通信;上位机使用Labview软件实现程序编程,实时显示煤矿井下采集到的CH₄、CO、O₂浓度、温湿度和人员坐标等参数并进行Web发布;该系统结合了基于模糊逻辑算法的预警技术、基于物理隔离的防爆技术,同时提出了一种融合LQI的RSSI加权质心算法;实验证明该系统运行稳定可靠,提高了人员定位的精度,具有良好的应用前景。     

Study on LiFe<Subscript>1 − <Emphasis Type="Italic">x</Emphasis></Subscript>Sm<Subscript><Emphasis Type="Italic">x</Emphasis></Subscript>PO<Subscript>4</Subscript>/C used as cathode materials for lithium-ion batteries with low Sm component

LiFe_1???x Sm _x PO₄/C cathode materials were synthesized though a facile hydrothermal method. Compared with high-temperature solid-phase sintering, the method can allow for the fabrication of low Sm content (2 %), a scarce and expensive rare earth element, while the presence of an optimized carbon coating with large amount of sp²-type carbon sharply increases the material’s electrochemical performance. The high-rate dischargeability at 5 C, as well as the exchange current density, can be increased by 21 and 86 %, respectively, which were attributed to the fine size and the large cell parameter a/c as much. It should be pointed out that the a/c value will be increased for the LiFePO₄ Sm-doped papered by both of the two methods, while the mechanism is different: The value c is increased for the front and the value a is decreased for the latter, respectively.     

相同尺度下气泡与复杂壁面的耦合特性研究

采用格子Boltzmann方法(LBM)建立了气液固三相耦合的动力学模型,研究了相同尺度下上浮气泡与复杂壁面的相互耦合作用.首先,基于黏性流体理论,通过构建一组格子Boltzmann(LB)方程来描述气液两相的运动,并以LB离散体积力的形式计入了黏性力、表面张力和重力.同时,采用LBM中的Half-way反弹模型与有限差分格式相结合的方式进行固壁边界的处理.然后,利用本文建立的模型,对不同特征尺寸比条件下,气泡与考虑边缘效应的平面固壁和曲面固壁的耦合特性进行了研究.研究发现固壁边界条件以及特征尺寸比对气泡的运动和拓扑结构的变化都具有明显的非线性影响.最后,研究了流体属性对气泡与复杂壁面耦合规律的影响.     

Increment sizes of the principal value of Brownian local time

Let W be a standard Brownian motion, and define Y(t)= ∫₀ ^t ds/W(s) as Cauchy's principal value related to local time. We determine: (a) the modulus of continuity of Y in the sense of P. Lévy; (b) the large increments of Y. Received: 1 April 1999 / Revised version: 27 September 1999 / Published online: 14 June 2000