A Novel Method to Synthesize Polyorganozircosilazane

A new kind of polyorganozircosilazane as Si/Zr/C/N-based ceramic precursor was synthesized from the condensation reaction of hexamethyleyclotrisilazane lithium salts(D3^NLi）and zirconium tetrachloride(ZrCl4).In the presence of N,N,N’,N’-tetramethyl ethylene diamine(TMEDA),polyorganozircosilazane was obtained in high yield.     

Seven novel seco-prezizaane-type sesquiterpenes from the pericarps of Illicium merrillianum

Seven new seco-prezizaane-type sesquiterpenes were isolated from the methanol extract of the pericarps of Illicium merrillianum. Their structures were elucidated as 3-deoxypseudoanisatin (1), 2beta-hydroxy-3,6-dedioxypseudoanisatin (2), 8alpha-hydroxy-10-deoxycyclomerrillianolide (3), 10beta-hydroxypseudoanisatin (4), 10beta-hydroxycyclopseudoanisatin (5), 1,6-dihydroxy-3-deoxyminwanensin (6), and 8-deoxymerrilliortholactone (7) by analyses of their spectroscopic data and chemical transformation. Compounds 4 and 5 as well as 6 and 7 coexist as a keto/acetal equilibrated mixture in methanol solution.     

Experimental investigation on large deflection response of a frame impacted by a moving body

This paper reports on the experimental investigation of the dynamic large deflection response of a portal frame impacted at its midspan by a body moving at a certain speed. Both the deflection and velocity vs. time curves of the midspan and the dynamic history of a number of desired locations were recorded during the process of response. On the basis of the test data, the momentum and kinetic energy conversion between the frame and the moving body in the impact process are realized, and the occurrence and expansion of plastic regions are described. Investigation results show that the initial collision is approximately ideally inelastic, and that the elastic deformation plays a considerable role in the response though the input energy is much larger than the maximum elastic energy capacity of the beam member; therefore, in a general impact, the energy ratio should not be regarded as a sufficient criterion for a rigid—plastic solution. The ratios of the impulse transferred to and the energy absorbed by the frame in the initial collision to that carried by the moving body before impact is only related to the ratiobetween the equivalent mass of the frame paticipating in the initial collision and the mass of the impacting body, having nothing to do with the impacting velocity to a certain extent.     

Kantorovich-type inequalities and the measures of inefficiency of the glse

In this paper we introduce some Kantorovich inequalities for the Euclidean norm of a matrix, that is, the upper bounds to (X'B ^–1 X) ^–1 X'B ^–1 AB ^–1 X(X'B ^–1X)^–1 X' BX(X'AX) ^–1 X'CX² are given, where A²=trace (A'A). In terms of these inequalities the upper bounds to the three measures of inefficiency of the generalized least squares estimator (GLSE) in general Gauss-Markov models are also established.Project supported partially by the Third World Academy of Sciences under contract TWASRG 87-46 and by the National Natural Science Foundation.     

Layered petroleum reservoirs with cross-flows

Studied is a cylindrical reservoir consisting of three layers: a water-containing bottom layer, and two oil-containing top layers from whose upper layer oil is produced. For its solution, a corrected version of the finite Hankel transform for Neumann-Neumann boundary conditions was used together with numerical inversion of the Laplace transform. The effects of the water zone on the unsteady state pressure in the reservoir were evaluated at distances away from the well and at the well-bore itself. We found that the vertical pressure drop increases gradually with time and is more significant in the vicinity of the well-bore. For constant production and at any time t, smaller reservoirs experience higher pressure drops than larger ones. For the reservoir investigated, we found that for nondimensional time t _Dw <10⁴ the presence of a second fluid (water) has no effect on the pressure drop. Of all the formation and fluid properties investigated, porosity has the largest effect on pressure.Nomenclature c ₁, c ₂ Oil and water compressibilities, vol/vol/atm, vol/vol/psi - h Height of water zone from bottom of reservoir, cm, ft - h _D h/r _w , non-dimensional - H Height of reservoir, cm, ft - H _D H/r _w, non-dimensional - J ₀, J ₁ Bessel functions of the first kind, zero and first-order - K _r2, K _r1 Oil and water zones, horizontal permeabilities, darcies, md - K _z2, K _z1 Oil and water zones, vertical permeabilities, darcies, md - k ₁ n=1, 2, 3... - k ₂ n=1, 2, 3... - k _1,0 - k _2,0 - p(r, z, t) P(r, z, 0)–P(r, z, t), atm, psi - P(r, z, t) Pressure at any layer in the reservoir, atm, psi - P(r, z, 0) Initial pressure at any layer in the reservoir, atm, psi - P _D , non-dimensional - q Constant production rate of well, cc/sec, barrels/day - r Radius of reservoir, cm, ft - r _D r/r _w , non-dimensional - r _e Drainage radius, cm, ft - r _eD re/r _w , non-dimensional - r _w Well-bore radius, cm, ft - t Time, sec, hr - _Dw (k _r2 t)/( _{2 2} c ₂ r _w ² ), non-dimensional - Y ₀, Y ₁ Bessel functions of the second kind, zero and first-order - z Distance z measured vertically upward from bottom of reservoir, cm, ft - Z _D z/r _w , non-dimensional - z ₁ Height of the bottom of the producing layer, cm, ft - z _1D z ₁/r _w , non-dimensional - z ₂ Height of the top of the producing layer, cm, ft - z _2,D z ₂/r _w , non-dimensional - _n nth positive root of equation (18) - ₁ k _z1/k _r1, non-dimensional - ₂ k _z2/k _r2, non-dimensional - _{1 1 1} c ₁/k _r1, hydraulic diffusivity of layer I - _{2 2 2} c ₂/k _r2, hydraulic diffusivity of layers II and III - ₂, ₁ Viscosity of oil and water, cp, cp - _{n n} /r _w , l/cm, l/ft - ₂, ₁ Porosity of oil and water-filled zones, fraction - ( ₁/ ₂) (k _z2/k _z1), non-dimensional     

Weighted norm inequalities for the vectorvalued Hardy-Littlewood maximal functions of one parameter rectangles

Let N denote the Hardy-Littlewood maximal operator for the familyR of one parameter rectangles. In this paper, we obtain that for 1 _w ^p (l^r) to L _W ^P (l^r) if and only if w ∈ A_P(R); for 1≤p<∞, N is bounded from L _W ^P (l^r) to weak L _W ^P (l^r) if and only if W ∈ A_P(R). Here we say W∈A_p (1), if $$\begin{gathered} \mathop {sup}\limits_{R \in R} \left( {\tfrac{1}{{|R|}}\smallint _r wdx} \right)\left( {\tfrac{1}{{|R|}}\smallint _R w^{ - 1/(p - 1)} dx} \right)^{p - 1}< \infty ,1< p< \infty , \hfill \\ (Nw)(x) \leqslant Cw(x)a.e.,p = 1 \hfill \\ \end{gathered} $$ ,     

Essay on gravitation: Present-time variation of Newton's gravitational constant in superstring theories

Superstring theories provide an appropriate framework for studying the time variation of fundamental coupling constants. The present time variation of coupling constants in Superstring theories with currently favorable internal backgrounds critically depends on the shape of the potential for the size of internal space. If the potential is almost flat, as in perturbation theory to all orders, the present value of ¦/G¦ for Newton's gravitational constant is calculable and estimated to be 1×10^–11±1yr^–1, which is just at the edge of the present observational bound for/G. If the potential has a minimum with finite curvature due to unknown nonperturbative effects,/G will become unobservably small. The improvement of the measurement of/G of 1 or 2 orders of magnitude would discriminate between the two situations. Problems with the time variation of other coupling constants are also discussed.This essay received the fourth award from the Gravity Research Foundation for the year 1987-Ed.