首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   119129篇
  免费   6722篇
  国内免费   4841篇
化学   53402篇
晶体学   1191篇
力学   9210篇
综合类   405篇
数学   36543篇
物理学   29941篇
  2024年   149篇
  2023年   858篇
  2022年   1377篇
  2021年   1419篇
  2020年   1646篇
  2019年   1623篇
  2018年   11417篇
  2017年   11131篇
  2016年   7750篇
  2015年   2679篇
  2014年   2585篇
  2013年   3341篇
  2012年   7433篇
  2011年   14015篇
  2010年   7986篇
  2009年   8229篇
  2008年   9043篇
  2007年   11013篇
  2006年   2428篇
  2005年   3163篇
  2004年   2910篇
  2003年   3156篇
  2002年   2205篇
  2001年   1226篇
  2000年   1129篇
  1999年   1076篇
  1998年   1014篇
  1997年   942篇
  1996年   1100篇
  1995年   818篇
  1994年   726篇
  1993年   639篇
  1992年   555篇
  1991年   504篇
  1990年   387篇
  1989年   346篇
  1988年   277篇
  1987年   233篇
  1986年   217篇
  1985年   205篇
  1984年   171篇
  1983年   119篇
  1982年   101篇
  1981年   87篇
  1980年   76篇
  1979年   63篇
  1978年   56篇
  1977年   44篇
  1975年   44篇
  1914年   45篇
排序方式: 共有10000条查询结果,搜索用时 31 毫秒
991.
超短光脉冲源是光时分复用(OTDM)系统中的关键器件.提出了一种基于单端半导体光放大器(SOA)的注入型主动锁模光纤激光器产生超短光脉冲的方案,建立了该方案的理论模型.实验实现了高消光比稳定的重复频率10—40GHz皮秒级光脉冲的输出,输出波长在30nm范围内连续可调. 关键词: 超短光脉冲 单端半导体光放大器 主动锁模  相似文献   
992.
We investigate traces of functions, belonging to a class of functions with dominating mixed smoothness in ℝ3, with respect to planes in oblique position. In comparison with the classical theory for isotropic spaces a few new phenomenona occur. We shall present two different approaches. One is based on the use of the Fourier transform and restricted to p = 2. The other one is applicable in the general case of Besov-Lizorkin-Triebel spaces and based on atomic decompositions.  相似文献   
993.
In the present paper, we solve three boundary value problems related to the temperature field in oil strata — the fractional extensions of the incomplete lumped formulation and lumped formulation in the linear case and the fractional generalization of the incomplete lumped formulation in the radial case. By using the Caputo differintegral operator and the Laplace transform, the solutions are obtained in integral forms where the integrand is expressed in terms of the convolution of some auxiliary functions of Wright function type. A generalization of the Laplace transform convolution theorem, known as Efros’ theorem is widely used.  相似文献   
994.
We examine the resource allocation problem of partitioning identical servers into two parallel pooling centers, and simultaneously assigning job types to pooling centers. Each job type has a distinct Poisson arrival rate and a distinct holding cost per unit time. Each pooling center becomes a queueing system with an exponential service time distribution. The goal is to minimize the total holding cost. The problem is shown to be polynomial if a job type can be divided between the pooling centers, and NP-hard if dividing job types is not possible. When there are two servers and jobs cannot be divided, we demonstrate that the two pooling center configuration is rarely optimal. A heuristic which checks the single pooling center has an upper bound on the relative error of 4/3. The heuristic is extended for the multiple server problem, where relative error is bounded above by the number of servers.   相似文献   
995.
Prior studies have shown that inventories in a one vendor, multi-buyer supply chain with deterministic demands can be coordinated effectively through the use of common replenishment epochs (CRE). In this paper, we study the impact of demand uncertainty on the effectiveness of coordinating such a supply chain. We develop a model to analyse the coordination mechanism using CRE in a one-vendor, multi-buyer supply chain, when the demand faced by the buyers is stochastic. Our numerical study based on the model found that coordination through CRE may not always be beneficial when the demand variance is high. We also investigate a strategy of advance order processing by the vendor to improve the effectiveness of coordination through CRE.  相似文献   
996.
997.
The essential first step of any OR investigation is to ensure that the ‘right problem’ is studied. Our approach is to propose a set of six ‘rights’ or questions whereby achievement against particular aspects of a problem space is made and these provide the basis for scoping the context, understanding the system, and proposing sound options to the decision-maker. This style of problem structuring is an essential element of the Defence problem domain, and especially so for the Land Force, where there exist multiple degrees of freedom for poorly defined problems in an environment of uncertainty and ambiguity. Central to this is performing conceptual rather than analytical modelling, as perturbations then provide a basis for exploring a space, rather than solving a problem.  相似文献   
998.
Five novel fluorene‐containing polymers, poly[(9,9‐dimethylfluoren‐2‐yl)acetylene] ( PFA1 ), poly[(1‐pentyl‐2‐(9,9‐dimethylfluoren‐2‐yl)acetylene) ( PFA2 ), poly[1‐decyl‐2‐(9,9‐dimethylfluoren‐2‐yl)acetylene] ( PFA3 ), poly[1‐phenyl‐2‐(9,9‐dimethylfluoren‐2‐yl)acetylene] ( PFA4 ), and poly[1‐(3,4‐difluorophenyl)‐2‐(9,9‐dimethylfluoren‐2‐yl)acetylene] ( PFA5 ) were synthesized by the polymerization of the corresponding fluorene‐substituted acetylenic monomers ( M1–M5), using WCl6, MoCl5, and TaCl5 as catalysts and n‐Bu4Sn as a cocatalyst. The synthesized polymers were thermally stable and readily soluble in common organic solvents. The degradation temperatures for a 5% weight loss of the polymers were ∼352–503 °C under nitrogen. PFA1–PFA5 show emission peaks from 402 to 590 nm. Besides, their electroluminescent properties were studied in heterostructure light‐emitting diodes (LEDs), using PFA2–PFA5 as an emitting layer. The PFA5 device revealed an orange‐red emission peak at 602 nm with a maximum luminescence of 923 cd/m2 at 8 V. A device with the ITO/PEDOT/ a mixture of PFA2 (98 wt %) and PFA5 (2 wt %)/Ca/Al showed near white emission. Its maximum luminance and current efficiency are 450 cd/m2 at 15 V and 1.3 cd/A, respectively. © 2005 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 44: 519–531, 2006  相似文献   
999.
A new class of thermosetting poly(2,6‐dimethyl‐1,4‐phenylene oxide)s containing pendant epoxide groups were synthesized and characterized. These new epoxy polymers were prepared through the bromination of poly(2,6‐dimethyl‐1,4‐phenylene oxide) in halogenated aromatic hydrocarbons followed by a Wittig reaction to yield vinyl‐substituted polymer derivatives. The treatment of the vinyl‐substituted polymers with m‐chloroperbenzoic acid led to the formation of epoxidized poly(2,6‐dimethyl‐1,4‐phenylene oxide) with variable pendant ratios, and the structures and properties were studied with nuclear magnetic resonance spectroscopy, Fourier transform infrared spectroscopy, differential scanning calorimetry, thermogravimetric analysis, and gel permeation chromatography. The ratios of pendant functional groups were tailored for the polymer properties, and the results showed that the glass‐transition temperatures increased as the benzylic protons were replaced by bromo‐, vinyl‐, or epoxide‐functional groups, whereas the thermal stability decreased in comparison with the original polymer. Within a molar fraction of 20–50%, the degree of functionalization had little effect on the glass‐transition temperature; however, it correlated inversely with the thermal stability of each functionalized polymer. The thermal curing behavior of the epoxide‐functionalized polymer was enhanced by the increment of the pendant functionality, which resulted in a significant increase in the glass‐transition temperature as well as the thermal stability after the curing reaction. © 2006 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 44: 5875–5886, 2006  相似文献   
1000.
A novel cyclic ether monomer 3‐{2‐[2‐(2‐hydroxyethoxy)ethoxy]ethoxy‐methyl}‐3′‐methyloxetane (HEMO) was prepared from the reaction of 3‐hydroxymethyl‐3′‐methyloxetane tosylate with triethylene glycol. The corresponding hyperbranched polyether (PHEMO) was synthesized using BF3·Et2O as initiator through cationic ring‐opening polymerization. The evidence from 1H and 13C NMR analyses revealed that the hyperbranched structure is constructed by the competition between two chain propagation mechanisms, i.e. active chain end and activated monomer mechanism. The terminal structure of PHEMO with a cyclic fragment was definitely detected by MALDI‐TOF measurement. A DSC test implied that the resulting polyether has excellent segment motion performance potentially beneficial for the ion transport of polymer electrolytes. Moreover, a TGA assay showed that this hyperbranched polymer possesses high thermostability as compared to its liquid counterpart. The ion conductivity was measured to reach 5.6 × 10?5 S/cm at room temperature and 6.3 × 10?4 S/cm at 80 °C after doped with LiTFSI at a ratio of Li:O = 0.05, presenting the promise to meet the practical requirement of lithium ion batteries for polymer electrolytes. © 2006 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 44: 3650–3665, 2006  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号