全文获取类型
收费全文 | 147篇 |
免费 | 1篇 |
专业分类
化学 | 105篇 |
晶体学 | 3篇 |
力学 | 6篇 |
数学 | 17篇 |
物理学 | 17篇 |
出版年
2022年 | 3篇 |
2021年 | 1篇 |
2020年 | 1篇 |
2019年 | 2篇 |
2015年 | 1篇 |
2014年 | 1篇 |
2013年 | 5篇 |
2012年 | 3篇 |
2011年 | 5篇 |
2010年 | 5篇 |
2009年 | 4篇 |
2008年 | 7篇 |
2007年 | 7篇 |
2006年 | 9篇 |
2005年 | 5篇 |
2004年 | 1篇 |
2003年 | 4篇 |
2002年 | 2篇 |
2001年 | 6篇 |
2000年 | 8篇 |
1999年 | 1篇 |
1998年 | 3篇 |
1997年 | 3篇 |
1996年 | 3篇 |
1995年 | 1篇 |
1993年 | 2篇 |
1992年 | 1篇 |
1991年 | 2篇 |
1990年 | 2篇 |
1989年 | 3篇 |
1988年 | 4篇 |
1987年 | 2篇 |
1986年 | 3篇 |
1985年 | 5篇 |
1984年 | 3篇 |
1982年 | 3篇 |
1981年 | 3篇 |
1980年 | 2篇 |
1979年 | 3篇 |
1977年 | 2篇 |
1976年 | 1篇 |
1975年 | 2篇 |
1974年 | 2篇 |
1973年 | 5篇 |
1972年 | 1篇 |
1971年 | 1篇 |
1969年 | 2篇 |
1966年 | 1篇 |
1964年 | 1篇 |
1899年 | 1篇 |
排序方式: 共有148条查询结果,搜索用时 15 毫秒
141.
Complete probabilistic metric spaces 总被引:10,自引:0,他引:10
H. Sherwood 《Probability Theory and Related Fields》1971,20(2):117-128
142.
143.
144.
The crystal growth and perfection of 2,4,6-trinitrotoluene 总被引:1,自引:0,他引:1
Large crystals of TNT were grown from ethyl acetate solution by both temperature lowering and solvent evaporation. The perfection of crystals grown from seeds under carefully controlled conditions was generally higher than those prepared by uncontrolled solvent evaporation. Examination by X-ray topography revealed the crystals to have a characteristic growth induced defect structure comprising growth sectors and boundaries, growth banding, solvent inclusions and dislocations. Twins and stacking faults (SF) were also observed. Many of the defects noted in the topographs can be attributed to impurities. The influence of the highly anisotropic crystal structure on the nature of growth defects is discussed. A structural model proposed to explain twinning and SF formation is partially supported by topographic evidence. 相似文献
145.
We show that the performance of a streaming-potential based microfluidic energy conversion system can be strongly enhanced by the use of two phase flow. Injection of gas bubbles into a liquid-filled channel increases both the maximum output power and the energy conversion efficiency. In single-phase systems the internal conduction current induced by the streaming potential limits the output power, whereas in a two-phase system the bubbles reduce this current and increase the power. In our system the addition of bubbles enhanced the maximum output power of the system by a factor of 74 and the efficiency of the system by a factor of 163 compared with single phase flow. 相似文献
146.
D.B. Haidvogel H. Arango W.P. Budgell B.D. Cornuelle E. Curchitser E. Di Lorenzo K. Fennel W.R. Geyer A.J. Hermann L. Lanerolle J. Levin J.C. McWilliams A.J. Miller A.M. Moore T.M. Powell A.F. Shchepetkin C.R. Sherwood R.P. Signell J.C. Warner J. Wilkin 《Journal of computational physics》2008,227(7):3595-3624
Systematic improvements in algorithmic design of regional ocean circulation models have led to significant enhancement in simulation ability across a wide range of space/time scales and marine system types. As an example, we briefly review the Regional Ocean Modeling System, a member of a general class of three-dimensional, free-surface, terrain-following numerical models. Noteworthy characteristics of the ROMS computational kernel include: consistent temporal averaging of the barotropic mode to guarantee both exact conservation and constancy preservation properties for tracers; redefined barotropic pressure-gradient terms to account for local variations in the density field; vertical interpolation performed using conservative parabolic splines; and higher-order, quasi-monotone advection algorithms. Examples of quantitative skill assessment are shown for a tidally driven estuary, an ice-covered high-latitude sea, a wind- and buoyancy-forced continental shelf, and a mid-latitude ocean basin. The combination of moderate-order spatial approximations, enhanced conservation properties, and quasi-monotone advection produces both more robust and accurate, and less diffusive, solutions than those produced in earlier terrain-following ocean models. Together with advanced methods of data assimilation and novel observing system technologies, these capabilities constitute the necessary ingredients for multi-purpose regional ocean prediction systems. 相似文献
147.
Daniel M. Day Thomas J. Farmer Joe Granelli Janice H. Lofthouse Julie Lynch Con R. McElroy James Sherwood Seishi Shimizu James H. Clark 《Molecules (Basel, Switzerland)》2022,27(23)
Green chemistry places an emphasis on safer chemicals, waste reduction, and efficiency. Processes should be optimized with green chemistry at the forefront of decision making, embedded into research at the earliest stage. To assist in this endeavor, we present a spreadsheet that can be used to interpret reaction kinetics via Variable Time Normalization Analysis (VTNA), understand solvent effects with linear solvation energy relationships (LSER), and calculate solvent greenness. With this information, new reaction conditions can be explored in silico, calculating product conversions and green chemistry metrics prior to experiments. The application of this tool was validated with literature case studies. Reaction performance was predicted and then confirmed experimentally for examples of aza-Michael addition, Michael addition, and an amidation. The combined analytical package presented herein permits a thorough examination of chemical reactions, so that the variables that control reaction chemistry can be understood, optimized, and made greener for research and education purposes. 相似文献
148.
Claudius Lenz Sebastian Dörner Dr. Alexander Sherwood Prof. Dr. Dirk Hoffmeister 《Chemistry (Weinheim an der Bergstrasse, Germany)》2021,27(47):12166-12171
Psilocin ( 1 ) is the dephosphorylated and psychotropic metabolite of the mushroom natural product psilocybin. Oxidation of the phenolic hydroxy group at the C-4 position of 1 results in formation of oligomeric indoloquinoid chromophores responsible for the iconic blueing of bruised psilocybin-producing mushrooms. Based on previous NMR experiments, the hypothesis included that the 5,5’-coupled quinone dimer of 1 was the primary product responsible for the blue color. To test this hypothesis, ring-methylated 1 derivatives were synthesized to provide stable analogs of 1 dimers that could be completely characterized. The chemically oxidized derivatives were spectroscopically analyzed and compared to computationally derived absorbance spectra. Experimental evidence did not support the original hypothesis. Rather, the blue color was shown to stem from the quinoid 7,7’-coupled dimer of 1 . 相似文献