Nanostructured microspheres of MnO2 formed by room temperature solution processing

Nanostructured microspheres of manganese oxide have been prepared by the solution processing ofmanganese(II) salts using 1,4,7,10-tetraazacyclododecane and utilizing a crystalline intermediate stage.     

Mechanism of signal uncertainty generation for laser-induced breakdown spectroscopy

Relatively large measurement uncertainty severely hindered wide application for laser-induced breakdown spectroscopy (LIBS), therefore it is of great importance to understand the mechanism of signal uncertainty generation, including initiation and propagation. It has been found that the fluctuation of plasma morphology was the main reason for signal uncertainty. However, it still remains unclear what mechanism leads to laser-induced plasma morphology fluctuation. In the present work, we employed three fast-imaging cameras to capture three successive plasma images from a same laser-induced Titanium alloy plasma, which enables us to understand more clearly of the plasma evolution process especially for the early plasma evolution stage when plasma and surrounding gases interact drastically. Seen from the images, the plasma experienced an increasing morphological fluctuation as delay time increased, transforming from a “stable plasma” before the delay time of 100 ns to a “fluctuating plasma” after the delay time of 300 ns. Notably, the frontier part of plasma showed a significant downward motion from the delay time of 150 ns to 200 ns and crashed with the lower part of the plasma, making the plasma flatter and later even splitting the plasma into two parts, which was considered as a critical process for the transformation of “stable plasma” to “unstable plasma”. By calculating the correlation coefficient of plasma image pairs at successive delay times, it was found that the higher the similarity between two plasma at early stage, the more similar at later stage; this implied that the tiny plasma fluctuation earlier than the critical delay time (150–200 ns) was amplified, causing a large plasma fluctuation at the later stage as well as LIBS measurement uncertainty. The initiation of slight fluctuation was linked with Rayleigh–Taylor Instability (RTI) due to the drastic material interpenetration at the plasma-ambient gas interface at earlier stage (before 50 ns). That is, the uncertainty generation of LIBS was proposed as: plasma morphology fluctuation was inevitably trigged by RTI at the early stage and the tiny fluctuation was amplified by the back pressed downward process of plasma frontier material, leading to severe morphology fluctuation as well as LIBS signal uncertainty.     

Iron Oxide Nanoparticles Embedded onto 3D Mesochannels of KIT‐6 with Different Pore Diameters and Their Excellent Magnetic Properties

Here, we report the results of our detailed study on the fabrication of iron oxide magnetic nanoparticles confined in mesoporous silica KIT‐6 with a 3D structure and large, tunable pore diameters. It was confirmed by XRD, nitrogen adsorption, high‐resolution (HR) TEM, and magnetic measurements that highly dispersed iron oxide nanoparticles are occupied inside the mesochannels of KIT‐6. We also demonstrated that the size of the iron oxide nanoparticle can be controlled by simply changing the pore diameter of the KIT‐6 and the weight percentage of the iron oxide nanoparticles. The effect of the weight percentage and size of the iron oxide nanoparticles, and the textural parameters of the support on the magnetic properties of iron oxide/KIT‐6 has been demonstrated. The magnetization increases with decreasing iron content in the pore channels of KIT‐6, whereas coercivity decreases for the same samples. Among the KIT‐6 materials studied, KIT‐6 with 7.5 wt % of iron showed the highest saturation magnetic moment and magnetic remanence. However, all the samples register a coercivity of around 2000 Oe, which is generally observed for the hard magnetic materials. In addition, we have found a paramagnetic‐to‐superparamagnetic transition at low temperature for samples with different iron content at low temperature. The cause for this exciting transition is also discussed in detail. Magnetic properties of the iron oxide loaded KIT‐6 were also compared with pure iron oxide and iron oxide loaded over SBA‐15. It was found that iron oxide loaded KIT‐6 showed the highest magnetization due to its 3D structure and large pore volume. The pore diameter of the iron oxide loaded KIT‐6 support also plays a critical role in controlling the magnetization and the blocking temperature, which has a direct relation to the particle diameter and increases from 48 to 63 K with an increase in the pore diameter of the support from 8 to 11.3 nm.     

Simulation of peristaltic flow of chyme in small intestine for couple stress fluid

In this article couple stress fluid have been considered for the peristaltic flow of chyme in intestine. Problem under consideration have been formulated assuming that two non-periodic sinusoidal wave of different wavelength propagate with same speed c along the outer wall of the tube. Governing equations have been simplified under the assumptions of long wavelength and low Reynolds number approximation (such assumption are consistent that Re (Reynold number) is very small and long wavelength approximation also exists in the small intestine). Exact solutions have been evaluated for velocity and pressure rise. Physical behaviour of different parameter of couple stress fluid have been presented graphically for velocity, pressure rise, pressure gradient and frictional forces. The stream lines are also made against different parameters.     

Peristaltic flow of a nanofluid in a non-uniform tube

The present analysis discusses the peristaltic flow of a nanofluid in a diverging tube. This is the first article on the peristaltic flow in nanofluids. The governing equations for nanofluid are modelled in cylindrical coordinates system. The flow is investigated in a wave frame of reference moving with velocity of the wave c. Temperature and nanoparticle equations are coupled so Homotopy perturbation method is used to calculate the solutions of temperature and nanoparticle equations, while exact solutions have been calculated for velocity profile and pressure gradient. The solution depends on Brownian motion number N _b , thermophoresis number N _t , local temperature Grashof number B _r and local nanoparticle Grashof number G _r . The effects of various emerging parameters are investigated for five different peristaltic waves. It is observed that the pressure rise decreases with the increase in thermophoresis number N _t . Increase in the Brownian motion parameter N _b and the thermophoresis parameter N _t temperature profile increases. Streamlines have been plotted at the end of the article.     

Toward a theory of the double plasma resonance in the solar corona

Specific features of the double plasma resonance effect in a magnetized plasma of the solar corona are discussed. The effect consists in enhanced generation of plasma waves in the regions where the upper hybrid frequency coincides with electron gyrofrequency harmonics. It is widely used for interpretation of a fine structure in solar radio emission spectrum in the form of parallel drifting quasi-harmonic stripes of enhanced radiation intensity (zebra pattern). It is shown that the plasma-wave growth rate increases due to both dispersion properties of plasma waves, which are determined by the equilibrium plasma component, and electrons which are non-equilibrium with respect to the velocities transverse to the magnetic field. Special attention is given to an incorrect consideration of the double plasma resonance effect in some papers. Translated from Izvestiya Vysshikh Uchebnykh Zavedenii, Radiofizika, Vol. 52, No. 2, pp. 95–108, February 2009.     

Physiological Transportation of Casson Fluid in a Plumb Duct

This paper is devoted to a study of the peristaltic motion of a Casson fluid of a non-Newtonian fluid accompanied in a horizontai tube.To characterize the non-Newtonian fluid behavior,we have considered the Casson fluid model.Suitable similarity transformations are utilized to transform the governing partial differential momentum into the non-linear ordinary differential equations.Exact analytical solutions of these equations are obtained and are the properties of velocity,pressure and profiles are then studied graphically.     

Peristaltic flow of Sisko fluid in a uniform inclined tube

We have analyzed an incompressible Sisko fluid through an axisymmetric uniform tube with a sinusoidal wave propagating down its walls. The present analysis of non- Newtonian fluid is investigated under the considerations of long wavelength and low Reynolds number approximation. The analytic solution is obtained using （i） the regular perturbation method （ii） the Homotopy analysis method （HAM）. The comparison of both the solutions is presented graphically. The results for the pressure rise, frictional force and pressure gradient have been calculated numerically and the results are studied for various values of the physical parameters of interest, such as α （angle of inclination）, b^＊ （Sisko fluid parameter）, Ф （amplitude ratio） and n （power law index）. Trapping phenomena is discussed at the end of the article.