Synthesis and electrochemical properties of P2-Na<Subscript>2/3</Subscript>Ni<Subscript>1/3</Subscript>Mn<Subscript>2/3</Subscript>O<Subscript>2</Subscript>

The pure phase P2-Na_2/3Ni_1/3Mn_2/3O₂ was synthesized by a solid reaction process. The optimum calcination temperature was 850 °C. The as-prepared product delivered a capacity of 158 mAh g^?1 in the voltage range of 2–4.5 V, and there was a phase transition from P2 to O2 at about 4.2 V in the charge process. The P2 phase exhibited excellent intercalation behavior of Na ions. The reversible capacity is about 88.5 mAh g^?1 at 0.1 C in the voltage range of 2–4 V at room temperature. At an elevated temperature of 55 °C, it could remain as an excellent capacity retention at low current rates. The P2-Na_2/3Ni_1/3Mn_2/3O₂ is a potential cathode material for sodium-ion batteries.     

谷值V~2控制Boost变换器的精确建模与动力学分析

建立了谷值V2控制Boost变换器的离散迭代映射模型,在此基础上得到了输入电压、输出电容及其等效串联电阻(equivalent series resistance,ESR)变化时的分岔图,推导了不动点处的雅可比矩阵,利用特征值和最大Lyapunov指数对系统进行了稳定性分析,并验证了分岔图的正确性.重点研究了输入电压和输出电容及其ESR对谷值V2控制Boost变换器的动力学特性的影响.研究结果表明,输入电压增大时,变换器从周期1态经历1次倍周期分岔和边界碰撞分岔进入混沌状态;输出电容及其ESR具有相同的分岔路由,随着输出电容及其ESR的逐渐减小,变换器具有从周期1态经历周期2态、周期4态、周期8态、逐渐演变到混沌态的动力学行为.最后,用仿真和实验结果验证了本文理论分析的正确性.     

物理隔离网络电磁漏洞研究

物理隔离网络的电磁攻击手段, 其主要目标是建立与外部互联网的隐蔽连接通道。近年来跨越物理隔离网络的方法和工具被陆续公开, 相应的分析方法和检测手段也逐步被国内外安全团队提出。掌握漏洞才能掌握网络安全的主动权, 对比网络安全漏洞, 电磁漏洞定义为能对设备或系统造成损害的电磁因素。以物理隔离网络为例, 电磁漏洞主要指的是网络的硬件和系统缺陷, 利用这些缺陷可以直接建立或通过植入恶意软件建立能突破物理隔离的电磁信号的信息收、发隐蔽通道。通过广泛的漏洞挖掘与验证, 从物理信号类型、信息传递方向、信号生成与作用机理、漏洞利用方式以及漏洞检测方法上提出物理隔离网络电磁漏洞分类方法; 通过综合借鉴网络安全漏洞、电磁信息安全检测、物理隔离隐蔽通道等领域的研究方法, 提出电磁漏洞的研究方法; 从深化主动检测、群智漏洞挖掘、网络电磁安全融合、大数据监测等角度, 提出了物理隔离网络电磁漏洞库的建立方法。     

Gd替代对La0.6-xGdxSr1.4MnO4磁性和输运性质的影响

随着x的增加，多晶La0.6-xGdxSr1.4MnO4（x=0, 0.1, 0.2, 0.4, 0.6）的零场冷却 曲线从类自旋玻璃型转变成顺磁型，并且每条零场冷却 曲线都有一在20K的拐点。这一行为可以从Gd和Mn各自对材料总磁性的不同贡献来理解。另外，在所有的样品中，从100K到室温，都观察到了热激活导电行为。由于Mn-Mn间强的反铁磁耦和，直到外场达到50 kOe，都没有观察到明显的磁电阻效应。     

大面积染料敏化太阳电池的串联阻抗特性研究

在电子扩散微分方程的基础上,研究了染料敏化太阳电池光生电流和光生电压随光照强度不同的变化关系.提出敏化太阳电池串联阻抗功率损耗模型,理论模拟了大面积电池（有效面积>1 cm²）光电转换效率随多孔薄膜有效面积宽度变化的曲线、透明导电基底膜与银栅极的比接触电阻以及在不同入射光强下银栅极体电阻对大面积染料敏化太阳电池光伏性能的影响.结果表明透明导电基底膜的方块电阻和银栅极体电阻对大面积染料敏化太阳电池的性能有很大影响,而这种影响随光强的减弱逐渐减小. 关键词： 染料敏化 太阳电池 串联阻抗 光电转换效率     

Analysis of a combined mixed finite element and discontinuous Galerkin method for incompressible two‐phase flow in porous media

We analyze a combined method consisting of the mixed finite element method for pressure equation and the discontinuous Galerkin method for saturation equation for the coupled system of incompressible two‐phase flow in porous media. The existence and uniqueness of numerical solutions are established under proper conditions by using a constructive approach. Optimal error estimates in L²(H¹) for saturation and in L ^∞ (H(div)) for velocity are derived. Copyright © 2013 John Wiley & Sons, Ltd.     

Global exixtence and exponential decay estimates for a dampad quasilinear equation

We prove the existence and uniqueness of a global solution of a damped quasilineat hyperbolic equatiion. We apply a method based on a special integral inequality, to show that the solution decays exponentially, and to obtain precise estimates of the constants in estimates.     

Study of kinetics and mechanism of the acid dissociation of copper(II) complex of novel C-functionalized macrocyclic dioxotetraamines

The kinetics of the acid dissociation of copper(II) complexes of novel C-functionalized macrocyclic dioxotetraamines has been studied by means of a stopped-flow spectrophotometer. The acid dissociation rate follows the law V_d = C_comkK₁K₂H ²/(1+K₁H+K₁K₂H ²). From the experimental facts we have obtained, the dissociation kinetics are interpreted by a mechanism involving the negatively charged carbonyl oxygen of the complex being rapidly protonated in a pre-equilibrium step, the rate-determining step being intramolecular hydrogen (enolic tautomer) migration (to imine nitrogen). The dissociation rate reached a plateau in the strongly acidic solution. By means of temperature coefficient method, ΔH ^φ, ΔS ^φ of the pre-equilibrium step and ΔH ^≠, ΔS^≠ of the rate-determining step were obtained. The results of 13-membered macrocyclic dioxotetraamines have been discussed. The influence of the substituents to the acid dissociation rates has also been discussed. The Bronsted type linear free energy relationships do also exist in these C-functionalized dioxotetraamine copper(II) complexes.     

DBC-偶氮肿-锇-溴酸钾催化光度法测定微量锇

酸性介质中Os(Ⅳ)对溴酸钾氧化DBC-偶氮肿的褪色反应有明显的催化作用,据此反应建立了微量娥的催化光度分析法,锇在1.0-20.0μg·L-1符合比耳定律.反应在水相中进行,灵敏度高,简便快速,用于贵金属精矿中娥的测定,结果满意.     

氧化条件下NOx催化的甲烷均相部分氧化

考察了没有固体催化剂时NOx对甲烷气相氧化的促进作用.实验结果表明，即使在强氧化条件下（O2/CH4=5），NOx对甲烷部分氧化制一氧化碳仍然有明显的催化活性.在CH4-O2体系中加入0.005％～0.2％的NO后，反应温度可降低200-300 ℃.在反应产物中还可观察到甲醛和乙烯，通过改变反应条件可以控制它们的相对浓度.