全文获取类型
收费全文 | 644篇 |
免费 | 79篇 |
国内免费 | 58篇 |
专业分类
化学 | 463篇 |
晶体学 | 13篇 |
力学 | 36篇 |
综合类 | 5篇 |
数学 | 97篇 |
物理学 | 167篇 |
出版年
2024年 | 1篇 |
2023年 | 12篇 |
2022年 | 8篇 |
2021年 | 21篇 |
2020年 | 17篇 |
2019年 | 18篇 |
2018年 | 9篇 |
2017年 | 15篇 |
2016年 | 20篇 |
2015年 | 34篇 |
2014年 | 34篇 |
2013年 | 43篇 |
2012年 | 46篇 |
2011年 | 57篇 |
2010年 | 41篇 |
2009年 | 38篇 |
2008年 | 37篇 |
2007年 | 32篇 |
2006年 | 26篇 |
2005年 | 38篇 |
2004年 | 28篇 |
2003年 | 27篇 |
2002年 | 14篇 |
2001年 | 15篇 |
2000年 | 12篇 |
1999年 | 12篇 |
1998年 | 11篇 |
1997年 | 11篇 |
1996年 | 11篇 |
1995年 | 20篇 |
1994年 | 11篇 |
1993年 | 9篇 |
1992年 | 14篇 |
1991年 | 4篇 |
1990年 | 6篇 |
1989年 | 4篇 |
1988年 | 1篇 |
1987年 | 3篇 |
1986年 | 3篇 |
1985年 | 2篇 |
1984年 | 1篇 |
1983年 | 1篇 |
1982年 | 3篇 |
1976年 | 2篇 |
1974年 | 4篇 |
1973年 | 1篇 |
1971年 | 1篇 |
1957年 | 2篇 |
1945年 | 1篇 |
排序方式: 共有781条查询结果,搜索用时 15 毫秒
101.
Nakata K Sakamoto M Taguchi S Yoshida N Shimazu K 《Journal of colloid and interface science》2005,288(2):634-637
The water-insoluble poly-beta-cyclodextrin (poly-CD)/Nafion composite film was easily prepared by casting a mixed solution of poly-CD and Nafion onto substrate plates. FT-IR measurements showed that the 50/50 wt% poly-CD/Nafion composite film remained stable on the glass and quartz substrates after immersion in water for more than 3 h, while a pure poly-CD film was almost completely dissolved by immersion within 1 h. The film stability was also evaluated from the amount of p-nitrophenol (p-NP) inclusion in the film, which was determined from the decrease in UV-vis absorbance of the p-NP solution into which the film was immersed. The composition dependence of the inclusion amount showed that the film was stable up to 50 wt% CD, but became less stable with further increase in the CD concentration in the film. From the isotherms for the inclusion of p-NP and 1-naphthoate (1-Naph) into the film, the inclusion (stability) constants were determined to be 3.7x10(3) M(-1) and 1.9x10(2) M(-1), respectively. These results show that the selective inclusion of CD is retained after preparation of the composite film. 相似文献
102.
103.
相干性对X光全息图分辨率的影响 总被引:4,自引:4,他引:0
分析计算了X光束的相干性对X光全息图分辨率的影响,结论是X光无透镜傅里叶变换全息术所要求的相干长度和分辨率与样品尺雨戌二次线型关系;X光同轴全息术所要求的相干长度和分辨率的平方以及样品到全息图的距离成正比。 相似文献
104.
Molecular constants of LiCl(X~1Σ~+) and elastic collisions of two ground-state Cl and Li atoms at low and ultralow temperatures
下载免费PDF全文
![点击此处可从《中国物理 B》网站下载免费的PDF全文](/ch/ext_images/free.gif)
Interaction potentials for LiCl(X 1 Σ +) are constructed by the highly accurate valence internally contracted mul-tireference configuration interaction in combination with a number of large correlation-consistent basis sets,which are used to determine the spectroscopic parameters (D 0,D e,R e,ω e,ω e χ e,B e and α e).The potentials obtained at the basis sets,i.e.,aug-cc-pV5Z-JKFI for Cl and cc-pV5Z for Li,are selected to study the elastic collision properties of Li and Cl atoms at the impact energies from 1.0×10 12 to 1.0×10 4 a.u.The derived total elastic cross sections are very large and almost constant at ultralow temperatures,and their shapes are mainly dominated by the s-partial wave at very low impact energies.Only one shape resonance can be found in the total elastic cross sections over the present collision energy regime,which is rather strong and obviously broadened by the overlap contributions of the abundant resonances coming from various partial waves.Abundant resonances exist for the elastic partial-wave cross sections until l=22 partial waves.The vibrational manifolds of the LiCl(X 1 Σ +) molecule,which are predicted at the present level of theory and the basis sets cc-pV5Z for Li and the aug-cc-pV5Z-JKFI for Cl,should achieve much high accuracy due to the employment of the large correlation-consistent basis sets. 相似文献
105.
We discuss on invariant subspaces of H2(Γ2) on which . 相似文献
106.
Helena ?těpánková Karel Kou?il Vojtěch Chlan Peter G?rnert Robert Müller Josef ?těpánek 《Journal of magnetism and magnetic materials》2010,322(9-12):1323-1326
57Fe nuclear magnetic resonance (NMR) spectra of hexaferrite BaFe12O19 powder samples prepared by glass crystallization method were measured at 4.2 K and analyzed in comparison to spectra of single crystals. Samples with various mean particle dimensions were tested. NMR spectral lines corresponding to individual iron sublattices showed pronounced frequency shifts of their positions and a significant line broadening compared to single crystals. The significant contribution to the line shifts and line shape had a uniform macroscopic origin giving identical absolute value of shifts and the same line shapes for all measured lines of a particular sample. Estimations of demagnetization fields based on mean particle dimensions reasonably corresponded to the observed frequency shifts for particle mean diameter 67 nm, or had a higher value for a sample with mean diameter of 340 nm, for which a presence of domain walls was detected by NMR. In the spectrum of a sample with the smallest particles (~16 nm), an additional contribution having broader lines and faster spin-spin relaxations was found. It could be assigned to weaker exchange interactions or deviations of magnetic moment directions from the hexagonal axis in a surface layer. 相似文献
107.
5种丹参主要成分及微结构的检测及综合表征 总被引:1,自引:0,他引:1
利用X射线荧光(XRF)、粉末X射线衍射(PXRD)和傅里叶变换红外光谱(FTIR)分析技术,对安国栽培的5个不同种质丹参主要成分及微结构检测,对各样品中多种元素种类及含量、晶体及非晶体成分以一套综合特征图的方式对其表征;该谱将同种属不同种质丹参中的共有成分和细微差异之处给与直观地描述。3种技术共有制样简单,测定速度快,再现性和客观性好的特点;可用于药材优良品种的选育、中药材GAP种植条件的指导、药材产地特征、主要成分及微结构的检测及表征、质量稳定性的控制及真伪鉴别。 相似文献
108.
Yonghui Xi Huicheng Wang Kit Ian Kou Zhaoping Hu 《Journal of Applied Analysis & Computation》2016,6(3):893-906
The main purpose of this article is to study the periodicity of a Lotka-Volterra''s competition system with feedback controls. Some new and interesting sufficient conditions are obtained for the global existence of positive periodic solutions. Our method is base on combining matrix''s spectral theory and inequality $|x(t)|\leq x(t_{0})+\int_{0}^{\omega }|\dot{x}(t)|{\rm d}t$. Some examples and their simulations show the feasibility of our main result. 相似文献
109.
寇吉垚 《应用数学与计算数学学报》2010,24(2):119-123
本文主要讨论了生存函数的插值问题,使用了非节点端点的三次样条插值和α-power插值两种方法对生存函数进行了插值,并与传统的三种插值假设:死亡均匀分布假设、常数死亡力假设、Balducci假设做了比较.另外,我们对α-power插值中的α进行了拟合,并通过误差分析表明先对α拟合后再进行α-power插值,其插值的误差将会变得非常小,几乎与样条插值相仿. 相似文献
110.
Uchiyama M Ozawa H Takuma K Matsumoto Y Yonehara M Hiroya K Sakamoto T 《Organic letters》2006,8(24):5517-5520
We systematically investigated, for the first time, the relationship between regioselectivity and acid/base effects in the cyclization reactions between carboxylic acids and carbon-carbon triple bonds. We found novel acid- and base-promoted cyclizations to selectively give isocoumarin or pyran-2(2H)-one and phthalide or furan-2(5H)-one skeletons, respectively, and established a catalytic version of regioselective heterocyclic ring synthesis. Density functional theory calculations and application to a short route to thunberginol A were also described. [reaction: see text]. 相似文献