全文获取类型
收费全文 | 6556篇 |
免费 | 1081篇 |
国内免费 | 1122篇 |
专业分类
化学 | 5492篇 |
晶体学 | 62篇 |
力学 | 290篇 |
综合类 | 81篇 |
数学 | 805篇 |
物理学 | 2029篇 |
出版年
2024年 | 24篇 |
2023年 | 112篇 |
2022年 | 144篇 |
2021年 | 165篇 |
2020年 | 236篇 |
2019年 | 278篇 |
2018年 | 237篇 |
2017年 | 175篇 |
2016年 | 293篇 |
2015年 | 344篇 |
2014年 | 367篇 |
2013年 | 504篇 |
2012年 | 548篇 |
2011年 | 524篇 |
2010年 | 436篇 |
2009年 | 429篇 |
2008年 | 450篇 |
2007年 | 415篇 |
2006年 | 397篇 |
2005年 | 340篇 |
2004年 | 329篇 |
2003年 | 310篇 |
2002年 | 357篇 |
2001年 | 230篇 |
2000年 | 194篇 |
1999年 | 194篇 |
1998年 | 129篇 |
1997年 | 105篇 |
1996年 | 77篇 |
1995年 | 63篇 |
1994年 | 63篇 |
1993年 | 36篇 |
1992年 | 37篇 |
1991年 | 43篇 |
1990年 | 30篇 |
1989年 | 22篇 |
1988年 | 18篇 |
1987年 | 14篇 |
1986年 | 19篇 |
1985年 | 20篇 |
1984年 | 9篇 |
1983年 | 8篇 |
1982年 | 7篇 |
1981年 | 4篇 |
1979年 | 4篇 |
1975年 | 2篇 |
1974年 | 2篇 |
1971年 | 2篇 |
1968年 | 3篇 |
1936年 | 2篇 |
排序方式: 共有8759条查询结果,搜索用时 15 毫秒
91.
A detailed singlet potential energy surface(PES) of [Si,C,O,O] system including a van der Waals (vdW) comples SiO……CO2,eight isomers,and twelve transiton states is investigated by MP2 and QCISD(T) (single-point)methods.At the final QCISD(T)/6-311 G(2df)//MP2/6-311G(d) level with zero-point energy included,the complex SiO……CO is found to be thermodynamically and kinetically the most stable species.Although eight ismoers are located as local energy minima,they are rather unstable toward isomerization to the dissociation fragments or comples.For the reaction of silocon atoms with carbon dioxide,two competitive reaction channels are found,and the primary pathway,which leads to the products of SiO and CO fragments,is the direct oxygen-abstraction process from carbon dioxide by silicon atom with a41.16 kJ/mol reaction barrier height.Our predications are in good agreement with previous experimental and theoretical studies. 相似文献
92.
For the first time the isomerization of 1,3,2-diazaphospholidine-2-sclenide dervatives in refluxing benzene in the presence of trace water was observed. The structures of isomerized products were determined by IR, ^1H NMR,^31P NMR, elemental analysis and X-ray crystallography. The mechanism of isomerization was also proposed. 相似文献
93.
应用 Jobin-Yvon U—1000型拉曼光谱仪和LABRAMI型拉曼光谱系统研究了 3种卟啉TOHPP、TamPP和TSPP在化学还原沉积法制备的银膜上的RS和SERS光谱特征。结果表明:化学还原法制备的银膜可以作为这几种卟啉的拉曼增强活性载体。这3种卟啉在获谱的过程中都形成二聚态化合物和发生银离子搀和作用,较长的放置和测谱时间有利于银离子的搀和。 相似文献
94.
The reductive alkylation of amine with carbonyl compounds usingsodium hydrogen telluride has been investigated in recent years.Application of this method to the synthesis of N-alkyl derivativesof biologically important amino acids and their esters is described. 相似文献
95.
96.
Zhong Jie ZOU Yue Sheng DONG Jun Shan YANG 《中国化学快报》2005,16(11):1484-1486
A new β-carboline alkaloid, 4-(9H-β-carbolin-1-yl)-4-oxobutyric acid and a new derivate of isoferulic acid, (E)-3-(3-hydroxy-4-methoxyphenyl)acrylic acid carboxymethyl ester, were isolated from the roots of Anemone altaica. Their structures were determined on the basis of spectral data. 相似文献
97.
A quantitative theory of plate number N in capillary electrophoresis was developed for buffers containing neutral cyclodextrins (CDs) capable of forming inclusion complexes. In the theory, N was modeled by longitudinal diffusion, injection extent, width of the detection window, and the detector time constant. The apparent mobility was modeled as a weighted sum of the mobilities of the free-solution analyte and the inclusion complex. The apparent diffusion coefficient was modeled as a similarly weighted sum. Both the apparent mobility and diffusion coefficient were corrected by functions that compensated for increases of buffer temperature caused by Joule heat. The experimental N's and apparent mobilities of neutral thiourea and of the anions, dansyl D- and L-leucine, dansyl D- and L-aspartic acid, benzoate, and 4-nitrophenolate, were determined in buffers containing from 0 to 15 mM beta-CD. The binding constants, and mobilities and diffusion coefficients of the free-solution analyte and inclusion complex, were calculated as regression coefficients by fitting theory to these determinations. The regression coefficients were shown to have physicochemical meaning, as assessed by literature values, independent measurements, and theoretical predictions. The assessment showed the Nernst-Einstein equation does not relate mobilities and diffusion coefficients at the electrolyte concentration used. The interdependence of mobilities, diffusion coefficients, binding constants, and other dispersion sources was interpreted to evaluate the factors affecting the variation of N with CD concentration. From the interpretation, an approximate equation for N in low-concentration CD buffers was derived. The equation depends on free-solution and inclusion-complex mobilities and diffusion coefficients, the binding constant, the potential difference over the effective capillary length, and the number of plates in a CD-free buffer. 相似文献
98.
Thecurrentsurgeofinterestinthefield0fnon-linearoptics(NL0)isderivedbothfromaquestforafundamentalunderstanding0fthenon-linearprocess,anditSimPortanceinthetechn0logyofphotonics.Amongnon-linearphen0mena,thethird-ordernon-linearophcsoccuPyanimPortantp0sihonbecauseitprovidesthemechanicsforophcalswitching,ophcallogic,andreal-hmeholograPhy"'.0rganicmaterialwithextendednconjugahonsandlargeRdelocalizahonsarewellknownastheimPortantmaterialsofachievinglargethird-ordernonlinearihes3.ForexamPle,thiosen… 相似文献
99.
酶联免疫吸附法直接测定血清雌二醇 总被引:20,自引:0,他引:20
本合成了3种不同载体蛋白的雌二醇抗原,研究了载体蛋白免疫原性对雌二醇抗体产生的影响。应用酶联免疫吸附分析法测定了血清中雌二醇,浓度范围为5-160ng/ml(1.8×10^-^8-5.9×10^-^7mol/L).RSD%小于10.%,检测限为1.97ng/ml,相当于98.5pg/孔(按空白平均值的二倍标准偏差计算)。另外,本还建立了一种用考马斯亮蓝G-250测定半抗原与蛋白结合比的方法,提 相似文献
100.
富勒烯四甲氧基衍生物的合成与表征甘良兵,周胜,姜剑峰,黄春辉(北京大学化学与分子工程学院,北京,100871)武轶,吕木坚,潘景歧(北京微量化学研究所)(北京大学分析测试中心)关键词C_60衍生物,甲氧基,四氮杂环十二烷富勒烯化学是目前人们研究的热门... 相似文献