首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   56439篇
  免费   13449篇
  国内免费   4560篇
化学   55929篇
晶体学   539篇
力学   1799篇
综合类   204篇
数学   4540篇
物理学   11437篇
  2024年   100篇
  2023年   521篇
  2022年   804篇
  2021年   1009篇
  2020年   2120篇
  2019年   3370篇
  2018年   1830篇
  2017年   1376篇
  2016年   4357篇
  2015年   4539篇
  2014年   4635篇
  2013年   5575篇
  2012年   4853篇
  2011年   3965篇
  2010年   4131篇
  2009年   4028篇
  2008年   3653篇
  2007年   2990篇
  2006年   2618篇
  2005年   2659篇
  2004年   2227篇
  2003年   2008篇
  2002年   2799篇
  2001年   1980篇
  2000年   1776篇
  1999年   961篇
  1998年   529篇
  1997年   470篇
  1996年   412篇
  1995年   345篇
  1994年   296篇
  1993年   238篇
  1992年   208篇
  1991年   188篇
  1990年   201篇
  1989年   142篇
  1988年   97篇
  1987年   70篇
  1986年   82篇
  1985年   87篇
  1984年   40篇
  1983年   40篇
  1982年   38篇
  1981年   24篇
  1980年   12篇
  1979年   6篇
  1977年   5篇
  1968年   3篇
  1930年   2篇
  1916年   3篇
排序方式: 共有10000条查询结果,搜索用时 312 毫秒
91.
A graph G is N2locally connected if for every vertex ν in G, the edges not incident with ν but having at least one end adjacent to ν in G induce a connected graph. In 1990, Ryjá?ek conjectured that every 3‐connected N2‐locally connected claw‐free graph is Hamiltonian. This conjecture is proved in this note. © 2004 Wiley Periodicals, Inc. J Graph Theory 48: 142–146, 2005  相似文献   
92.
This work is concerned with Pontryagin's maximum principle of optimal control problems governed by some non-well-posed semilinear heat equations. A type of approach to the non-well-posed optimal control problem is given.  相似文献   
93.
In the title compound, catena‐poly[lithium‐μ3‐ethyl­ene­diphos­phon­ato], [Li(C2H7O6P2)]n, the supra­molecular monoclinic (C2/c) structure consists of one‐dimensional lithium chains [Li⋯Li = 2.7036 (8) Å] that are embedded within ethyl­ene­diphosphon­ate anions linked by strong symmetric hydrogen bonds [O⋯O = 2.473 (3) Å]. The Li atoms and the H atom in the symmetric hydrogen bond reside on twofold rotation axes and there is an inversion center at the mid‐point of the C—C bond of the ethylenediphosphonate ligand.  相似文献   
94.
The inhomogeneous Dirichlet problems concerning divergence form elliptic equations are studied. Optimal regularity requirements on the coefficients and domains for the W1,p theory, 1 < p < ∞, are obtained. The principal coefficients are supposed to be in the John‐Nirenberg space with small BMO seminorms. The domain is a Reifenberg domain. These conditions for the W1,p theory not only weaken the requirements on the coefficients but also lead to a more general geometric condition on the domains. In fact, these domains might have fractal dimensions. © 2004 Wiley Periodicals, Inc.  相似文献   
95.
相对论重离子碰撞实验中混合事件方法的研究   总被引:1,自引:0,他引:1  
把RQMD(Relativistic Quantum Molecular Dynamics)产生器产生的数据输入作为原始事例取样,讨论了在比较复杂的背景情况下,一种新的混合事件方法,用以证实在相对论重离子碰撞实验中高能量激发共振态的存在.并以共振态重子Δ++为例演示了这一方法的应用.  相似文献   
96.
A new MnIII‐Schiff base complex, [MnL(OH2)](ClO4) ( 1 ) (H2L = N, N′‐bis‐(3‐Br‐5‐Cl‐salicylidene)‐1, 2‐diimino‐2‐methylethane), an inorganic model of the catalytic center (OEC, Oxygen Evolving Complex) in photosystem II (PSII), has been synthesized and characterized by elemental analysis, IR and EPR spectroscopy, mass spectrometry, magnetic susceptibility measurement and the study of its redox properties by cyclic and normal pulse voltammetry. This complex mimics reactivity (showing a relevant photolytic activity), and also some structural characteristics (parallel‐mode MnIII EPR signal from partially assembled OEC cluster) of the natural OEC. The complex 1 was found to rearrange in solution into a crystallographically solved square‐pyramidal complex, [MnLL′] ( 2 ) (HL′ = 6‐bromo‐4‐chloro‐2‐cyanophenol), through a process, which probably liberates radical species (detected by EPR), and provokes a C—N bond cleavage in the ligand. A photo‐radical mechanism is discussed to explain this rearrangement.  相似文献   
97.
模糊关系矩阵传递闭包的Warshall算法   总被引:8,自引:2,他引:6  
通过对照关系的传递闭包和模糊关系的传递闭包,把求关系矩阵的传递闭包的算法完整地推广到模糊关系矩阵上。  相似文献   
98.
The development of the poly(3‐hydroxybutyrate) (PHB) morphology in the presence of already existent poly(vinylidene fluoride) (PVDF) spherulites was studied by two‐stage solidification with two separate crystallization temperatures. PVDF formed irregular dendrites at lower temperatures and regular, banded spherulites at elevated temperatures. The transition temperature of the spherulitic morphology from dendrites to regular, banded spherulites increased with increasing PVDF content. A remarkable amount of PHB was included in the PVDF dendrites, whereas PHB was rejected into the remaining melt from the banded spherulites. When PVDF crystallized as banded spherulites, PHB could consequently crystallize only around them, if at all. In contrast, PHB crystallized with a common growth front, starting from a defined site in the interfibrillar regions of volume‐filling PVDF dendrites. It formed by itself dendritic spherulites that included a large number of PVDF spherulites. For blends with a PHB content of more than 80 wt %, for which the PVDF dendrites were not volume‐filling, PHB first formed regular spherulites. Their growth started from outside the PVDF dendrites but could later interpenetrate them, and this made their own morphology dendritic. These PHB spherulites melted stepwise because the lamellae inside the PVDF dendrites melted at a lower temperature than those from outside. This reflected the regularity of the two fractions of the lamellae because that of those inside the dendrites of PVDF was controlled by the intraspherulitic order of PVDF, whereas that from outside was only controlled by the temperature and the melt composition. The described morphologies developed without mutual nucleating efficiency of the components. © 2003 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 41: 873–882, 2003  相似文献   
99.
A lithium(I) coordination polymer has been formed from LiClO4 and the 2,2′‐bipyrimidine (bpym) ligand in which each square pyramidal lithium(I) atom is coordinated in the basal plane by four nitrogen donor atoms derived from two bpym ligands and one water molecule at the apical position. These are connected into a layer structure via hydrogen‐bonding interactions involving the perchlorate anions. Copyright © 2004 John Wiley & Sons, Ltd.  相似文献   
100.
浮栅ROM器件辐射效应机理分析   总被引:1,自引:0,他引:1       下载免费PDF全文
分析了浮栅ROM器件的辐射效应机理,合理地解释了实验中观察到的现象.指出辐射产生的电子空穴对在器件中形成的氧化物陷阱电荷和界面陷阱电荷是导致存储单元及其外围电路出现错误的原因.浮栅ROM器件的中子、质子和60Co γ辐射效应都是总剂量效应 . 关键词: FLASH ROM EEPROM 中子 质子 60Co γ')" href="#">60Co γ 总剂量效应  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号