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LaNi4M(Ni,Cu,Fe)-H2体系的量热研究 总被引:1,自引:0,他引:1
本文用量热法测定了氢在LaNi5,LaNi4Cu,LaNi4Fe中溶解的相对偏摩尔焓△HHα→β和偏摩尔自由能△GHα→β,并计算了偏摩尔熵△SHα→β。用X光衍射分析计算了LaNi5,LaNi4Cu,LaNi4Fe的晶胞体积V,发现了△HHα→β和△GHα→β)与V存在线性关系。 相似文献
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镧镍体系(LaNi5-xMx)吸氢化合物的研究(Ⅰ)——LaNi5的化学合成及吸氢性能 总被引:4,自引:0,他引:4
过渡金属氢化物因与氢能源的利用紧密有关,近年来在国际上引起极大注意。本文提出了吸氢化合物LaNi5的一种新的合成方法--共沉淀还原法,并详细研究了反应过程。 相似文献
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The binding equilibrium between l- and human serum albumin (HSA) or bovine serum albumin (BSA) has been studied by means of the resonance Rayleigh scattering (RRS) and equilibrium dialysis. It has been found for the first time that RRS and multiple frequency scattering (MFS) are enhanced as the l- binding to the HSA and BSA, but fluorescence quenches. The equilibrium dialysis results suggest that the binding of l- to HSA and BSA fits a phase-distribution model other than Scsitchard model, and that the order of magnitude of its phase-distribution constant was found to be 104. It is most probable that Cl~ or other anion ions influence the binding of P by changing the ionic strength in the solution. The dialysis at different pH indicates that the binding mechanism is due to the electrostatic forces between the T-and protonated basic amino-acid residues. 相似文献
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理科化学大一“普通化学”的改革思考 总被引:10,自引:0,他引:10
时代进入新世纪,高等学校面临新的一轮教学改革.为适应国家经济建设和科教兴国的需要,认真进行改革,需要率先回顾前50年历届教学改革的经验和教训.1952年高等学校全面学习苏联,引入了苏联教育体制和课程体制. 相似文献
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The binding equilibrium between l− and human serum albumin (HSA) or bovine serum albumin (BSA) has been studied by means of the resonance Rayleigh scattering
(RRS) and equilibrium dialysis. It has been found for the first time that RRS and multiple frequency scattering (MFS) are
enhanced as the l− binding to the HSA and BSA, but fluorescence quenches. The equilibrium dialysis results suggest that the binding of l− to HSA and BSA fits a phase-distribution model other than Scatchard model, and that the order of magnitude of its phase-distribution
constant was found to be 104. It is most probable that Cl− or other anion ions influence the binding of l− by changing the ionic strength in the solution. The dialysis at different pH indicates that the binding mechanism is due
to the electrostatic forces between the l− and protonated basic amino-acid residues. 相似文献
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碳硼烷是一类对空气、热和化学作用稳定的有机硼化合物。到目前已制得了几百个各种类型的碳硼烷衍生物,但关于其醚类衍生物则报导得很少,对称性的醚类衍生物几乎未见报导[1-4]。就合成方法而言,直接由炔化物合成1,2-二碳对称取代的碳硼烷也是少见的。我们由炔化物与双-(二乙硫醚)合十二氢癸硼烷直接合成了两个新的对称性o-碳硼烷醚类衍生物,扩展了用直接法合成o-碳硼烷衍生物的途径。 相似文献
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合成了9种新的五苯并咪唑甲基二乙三胺双铜配合物,对配合物进行了元素分析、IR、UV-vis、ESR、磁性等表征。测定了配合物的儿茶酚酶活性及生物活性。配合物的双铜间存在反铁磁相互作用,Cu—N键具部分共价性。发现该类配合物具有体外抗癌活性和农药活性。 相似文献
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