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51.
Korchevskaya E. V. Ostrovskii Yu. V. Malin A. A. Trukhanovich M. Z. Shcherbinin M. B. Ostrovskii V. A. 《Russian Journal of Organic Chemistry》2002,38(5):735-737
The reaction of 5'-O-benzoyl-2,3'-anhydrothymidine with dimethylammonium azide in the system DMF-1,4-dioxane in the temperature range from 80 to 100°C follows the overall second-order kinetics and first-order kinetics with respect to each reactant. The activation parameters in the systems containing 30, 40, and 50 vol % of dioxane are, respectively: H
298 99, 85, and 79 kJ mol-
1; S
298 -46, -83, and -101 J mol-
1 K-
1. A refined model of the transition state for the rate-determining stage was proposed, which takes into account specific interaction with 1,4-dioxane. 相似文献
52.
Korlyukov A. A. Alekseev N. V. Knyazev S. P. Chernyshev E. A. Pavlov K. V. Krivolapova O. V. Shcherbinin V. V. Antipin M. Yu. Lyssenko K. A. 《Russian Chemical Bulletin》2001,50(11):2203-2205
A general procedure was developed for the synthesis of halocyclopropylgermanes. This procedure was used for the preparation of tribromo(7-bromobicyclo[4.1.0]hept-7-yl)germane. The molecular structure was established by GLC-mass spectrometry, 1H NMR spectroscopy, and X-ray diffraction analysis. 相似文献
53.
Radiophysics and Quantum Electronics - 相似文献
54.
55.
P. V. Yurenev A. V. Shcherbinin N. F. Stepanov 《Russian Journal of Physical Chemistry A, Focus on Chemistry》2010,84(1):39-43
The nonstationary density functional theory method (time-dependent DFT, TD-DFT) was used to theoretically estimate the frequencies
and intensities of absorption bands of the complex hexaamminoruthenium(II) ion in aqueous solution. The spectrum simultaneously
contained both valence (ligand-field, LF) transitions and an intense band of charge transfer to the solvent (CTTS). A comparison
of the quality of the results obtained with the use of various exchange-correlation functionals was performed. The closest
agreement with the experimental absorption spectrum was obtained with the use of the LC-BLYP hybrid functional with exchange
potential corrections at large distances. 相似文献