全文获取类型
收费全文 | 5604篇 |
免费 | 186篇 |
国内免费 | 13篇 |
专业分类
化学 | 3379篇 |
晶体学 | 134篇 |
力学 | 174篇 |
数学 | 462篇 |
物理学 | 1654篇 |
出版年
2023年 | 46篇 |
2022年 | 125篇 |
2021年 | 129篇 |
2020年 | 142篇 |
2019年 | 150篇 |
2018年 | 134篇 |
2017年 | 180篇 |
2016年 | 226篇 |
2015年 | 166篇 |
2014年 | 223篇 |
2013年 | 447篇 |
2012年 | 340篇 |
2011年 | 354篇 |
2010年 | 235篇 |
2009年 | 206篇 |
2008年 | 287篇 |
2007年 | 242篇 |
2006年 | 181篇 |
2005年 | 166篇 |
2004年 | 134篇 |
2003年 | 118篇 |
2002年 | 115篇 |
2001年 | 65篇 |
2000年 | 60篇 |
1999年 | 41篇 |
1998年 | 38篇 |
1997年 | 42篇 |
1996年 | 44篇 |
1995年 | 32篇 |
1994年 | 36篇 |
1993年 | 45篇 |
1992年 | 53篇 |
1991年 | 37篇 |
1990年 | 40篇 |
1989年 | 49篇 |
1988年 | 45篇 |
1987年 | 43篇 |
1986年 | 35篇 |
1985年 | 62篇 |
1984年 | 58篇 |
1983年 | 41篇 |
1982年 | 45篇 |
1981年 | 52篇 |
1980年 | 46篇 |
1979年 | 46篇 |
1978年 | 43篇 |
1977年 | 51篇 |
1976年 | 54篇 |
1975年 | 44篇 |
1974年 | 38篇 |
排序方式: 共有5803条查询结果,搜索用时 15 毫秒
21.
Our main object in this paper is to discuss some results on rings with left identity in which certain subsets satisfy some functional identities. 相似文献
22.
Excess enthalpies of mixing H
m
E
of tetrahydrofuran and tetrahydropyran with trichloromethane, tetrachloromethane, 1,2-dichloroethane, 1,1,2-trichloroethane and 1,1,2,2-tetrachloroethane have been determined at 26.9°C and are found to be negative over the entire composition range for both sets of the ether mixtures. H
m
E
decreases in the sequence; dichloroethane > tetrachloromethane > trichloroethane > trichloromethane > tetrachloroethane. The results are explained on the basis of strong O...H-C and weak Cl...O specific interactions. Flory's theory has been used to correlate the experimental data with good agreement found between the theoretical and experimental values of H
m
E
. 相似文献
23.
M K Parida Nita Sinha B Adhikary B Allanach A Alok K S Babu B Brahmachari D Choudhury E J Chun P K Das A Ghosal D Hitlin W S Hou S Kumar H N Li E Ma S K Majee G Majumdar B Mishra G Mohanty S Nandi H Pas M K Parida S D Rindani J P Saha N Sahu Y Sakai S Sen C Sharma C D Sharma S Shalgar N N Singh S Uma Sankar N Sinha R Sinha F Simonetto R Srikanth R Vaidya 《Pramana》2006,67(5):849-860
This is the report of flavor physics and model building working group at WHEPP-9. While activites in flavor physics have been
mainly focused on B-physics, those in model building have been primarily devoted to neutrino physics. We present summary of working group discussions
carried out during the workshop in the above fields, and also briefly review the progress made in some projects subsequently. 相似文献
24.
25.
26.
An explicit expression has been derived for the volume dependence of electron-phonon coupling strength () by using a recently proposed quadratic form of the screened pseudopotential and by considering the variation of Fermi momentum with volume. Variation of Coulomb pseudopotential (
*) has also been explicitly considered by varying the Fermi momentum. Dependence of transition temperatureT
c
and the logarithm of the effective interaction strength (N
0
V) on the volume has been studied for eight nontransition metallic superconductors. A linear drop inT
c
for small values of (–/
0) as well as the calculated values of= InN
0
V/ In, exhibits better matching with the experimental data, as compared to the earlier theoretical results. 相似文献
27.
Sahadev R. K. Sharma S. K. Sindhwani 《Monatshefte für Chemie / Chemical Monthly》1992,123(10):883-889
Summary The chelation behaviour of some trivalent lanthanide and yttrium metal ion with biologically active 2-hydroxy-1-naphthaldehyde thiosemicarbazone (HNATS) has been investigated by potentiomotric measurements at 20±0.5°C in 75% (v/v) dioxane-water medium at various ionic strengths of sodium perchlorate. The method of Bjerrum and Calvin, as modified by Irving and Rossotti has been used to find out the values of
(average number of ligand bound per metal ion) andpL (free ligand exponent). The formation constants of metal chelates have been computed on a PC-XT computer, using a program patterned after that of Sullivan et al. to give
n
values using weighted least squares method. TheS
min
values (S
min
=2) have been calculated. The order of formation constants of chelates was found to be: La3+3+3+3+3+3+3+3+3+3+. The formation constants of the chelates formed have been correlated to size and ionization potentials of the metal ions.
Potentiometrische Untersuchungen der Komplexierungsgleichgewichte zwischen einigen trivalenten Metallionen und biologisch aktivem 2-Hydroxy-1-naphthaldehyd-thiosemicarbazon (HNATS)
Zusammenfassung Es wurde das Chelierungsverhalten einiger trivalenter Lanthanidenionen mit biologisch aktivem 2-Hydroxy-1-naphthaldehyd-thiosemicarbazon (HNATS) mittels potentiometrischer Messungen bei 20±0.5°C in 75% (v/v) Dioxan-Wasser bei verschiedener Ionenstärke an Natriumperchlorat untersucht. Die Methode nach Bjerrum und Calvin in der Modifikation nach Irving und Rossotti wurde zur Ermittlung der Werte (mittlere Anzahl an Liganden pro Metallion) undpL (Exponent an freiem Liganden) verwendet. Die Komplexbildungskonstanten wurden in Anlehnung an Sullivan et al. an einem PC-XT Computer errechnet. DieS min-Werte (S min=2) wurden ebenfalls bestimmt. Die Reihung der Chelatbildungskonstanten war: La3+相似文献3+ 3+ 3+ 3+ 3+ 3+ 3+ 3+ 3+. Die Bildungskonstanten sind mit der Größe und dem Ionisierungspotential der Metallionen zu korrelieren.
28.
R. Bacaud M. Besson D. Brodzki P. Bussière H. Charcosset G. Diega-Mariadassou M. Oberson B. K. Sharma 《Hyperfine Interactions》1989,46(1-4):583-589
Mössbauer Spectroscopy, X-Ray Diffraction and Electron Microscopy were applied to the study of solid residues of coal hydroliquefaction, for which tin-based catalysts were used. In the general case hydroliquefaction runs were performed in the presence of added sulphur and of finely dispersed SnO2 as a catalyst precursor. The only observed tin species were SnO2 and SnS, the former with percentages higher than expected from XRD, due to its large f factor, the latter as a symmetric doublet, which suggests that any asymmetry should be ascribed to small particle sizes rather than to structure. When the S content was only that of coal and the catalyst precursor β-Sn, FeSn2 occurred together with Sn sulfides and oxides, while no β-Sn was detected. The main catalytic role is ascribed to SnS. 相似文献
29.
Bortoletto D Goldberg M Horwitz N Mestayer MD Moneti GC Sharma V Shipsey IP Skwarnicki T Csorna SE Letson T Brock IC Ferguson T Artuso M Bebek C Berkelman K Blucher E Byrd J Cassel DG Cheu E Coffman DM Crawford G DeSalvo R DeWire JW Drell PS Ehrlich R Galik RS Gittelman B Gray SW Halling AM Hartill DL Heltsley BK Kandaswamy J Kowalewski R Kreinick DL Kubota Y Lewis JD Mistry NB Mueller J Namjoshi R Nandi S Nordberg E O'Grady C Peterson D Pisharody M Riley D Sapper M Silverman A Stone S Worden H 《Physical review letters》1989,62(21):2436-2439
30.
Alam MS Katayama N Kim IJ Li WC Lou XC Sun CR Bortoletto D Goldberg M Horwitz N Mestayer MD Moneti GC Sharma V Shipsey IP Skwarnicki T Csorna SE Letson T Brock IC Ferguson T Artuso M Bebek C Berkelman K Blucher E Byrd J Cassel DG Cheu E Coffman DM Crawford G DeSalvo R DeWire JW Drell PS Ehrlich R Galik RS Gittelman B Gray SW Halling AM Hartill DL Heltsley BK Kandaswamy J Kowalewski R Kreinick DL Kubota Y Lewis JD Mistry NB Mueller J Namjoshi R Nandi S Nordberg E O'Grady C Peterson D Pisharody M 《Physical review D: Particles and fields》1989,40(11):3790