Synthesis and characterization of diiron dithiolate complexes containing a quinoxaline bridge

A potential model complex for the hydrogenase active site, [Fe(2){(μ-CH(2)S)(2)R}(CO)(6)] (1) (R = quinoxaline), was synthesized by condensation of [(μ-LiS)(2)Fe(2)(CO)(6)] with 2,3-bis(bromomethyl)quinoxaline. Reactions of 1 with bis(diphenylphosphino)methane (dppm) under a range of conditions yielded substituted complexes [Fe(2){(μ-CH(2)S)(2)R}(CO)(5)(dppm)] (2), [Fe(2){(μ-CH(2)S)(2)R}(CO)(4)(k(2)-dppm)] (3) and [Fe(2){(μ-CH(2)S)(2)R}(CO)(4)(μ-dppm)] (4). X-ray crystallography confirms that in 2, the dppm is terminally bonded to an iron atom via one phosphorus atom, whereas in 3, it acts as a chelating ligand to coordinate to an iron center in a dibasal-substituted manner. In 4, the dppm bridges the two iron atoms in a cis basal/basal fashion with one phosphorus bonded to each iron atom. Treatment of 1 with various tertiary phosphines at room temperature in acetonitrile (MeCN) generates a range of mono-substituted products [Fe(2){(μ-CH(2)S)(2)R}(CO)(5)L] (5, L = PEt(3); 6, PMe(3); 7, PPh(3); 8, Me(2)PPh). With Bu(t)NC, mono- and di-substituted [Fe(2){(μ-CH(2)S)(2)R}(CO)(5)(Bu(t)NC)] (9) and [Fe(2){(μ-CH(2)S)(2)R}(CO)(4)(Bu(t)NC)(2)] (10) complexes are generated. All the complexes were characterized by elemental analysis, IR, MS and NMR spectroscopy. IR and NMR spectroscopic studies suggest that addition of excess HBF(4)·OEt(2) acid to 1-4 led to the protonation of quinoxaline nitrogen atoms. In contrast, 5-10 were not stable in acidic media. Electrochemistry of 1-4 was investigated in the acetonitrile medium (0.1 M Bu(4)NPF(6)). The electrochemical instability of the reduced ligand, quinoxaline, and the reduced forms of these complexes revealed from the electrochemical studies suggests that they do not provide ideal models of the hydrogenase active site.     

Rapid transfer alignment of laser SINS using quaternion based angular measurement

A novel rapid transfer alignment algorithm for laser strapdown inertial navigation system (SINS) is studied. Transfer alignment have typically relied on velocity measurements from the master SINS as the source of alignment information, but lever arm error must be compensated accurately while velocity information is utilized, all most every quaternion based error model is nonlinear, so nonlinear filtering algorithms are need, suffering from computational complex and large error. Aim at these problems, a novel improved rapid transfer alignment algorithm formulation is presented, applying quaternion to built the process and measurement models, the improvement employs a special manipulation of the measurement equation results in a linear pseudo-measurement equation, thus the classical linear Kalman filter is employed to estimate the state, need not lever arm error compensation, results in the reduce of computational burden. Observability analysis of this new transfer alignment algorithm has been done based on the piece-wise constant system (PWCS) method, results show that the presented algorithm can accomplish the initial alignment task perfectly. A transfer alignment simulation system is also developed for the evaluation and analysis of the presented algorithm, simulation results are confirmed with the theoretical conclusion, which can achieve the transfer alignment accuracy about 1 mrad within 10 s.     

激光驻波场作用下原子束横向速度聚束

分别从理论和实验上研究了在负失谐强激光驻波场作用下，原子速度聚集在某一特定速度附近的现象，即速度聚束，产生速度聚束的原因是，当原子的速度小于某一临界速度时，激光对原子的辐射压力加热原子，而当原子速度大于这个临界速度时则冷却原子，因此原子将伙集于这个临界速度附近。     

扩散方程基本解的积分处理

详细讨论了时间相关热交换问题扩散方程基本解的时间积分特性，给出了完整的解析处理及相应级数展开表达式，并提出采用按时段构造的时间单元局部化基本解作为边界元法的加权函数，从而显著减少可动边界问题边界元解法的存贮量和计算时间。     

光纤Bragg光栅热敏力敏效应研究及应用探讨

本文报道了光纤Bragg光栅热敏力敏效应的实验研究结果,测量所得的光纤Bragg光栅温度系数和应力系数分别为6.84×10^-6/℃和7.27×10^-6/gf,与理论值6.85×10^-6/℃和7.32×10^-6/gf符合得很好.在20～180℃和0～50gf的温度应力测量范围内,光纤Bragg光栅透射谱中心波长移动量同温度应力具有良好的线性关系.基于光纤Bragg光栅的热敏力敏效应,本文还讨论了光纤Bragg光栅温度应变传感器实用化时必须首先考虑的一些关键问题.     

浅谈大功率电子节能灯的设计与制作

本文简要介绍大功率电子节能灯设计原理及应注意的几个问题。     

R-n模张量积与张量函子

文[1]引进了左R-n模范畴_RM_n~L,本文是在_RM_n中,建立相应的张量积,证明了它的存在性与唯一性,并讨论了张量函子与Hom函子的伴随性。 文中沿用[1]的记号。     

Bandgaps and vibration isolation of local resonance sandwich-like plate with simply supported overhanging beam

Applied Mathematics and Mechanics - The concept of local resonance phononic crystals proposed in recent years provides a new chance for theoretical and technical breakthroughs in the structural...     

Diastereoselective cycloadditions of a soluble polymer-supported substituted allyl alcohol derived from Baylis-Hillman reaction with nitrile oxides

A diastereoselective cycloaddition of a soluble polymer-supported Baylis-Hillman adduct with nitrile oxides is described. The reaction has shown to proceed with moderate diastereoselectivity, favoring the syn isomer of the resulting 3,5-substituted isoxazolines. The stereochemistry of the products has been assigned using ¹H NMR studies. The structure of one of the diastereomers has been determined by single-crystal X-ray crystallographic analysis.     

Efficient construction of tri- and tetracyclic heterocycles from linear 1,6-dienes by a domino reaction

Tri- and tetracyclic heterocycle systems were constructed by a palladium-catalyzed domino reaction of linear 1,6-dienes that contain acryl groups with aryl halides through C-C coupling and aromatic C-H functionalization. Three different acrylamides have been shown to be very active for the reaction. The substituents on the aryl halides could be ethoxycarbonyl, ketyl, chloro, sulfonyl, cyano, etc. Thus, the ready accessibility of the starting materials, the wide range of compatibility of substrates including both dienes and aryl halides, and the generality of this process make the reaction highly valuable in view of the synthetic and medicinal importance of these kinds of heterocycles.