全文获取类型
收费全文 | 9778篇 |
免费 | 1544篇 |
国内免费 | 1785篇 |
专业分类
化学 | 8245篇 |
晶体学 | 153篇 |
力学 | 468篇 |
综合类 | 110篇 |
数学 | 1193篇 |
物理学 | 2938篇 |
出版年
2024年 | 13篇 |
2023年 | 87篇 |
2022年 | 262篇 |
2021年 | 235篇 |
2020年 | 259篇 |
2019年 | 378篇 |
2018年 | 285篇 |
2017年 | 321篇 |
2016年 | 427篇 |
2015年 | 526篇 |
2014年 | 614篇 |
2013年 | 766篇 |
2012年 | 921篇 |
2011年 | 905篇 |
2010年 | 682篇 |
2009年 | 696篇 |
2008年 | 791篇 |
2007年 | 684篇 |
2006年 | 605篇 |
2005年 | 595篇 |
2004年 | 522篇 |
2003年 | 385篇 |
2002年 | 439篇 |
2001年 | 363篇 |
2000年 | 272篇 |
1999年 | 180篇 |
1998年 | 160篇 |
1997年 | 126篇 |
1996年 | 99篇 |
1995年 | 74篇 |
1994年 | 82篇 |
1993年 | 55篇 |
1992年 | 51篇 |
1991年 | 47篇 |
1990年 | 50篇 |
1989年 | 28篇 |
1988年 | 34篇 |
1987年 | 16篇 |
1986年 | 18篇 |
1985年 | 14篇 |
1984年 | 6篇 |
1983年 | 7篇 |
1982年 | 4篇 |
1981年 | 3篇 |
1980年 | 2篇 |
1977年 | 3篇 |
1959年 | 1篇 |
1939年 | 1篇 |
1936年 | 7篇 |
1935年 | 1篇 |
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
31.
This paper addresses a kind of risk decision-making problem existing widely in public administration and business management, which is characterized by (1) occurrence probabilities of states of nature can be estimated by analysing historical observations, but historical observations of different objects are unhomogeneous, (2) the relation between observations and occurrence probabilities of states of nature are affected by some qualitative and quantitative indicators, (3) it is a real-time decision-making problem, that is, there are many decisions for different objects to be made in a limited time, (4) considering decision's execution, impact of resource constrains is an important issue in decision-making process. In this paper, we develop a rule-based approach to address the problem. In the proposed approach, a two-step clustering method is employed to classify objects into categories, and observations in each category can be approximately viewed as homogeneous. For objects in each category, occurrence probabilities of states of nature are estimated by logistic regression, and the decision rule is obtained through solving an optimization model, which is to minimize the total decision risks while satisfying resource constrains. Effect and efficacy of our approach are illustrated through its application to China's customs inspection decision. 相似文献
32.
Two novel dithienylethenes with ferrocene units were synthesized by Wittig reaction. The structure of 2a has been established by X‐ray diffraction studies. They could reversibly interconvert between two thermally stable forms, an open and a closed one, using light of different wavelengths as triggers. Copyright © 2006 John Wiley & Sons, Ltd. 相似文献
33.
Zero field Mössbauer spectra and powder susceptibility measurements show that the condensed, hydrogen bonded network compound FeSO3 3H2O orders antiferromagnetically (TNéel 9.5 K). The related anhydrous material FeSO3 also shows antiferromagnetic exchange but no evidence of long range three-dimenstional magnetic order to as low as 1.4 K.Supported by the U.S. National Science Foundation Division of Materials Research—Solid State Chemistry Program Grant No. DMR 8313710. 相似文献
34.
Pure copolymer nanoparticles from 8-aminoquinoline (AQ) and 2-ethylaniline (EA) were easily synthesized by a chemically oxidative polymerization in three different aqueous media. The potential and temperature of polymerization solution were used to successfully follow the polymerization progress. The molecular and morphological structures of the resulting AQ/EA copolymer particles were systematically characterized by IR, UV/Vis, NMR, gel permeation chromatography, laser particle-size analysis, atomic force and transmission electron microscopy. The oxidation potential of the monomers as well as the polymerization yield, structure, and properties of the particles were found to significantly depend on AQ/EA ratio, polymerization temperature and medium. It is surprisingly found that AQ homopolymerization and AQ/EA (50:50) copolymerization at 5 degrees C in HCl simply afford nano-ellipsoids with the major/minor axis diameters of 24/14 nm and 80/67 nm, respectively. A simple method of synthesizing semiconducting pure nanoparticles by introducing the AQ units with positively charged quaternary ammonium groups but in the absence of adscititious stabilizer or sulfonic substituent on the monomers is established first. Both the molecular weight and bulk electroconductivity of the copolymers exhibit a maximum at AQ content of 10 mol %. The solubility and film formability of the copolymers are good in highly polar solvents and reach the optimal at the AQ content of 20 and 10 mol %, respectively. 相似文献
35.
New anti-HIV prodrugs, conjugates of AZT and d4T with boranophosphates, were prepared by the H-phosphonate method. Their structures were determined by negative ion electrospray ionization mass spectrometry (ESI-MS) in conjunction with tandem mass spectrometry (MS/MS). The fragmentation pathways were investigated, and most of the fragment ions contained the boranophosphate or phosphinate group. 相似文献
36.
[structure: see text] A family of chiral metallacyclophanes has been readily assembled based on robust Pt-acetylide linkage and characterized by a variety of spectroscopic techniques and X-ray crystallography. The steric congestion around the chiral dihydroxy groups in rigid metallacyclophane 4 prevents their reactions with Ti(O(i)()Pr)(4) to form active catalysts for enantioselective diethylzinc additions to aromatic aldehydes. In contrast, chiral dihydroxy groups in more flexible unclosed metallacyclophane 5 are effective ligands for enantioselective catalytic diethylzinc additions to aromatic aldehydes. 相似文献
37.
Lithuanian Mathematical Journal - Let Hk denote the space of holomorphic Hecke cusp forms of even integral weight k for the full modular group Γ = SL(2, ℤ). Let λf (n), λg(n),... 相似文献
38.
Fuzzy Optimization and Decision Making - In the decision-making process, retaining the original data information has become a most crucial step. Dual hesitant fuzzy sets (DHFS), which can reflect... 相似文献
39.
Some Estimates for $θ$-Type Calderόn–Zygmund Operators and Linear Commutators on Certain Weighted Amalgam Spaces 下载免费PDF全文
In this paper, we first introduce some new kinds of weighted amalgam
spaces. Then we discuss the strong type and weak type estimates for a class of
Calderόn–Zygmund type operators $T_θ$ in these new weighted spaces. Furthermore,
the strong type estimate and endpoint estimate of linear commutators $[b, T_θ]$ formed
by $b$ and $T_θ$ are established. Also we study related problems about two-weight, weak
type inequalities for $T_θ$ and $[b, T_θ]$ in the weighted amalgam spaces and give some
results. 相似文献
40.
In this paper, we study the spectrum of the Dirichlet Laplacian in a bounded (or, more generally, of finite volume) open set R
n
(n1) with fractal boundary of interior Minkowski dimension (n–1,n]. By means of the technique of tessellation of domains, we give the exact second term of the asymptotic expansion of the counting functionN() (i.e. the number of positive eigenvalues less than ) as +, which is of the form /2 times a negative, bounded and left-continuous function of . This explains the reason why the modified Weyl-Berry conjecture does not hold generally forn2. In addition, we also obtain explicit upper and lower bounds on the second term ofN(). 相似文献