基于摩擦磨损的KDP晶体固结磨料抛光垫优化

本文通过固结磨料球与KDP晶体对磨的单因素试验探究固结磨料球中反应物种类、磨粒浓度、反应物浓度、基体硬度对摩擦系数、磨痕截面积和磨痕处粗糙度的影响,试验结果表明:KHCO₃固结磨料球对磨后磨痕对称性好,磨痕处的粗糙度值低;磨痕截面积随磨粒和反应物浓度的增加而增大,随基体硬度的增大而降低;磨痕处粗糙度随磨粒和反应物浓度的增加先降低后上升,随基体硬度的增大先上升后降低;摩擦系数受磨粒和反应物浓度影响不明显,随基体硬度的增大而降低。选择KHCO₃作为反应物,Ⅰ基体,磨粒浓度为基体质量的100%,反应物浓度为15%制备固结磨料球与KDP晶体对磨后的磨痕轮廓对称度好且磨痕处粗糙度值低,以该组分制备固结磨料垫干式抛光KDP晶体,可实现晶体表面粗糙度Sa值为18.50 nm,材料去除率为130 nm/min的高效精密加工。     

THE CONSTRUCTION OF WAVELET-BASED TRUNCATED CONICAL SHELL ELEMENT USING B-SPLINE WAVELET ON THE INTERVAL

Based on B-spline wavelet on the interval (BSWI), two classes of truncated conicalshell elements were constructed to solve axisymmetric problems, i.e. BSWI thin truncated conicalshell element and BSWI moderately thick truncated conical shell element with independent slope-deformation interpolation. In the construction of wavelet-based element, instead of traditionalpolynomial interpolation, the scaling functions of BSWI were employed to form the shape functionsthrough the constructed elemental transformation matrix,and then construct BSWI element viathe variational principle. Unlike the process of direct wavelets adding in the wavelet Galerkinmethod, the elemental displacement field represented by the coefficients of wavelets expansionwas transformed into edges and internal modes via the constructed transformation matrix. BSWIelement combines the accuracy of B-spline function approximation and various wavelet-basedelements for structural analysis. Some static and dynamic numerical examples of conical shellswere studied to demonstrate the present element with higher efficiency and precision than thetraditional element.     

Sampled-data output voltage regulation for a DC–DC buck converter nonlinear system with actuator and sensor failures

Nonlinear Dynamics - This paper considers the distributed adaptive neural consensus tracking control problem for a class of uncertain nonaffine nonlinear multi-agent systems. By making use of the...     

工业SO2及碳黑颗粒紫外成像遥感监测技术

为了准确有效监测工业烟囱排放,基于SO2及碳黑颗粒物的光学特性,设计并研制出一套双通道紫外成像遥感监测系统.该成像系统的两个光谱通道的中心波长分别定于310 nm和330 nm,利用两个通道的光学厚度之差反演SO2浓度图像,颗粒物浓度图像由330 nm通道获取,根据浓度图像结合光流法获取烟羽运动速度,进而计算得出SO2和碳黑颗粒物的排放速率.结果表明,该工业烟囱的SO2及碳黑颗粒物排放速率分别为72.48±3.16 kg/h和6.33±1.18 kg/h.实验采用紫外相机同时对工业烟囱排放的SO2及碳黑颗粒物进行监测,实验表明双通道紫外成像遥感监测兼具高时间分辨率与高空间分辨率,测量结果准确直观,在工业废气污染、船舶尾气污染以及火山喷发污染排放遥感监测中具有非常明显的技术优势及巨大的应用前景.     

考虑地表反射类型的气溶胶散射偏振特性

采用逐次阶散射法求解矢量辐射传输方程来研究气溶胶在不同地表反射模型下的散射偏振特性.首先,选取单一地表反射模型和耦合地表反射模型两种地表反射模型.然后,根据地表反射模型计算得到相应的地表反射率,进而采用逐次阶散射法对矢量辐射传输方程进行求解,得到散射光的Stokes矢量.最后,由Stokes矢量计算得出散射光的偏振度.仿真结果表明,两种地表反射模型下气溶胶单次散射的散射辐射强度和线偏振度均相等;耦合地表反射模型的总散射辐射强度和线偏振度总是大于单一地表反射模型;单一地表反射模型的气溶胶单次散射相对总散射的贡献总是大于耦合地表反射模型.研究结果对气溶胶光学特性的反演具有一定意义.     

不同气体工质对激光推力器冲量耦合系数的影响

通过冲击摆实验,测量了激光推力器在不同气体工质(氩气,氦气)、不同工作压力条件下的冲量耦合系数,比较了不同气体对激光推力器冲量耦合系数的影响.实验结果表明:冲量耦合系数随着环境压力的下降而下降,并且下降趋势越来越快;在氩气中测量的冲量耦合系数比氦气的高;实验产生误差的主要因素是摆角的测量误差.     

Catalytic asymmetric synthesis of enantioenriched α-deuterated pyrrolidine derivatives

The recent promising applications of deuterium-labeled pharmaceutical compounds have led to an urgent need for the efficient synthetic methodologies that site-specifically incorporate a deuterium atom into bioactive molecules. Nevertheless, precisely building a deuterium-containing stereogenic center, which meets the requirement for optimizing the absorption, distribution, metabolism, excretion and toxicity (ADMET) properties of chiral drug candidates, remains a significant challenge in organic synthesis. Herein, a catalytic asymmetric strategy combining H/D exchange (H/D-Ex) and azomethine ylide-involved 1,3-dipolar cycloaddition (1,3-DC) was developed for the construction of biologically important enantioenriched α-deuterated pyrrolidine derivatives in good yields with excellent stereoselectivities and uniformly high levels of deuterium incorporation. Directly converting glycine-derived aldimine esters into the deuterated counterparts with D₂O via Cu(i)-catalyzed H/D-Ex, and the subsequent thermodynamically/kinetically favored cleavage of the α-C–H bond rather than the α-C–D bond to generate the key N-metallated α-deuterated azomethine ylide species for the ensuing 1,3-DC are crucial to the success of α-deuterated chiral pyrrolidine synthesis. The current protocol exhibits remarkable features, such as readily available substrates, inexpensive and safe deuterium source, mild reaction conditions, and easy manipulation. Notably, the synthetic utility of a reversed 1,3-DC/[H/D-Ex] protocol has been demonstrated by catalytic asymmetric synthesis of deuterium-labelled MDM2 antagonist idasanutlin (RG7388) with high deuterium incorporation.

A strategy of combining H/D-Ex and azomethine ylide-involved 1,3-DC was developed for the construction of α-deuterated pyrrolidine derivatives in good yields with excellent stereoselectivities and uniformly high levels of deuterium incorporation.     

溶胶-凝胶法制备丙烯酸树脂/TiO2有机-无机杂化材料及其结构表征

通过预水解的二氧化钛(TiO2 )溶胶与丙烯酸树脂共混或原位聚合的方法制备了均匀透明的丙烯酸树脂 TiO2 有机 无机杂化材料.考察了TiO2 溶胶制备方法、聚合物中—COOH官能团含量和杂化材料制备方法对杂化材料结构的影响.索氏抽提实验表明聚合物中的羧酸官能团和无机TiO2 相间发生了交联反应,且随着—COOH官能团含量的增加,交联程度增大.小角X射线散射(SAXS)结果发现,杂化材料中TiO2 为疏松的三维网状结构,且在纳米尺度范围内,但这种三维网状结构随着TiO2 溶胶制备中水或酸的用量增加,其致密度增加,尺寸增大.同原位聚合法相比,共混法可制备出更均匀的杂化体系,且TiO2 为单分散.     

聚乳酸/β-磷酸三钙多孔复合支架的制备及性能研究

以聚乳酸和β-磷酸三钙共混制备了多孔复合支架,并对其孔隙率、降解性和力学性能进行了研究。结果表明,β-磷酸三钙的引入可以有效地减缓支架的降解,提高支架的力学性能。