全文获取类型
收费全文 | 5473篇 |
免费 | 159篇 |
国内免费 | 949篇 |
专业分类
化学 | 2812篇 |
晶体学 | 2篇 |
力学 | 388篇 |
综合类 | 191篇 |
数学 | 1070篇 |
物理学 | 2118篇 |
出版年
2022年 | 1篇 |
2020年 | 2篇 |
2016年 | 8篇 |
2015年 | 24篇 |
2014年 | 12篇 |
2013年 | 55篇 |
2012年 | 72篇 |
2011年 | 973篇 |
2010年 | 509篇 |
2009年 | 546篇 |
2008年 | 76篇 |
2007年 | 88篇 |
2006年 | 140篇 |
2005年 | 319篇 |
2004年 | 941篇 |
2003年 | 557篇 |
2002年 | 450篇 |
2001年 | 331篇 |
2000年 | 116篇 |
1999年 | 102篇 |
1998年 | 135篇 |
1997年 | 90篇 |
1996年 | 76篇 |
1995年 | 55篇 |
1994年 | 50篇 |
1993年 | 200篇 |
1992年 | 166篇 |
1991年 | 107篇 |
1990年 | 98篇 |
1989年 | 98篇 |
1988年 | 83篇 |
1987年 | 6篇 |
1986年 | 61篇 |
1985年 | 8篇 |
1984年 | 21篇 |
1983年 | 2篇 |
1979年 | 1篇 |
1936年 | 2篇 |
排序方式: 共有6581条查询结果,搜索用时 0 毫秒
131.
微乳液进样火焰原子吸收光度法测定食品中的微量锰 总被引:8,自引:0,他引:8
研究了多种表面活性剂及微乳液对火焰原子吸收光谱法测定锰的增敏作用,并选择增敏作用最强的微乳液作为锰测定的增敏试剂,拟定了测定锰的新方法。 相似文献
132.
ICP—AES法中稀土元素间的相互干扰研究 总被引:5,自引:0,他引:5
稀土元素的谱线较复杂,相互间存在着不同程度的干扰。本文着重研究了ICP-AES法中,它们间的干扰情况,并用几种校正方法进行了比较。 相似文献
133.
134.
金属Zn液态结构变化的研究 总被引:2,自引:0,他引:2
利用TB模型给出的原子间相互作用势详细计算了不同温度下Zn的双体分布函数g(r),结果发现随着温度的不断降低,液态金属Zn的g(r)第一峰变得高而尖,第二峰由弱变强,说明了液态金属Zn的有序度随温度降低而不断增强;利用键对分析技术统计了液态金属Zn在不同温度下的键取向序参数、键对数。键取向序参数及键对数随温度的变化,进一步证明了低温液态的有序度高于高温液态,从而充分说明液态金属在不同温度下有不同的结构形式,而不像人们想象得那样杂乱无章。 相似文献
135.
利用G98及GAMESS从头计算程序的RHF/6-31方法,对β-榄香烯的全部振动基频作了计算,并与实测红外光谱做了对比,归属了它们的振动模式,讨论了它们的特征基频,并对理论计算的振动频率进行了标度校正。 相似文献
136.
XU ShangJin WU ZhengFei & DENG YunPing College of Mathematics Information Science Guangxi University Nanning 《中国科学A辑(英文版)》2009,(2)
A graph is said to be s-arc-regular if its full automorphism group acts regularly on the set of its s-arcs. In this paper, we investigate connected cubic s-arc-regular Cayley graphs of finite nonabelian simple groups. Two suffcient and necessary conditions for such graphs to be 1- or 2-arc-regular are given and based on the conditions, several infinite families of 1-or 2-arc-regular cubic Cayley graphs of alternating groups are constructed. 相似文献
137.
QI GuoPeng JIANG Feng SUN XueWen & ZHAO SuoQi School of Chemical Engineering Tianjin University Tianjin China State key Laboratory of Heavy Oil Processing Petroleum University of China Beijing China 《中国科学:化学》2010,(5)
The isotope exchange method was employed to investigate the catalytic mechanism of ionic liquid in alkylation of benzenes with olefins.It is proposed that alkylation was induced by the Lewis acid AlCl3 which attracted π electrons of 1-dodecene to shift toward 1-carbon,thus forming a carbonium ion.The carbonium ion further reacted with benzenes to form a complex.Due to unstabilit of the complex,a deuterated ring proton was transferred into an electronegative 1-carbon of the side chain to substitute for the A... 相似文献
138.
LI Cun-man XIAO Yuan-sheng XUE Xing-ya FENG Jia-tao ZHANG Xiu-li LIANG Xin-miao . Dalian Institute of Chemical Physics Chinese Academy of Sciences Dalian P. R. China . Hebei Research Centre of Analysis Testing Hebei University of Science Technology Shijiazhuang 《高等学校化学研究》2011,(3):392-396
An efficient preparative method was successfully developed for isolation and purification of unstable components from medicinal plant extracts, using a combined method of preparative high performance liquid chro-matography(HPLC) and solid-phase extraction(SPE). The aim of this study was to obtain an effective method with high preparative efficiency and importantly to avoid the transformation of unstable compounds. The preparative HPLC system was based on an LC/MS controlled four-channel autopurification sys... 相似文献
139.
PREPARATION AND PROPERTIES OF CLAY/POLY(N-ISOPROPYLACRYLAMIDE-co-ACRYL AMIDE)NANOCOMPOSITE HYDROGELS
LIU Xiaoli LIU Yang Zhang WEI JIANG Yongmei GU Chunju ZHU Meifang** Adler H.J. .State Key Lab for Modification of Polymer Materials Chemical Fibers College of Material Sci.& Eng. Donghua University Shanghai China .Institute of Macromolecular Chemistry Textile Chemistry Dresden University of Technology Mommsenstr. D- Dresden Germany 《Chinese Journal of Reactive Polymers》2006,(1)
Polymer hydrogels as a kind of soft materials have attracted increasing scientific and technological interest in past several decades. These materials have been applied widely in many fields [1], such as molecular filter [2,3], superabsorbent [4], and contact lenses [5] etc. However, synthetic polymeric hydrogels are seldom used as mechanical devices due to the lack of mechanical strength. Therefore, it is very imperative to improve their mechanical properties for wider use of polymeric hydrog… 相似文献
140.
Spectroscopy Investigation on Conformational Transition of Tea Glycoconjugate from Green Tea 总被引:5,自引:0,他引:5
The conformational transition of a new glycoconjugate, tea glycoconjugate (TGC), was investigated by spectroscopy techniques including circular dichroism (CD) and ultraviolet (UV) spectroscopy. The solution behaviors of TGC in the mediums of different temperature, pH value, and ions were compared. Results showed that the native conformation of TGC was partially ordered. The CD value and UV absorbance of TGC altered with the change of pH value, temperature, the addition of ions, and also accompanied order-disorder transition. Especially the conditions with temperature higher than the glass transition temperature (Tg=62℃), higher pH value or lower pH value will have the most impact on the conformation of TGC, which will destroy the hydrogen bonds between the TGC molecules. The results indicated that the outside factors play important roles on the stability of the conformation of TGC. 相似文献