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101.
Soumaya Touzani Hamada Imtara Shankar Katekhaye Hamza Mechchate Hayat Ouassou Ali S. Alqahtani Omar M. Noman Fahd A. Nasr Hugo Fearnley James Fearnley Anant Paradkar Ilham ElArabi Badiaa Lyoussi 《Molecules (Basel, Switzerland)》2021,26(15)
The biological activities of propolis samples are the result of many bioactive compounds present in the propolis. The aim of the present study was to determine the various chemical compounds of some selected propolis samples collected from Palestine and Morocco by the High-Performance Liquid Chromatography–Photodiode Array Detection (HPLC-PDA) method, as well as the antioxidant and antibacterial activities of this bee product. The chemical analysis of propolis samples by HPLC-PDA shows the cinnamic acid content in the Palestinian sample is higher compared to that in Moroccan propolis. The results of antioxidant activity demonstrated an important free radical scavenging activity (2,2-Diphenyl-1-picrylhydrazyl (DPPH); 2,2′-azino-bis 3-ethylbenzothiazoline-6-sulphonic acid (ABTS) and reducing power assays) with EC50 values ranging between 0.02 ± 0.001 and 0.14 ± 0.01 mg/mL. Additionally, all tested propolis samples possessed a moderate antibacterial activity against bacterial strains. Notably, Minimum Inhibitory Concentrations (MICs) values ranged from 0.31 to 2.50 mg/mL for Gram-negative bacterial strains and from 0.09 to 0.125 mg/mL for Gram-positive bacterial strains. The S2 sample from Morocco and the S4 sample from Palestine had the highest content of polyphenol level. Thus, the strong antioxidant and antibacterial properties were apparently due to the high total phenolic and flavone/flavonol contents in the samples. As a conclusion, the activities of propolis samples collected from both countries are similar, while the cinnamic acid in the Palestinian samples was more than that of the Moroccan samples. 相似文献
102.
Yaakov Idell Jörg Wiezorek Giovanni Facco Andreas Kulovits M. Ravi Shankar 《哲学杂志》2020,100(9):1102-1128
ABSTRACTType 316L austenitic stainless steel was severely plastically deformed at room temperature using linear plane-strain machining in a single pass that imparted shear strains up to 2.2 at strain rates up to 2?×?103 s?1. The resulting microstructures exhibited significant grain size refinement and improved mechanical strength where geometric dynamic recrystallization was identified as the primary microstructural recrystallization mechanism active at high strain rates. This mechanism is rarely observed in low to medium stacking fault energy materials. The critical stress required for twin initiation is raised by the combined effects of refined grain size and the increase in stacking fault energy due to the adiabatic heating of the chip, thus permitting geometric dynamic recrystallization. The suppression of martensite formation was observed and is correlated to the significant adiabatic heating and mechanical stabilisation of the austenitic stainless steel. A gradient of the amount of strain induced martensite formed from the surface towards the interior of the chip. As the strain rate is increased from 4?×?102 s?1–2?×?103 s?1, a grain morphology change was observed from a population of grains with a high fraction of irregular shaped grains to one dominated by elongated grain shapes with a microstructure characterised by an enhanced density of intragranular sub-cell structure, serrated grain boundaries, and no observable twins. As strain rates were increased, the combination of reduction in strain induced martensite and non-uniform intragranular strain led to grain softening where a Hall-Petch relationship was observed with a negative strengthening coefficient of ?0.08?MPa m1/2. 相似文献
103.
Radial basis function (RBF)‐based parametric models for closed and open curves within the method of regularized stokeslets 下载免费PDF全文
The method of regularized Stokeslets (MRS) is a numerical approach using regularized fundamental solutions to compute the flow due to an object in a viscous fluid where inertial effects can be neglected. The elastic object is represented as a Lagrangian structure, exerting point forces on the fluid. The forces on the structure are often determined by a bending or tension model, previously calculated using finite difference approximations. In this paper, we study spherical basis function (SBF), radial basis function (RBF), and Lagrange–Chebyshev parametric models to represent and calculate forces on elastic structures that can be represented by an open curve, motivated by the study of cilia and flagella. The evaluation error for static open curves for the different interpolants, as well as errors for calculating normals and second derivatives using different types of clustered parametric nodes, is given for the case of an open planar curve. We determine that SBF and RBF interpolants built on clustered nodes are competitive with Lagrange–Chebyshev interpolants for modeling twice‐differentiable open planar curves. We propose using SBF and RBF parametric models within the MRS for evaluating and updating the elastic structure. Results for open and closed elastic structures immersed in a 2D fluid are presented, showing the efficacy of the RBF–Stokeslets method. Copyright © 2015 John Wiley & Sons, Ltd. 相似文献
104.
Wayland E. Noland Michael J. Konkel Susan J. Fanburg Shankar Venkatraman Doyle Britton 《Journal of chemical crystallography》1999,29(1):9-14
The acid-catalyzed condensation of 1-benzylindole with acetone in the presence of N-phenylmaleimide gave a tetrahydrocarbazole, (4,5,10,10b-tetrahydro-5-methyl-2-phenyl-10-(phenylmethyl)pyrrolo[3,4-a]carbazole-1,3[2H, 3aH]-dione (1), as the major product and a novel spiro compound, 1,3,4,4-tetrahydro-1,1,3,3-tetramethyl-4,4-bis(phenylmethyl)-1,3(2H, 2H)-spiro[cyclopent[b]indole] (2), as the minor product. The structure of the spiro compound was determined by an X-ray crystallographic determination. The acid-catalyzed condensation of 1-benzylindole with acetone in the absence of N-phenylmaleimide gave a bisindole, (1,1-bis(phenylmethyl)-3,3-(1-methylethylidene)diindole (3), as the major product and the spiro-compound as the minor product. 相似文献
105.
Jhillu S. Yadav Basi V. Subba Reddy Tallapally Swamy Kattela Shiva Shankar 《Monatshefte für Chemie / Chemical Monthly》2008,139(11):1317-1320
Amines undergo smooth conjugate addition to p-quinones in H2O at ambient temperature in the absence of a catalyst to produce 2-aminoquinones in excellent yields. Significant rate acceleration
of this reaction is observed in H2O compared to organic solvents. H2O played a dual role in simultaneously activating the p-quinone and amine. This new methodology constitutes an easy, highly efficient, and green synthesis of substituted p-quinones.
Correspondence: J. S. Yadav, Division of Organic Chemistry, Indian Institute of Chemical Technology, Hyderabad 500007, India. 相似文献
106.
Mixed-ligand diorganotin esters, [R 2Sn(OP(O)(OH)Ph)(OS(O) 2R (1))] n [R = n-Bu, R (1) = Me ( 1), n-Pr ( 2); R = Et, R (1) = Me ( 3)], have been synthesized by reacting the tin precursors, R 2Sn(OR (1))OS(O) 2R with an equimolar amount of phenylphosphonic acid under mild conditions (room temperature, 6-8 h, CH 2Cl 2). These have been characterized by IR, multinuclear ( (1)H, (13)C{ (1)H}, (31)P, and (119)Sn) NMR, and single crystal X-ray diffraction studies. The asymmetric unit of 1 is comprised of a tetramer with four crystallographically unique tin atoms. The structure reveals a central eight-membered (Sn-O-S-O) 2 cyclic ring with two exocyclic tin atoms, which results from micro 3-binding of the two methanesulfonate groups. The remaining two sulfonates are monodentate and contribute in O...HO(P) hydrogen bonding. The molecular structure is extended into a 3D coordination polymer with the aid of hydrogenphenylphosphonate group on each tin atom, acting in a micro 2-O 2P mode and forms a series of eight-membered (Sn-O-P-O) 2 rings in the structural framework. 2 and 3 are isostructural and represent linear 1D coordination polymers via micro 2-binding mode of both alkanesulfonate and hydrogenphenylphosphonate groups. 相似文献
107.
Dhananjay Yadav Prof. Dr. Maya Shankar Singh 《European journal of organic chemistry》2023,26(10):e202201335
An operationally simple and efficient cascade approach to access a series of 1,3-thiazinanes has been developed through intermolecular [3+3] heteroannulative coupling employing β-ketothioamide as a C1 N1S1 unit and epichlorohydrin as a C3 unit at room temperature for the first time. The reaction proceeds by nucleophilic attack of thiocarbonyl sulfur to less hindered primary carbon of oxirane followed by sequential intramolecular N-cyclization and dehydrochlorination enabling the coupling by cleavage of C−O bond and formation of two new C−S and C−N bonds in one stretch. This protocol not only avoids potential toxicity and tedious work up procedures, but also features open atmosphere, good to high yields, gram-scalability, and easy performance from inexpensive, readily available starting materials under transition-metal-free conditions. A probable mechanism for the formation of 1,3-thiazinanes has been suggested. 相似文献
108.
Three series of novel dimeric supramolecules, possessing both inter- as well as intramolecular H-bonding, have been prepared and investigated for their thermal properties. They were obtained in excellent yields by condensing cholesteryl ω-(3-hydroxy-4-formylphen-oxy)alkanoates with 4-(n-alkoxy)benzohydrazides, 3,4-bis(n-decyl-oxy)benzohydrazide and 3,4,5-tris(n-decyloxy)benzohydrazide. The influence of increase in the number of terminal n-alkoxy tails from one to three and the length and parity of the flexible spacer on phase transitional behaviour have been thoroughly investigated with the aid of microscopic, calorimetric and X-ray diffraction (XRD) techniques. The results of these complementary studies clearly illustrate the dependence of thermal behaviour of the dimers on these structural factors. The rigid intermolecular association via H-bonds through complementary benzohydrazide component enforce their self-assembly into frustrated and polar smectic phases; H-bond force coupled with the bulkiness of steroid moiety affects the electrical switching property of this fluid polar structure. 相似文献
109.
s‐Triazine‐Based Functional Discotic Liquid Crystals: Synthesis,Mesomorphism and Photoluminescence 下载免费PDF全文
B. N. Veerabhadraswamy Hashambi K. Dambal D. S. Shankar Rao C. V. Yelamaggad 《Chemphyschem》2016,17(14):2225-2237
A new series of C3‐symmetric, π‐conjugated molecules was designed, synthesized and characterized. The materials were derived from electron‐accepting s‐triazine, appended covalently to electron‐donating styrylbenzene arms, and were readily prepared in excellent yield with high purity by means of three‐fold condensation of triphosphonate with n‐alkoxybenzaldehydes under Horner–Wadsworth–Emmons reaction conditions. Examination of the phase transitional properties by several complementary techniques evidenced self‐assembly into a hexagonal columnar phase, occurring over wide and reasonable thermal ranges. The photophysical properties were studied both in solution and in the fluid/frozen columnar states by UV/Vis absorption and photoluminescence spectroscopy. The emission spectra obtained as a function of the temperature rule out the breaking‐up of larger columns and a non‐radiative, thermally activated process. A study carried out on thin films of the glassy columnar state, which accounts for conserved fluorescence, defect‐free orientation, and freezing ionic species, with the help of atomic force microscopy (AFM) images, suggested a homogeneous granular morphology comprising fibrillar structures. Dissimilarities in the surface morphology and birefringence of thin films of the solid and frozen columnar states were clearly shown by Raman spectroscopy. An electrochemical investigation revealed a LUMO energy of ?4.0 eV. Thus, the discotic motifs presented herein meet certain criteria of organic materials, which are essential for developing electronic devices. 相似文献
110.