全文获取类型
收费全文 | 173篇 |
免费 | 24篇 |
国内免费 | 26篇 |
专业分类
化学 | 150篇 |
晶体学 | 2篇 |
力学 | 15篇 |
综合类 | 3篇 |
数学 | 19篇 |
物理学 | 34篇 |
出版年
2023年 | 2篇 |
2022年 | 12篇 |
2021年 | 6篇 |
2020年 | 8篇 |
2019年 | 4篇 |
2018年 | 8篇 |
2017年 | 2篇 |
2016年 | 12篇 |
2015年 | 12篇 |
2014年 | 10篇 |
2013年 | 7篇 |
2012年 | 13篇 |
2011年 | 11篇 |
2010年 | 5篇 |
2009年 | 13篇 |
2008年 | 10篇 |
2007年 | 12篇 |
2006年 | 10篇 |
2005年 | 6篇 |
2004年 | 6篇 |
2003年 | 6篇 |
2002年 | 7篇 |
2001年 | 4篇 |
2000年 | 3篇 |
1999年 | 6篇 |
1998年 | 8篇 |
1997年 | 6篇 |
1996年 | 1篇 |
1995年 | 1篇 |
1994年 | 3篇 |
1993年 | 1篇 |
1992年 | 1篇 |
1991年 | 5篇 |
1989年 | 1篇 |
1986年 | 1篇 |
排序方式: 共有223条查询结果,搜索用时 31 毫秒
41.
42.
非标记夹心式电化学可卡因适体传感器的研究 总被引:1,自引:0,他引:1
设计一种基于双链核酸适体的非标记夹心式电化学适体传感器, 建立简单、高灵敏度的可卡因分析方法. 首先将末端巯基修饰的捕获适体探针组装在金电极表面, 构建可卡因适体传感器. 该传感器与目标分子可卡因和部分互补的检测适体探针作用后, 在电极表面形成适体/可卡因/适体复合物. 以六氨合钌为信号分子, 基于单链适体和适体/可卡因/适体复合物对六氨合钌吸附量的不同, 通过计时电量法检测电极表面吸附六氨合钌的还原电量, 进行可卡因的分析检测. 在优化的条件下, 还原电量与可卡因浓度在1~50 mmol/L范围内呈良好的线性关系, 检出限为0.1 mmol/L. 用于血清中可卡因的检测, 回收率为96.4%~104%. 该方法简单, 灵敏度高, 可作为一种通用型的适体传感器模型. 相似文献
43.
L. Liu Y. J. Shangguan H. B. Tang H. M. Wang 《Applied Physics A: Materials Science & Processing》2014,116(4):1993-2000
Fretting wear behavior of laser-nitrided titanium alloy (Ti–5Al–5Mo–5V–1Cr–1Fe) fabricated by laser melting deposition (LMD) has been investigated to explore surface engineering for protection against wear damage of laser melting deposited titanium alloy. The morphology and volume of the wear scars of unmodified and laser-nitrided LMD Ti–5Al–5Mo–5V–1Cr–1Fe tested at different frequencies, 10 and 50 Hz, were studied using non-contact three-dimensional surface profilometer and scanning electron microscope. Friction coefficients measured at different frequencies or loading forces were compared for unmodified and laser-nitrided LMD specimens. Experimental results show that laser-nitrided LMD specimens have shown fretting resistance superior to unmodified LMD specimens due to the presence of hard TiN dendrites in the laser-nitrided layer. W-shaped wear scar caused by local rotation of fretting ball at the two ends of the scar was observed. Given a constant loading force of 50 N, unmodified and laser-nitrided LMD specimens exhibited similar friction coefficients and their friction coefficients increased with test frequency. The friction coefficients of both specimens increased with the reduction of normal load, which corresponds to the trend in Hertzian contact model. 相似文献
44.
Qing‐Feng Zhang Hon‐Yeung Cheung Xinchen Shangguan Guodong Zheng 《Journal of separation science》2012,35(23):3347-3353
The complexation of five polyphenols, namely trans‐resveratrol, astilbin, taxifolin, ferulic acid, and syringic acid (guest molecules) with α‐, β‐, and γ‐cyclodextrin (host molecules), was investigated by capillary electrokinetic chromatography. The binding constants were calculated based on the effective electrophoretic mobility change of guests with the addition of cyclodextrins into the background electrolyte. Because of cavity size, cyclodextrins showed structure‐selective complexation property to different guest. The stability of the trans‐resveratrol complexes was in the order of β‐ > α‐ > γ‐cyclodextrin. The cavity size of α‐cyclodextrin was too small for astilbin and taxifolin molecules, and thus they could not form complexes. The molecular size of syringic acid was too big for all cyclodextrins cavity, and no cyclodextrin could form complexes with it. Temperature studies showed that the binding constants decreased with the rise of temperature. Enthalpy and entropy values were calculated and the negative values of these parameters indicated that the complexation process was enthalpy‐controlled. Van der Waals force and release of high‐enthalpy water molecules from the cyclodextrins cavity played important roles in the process. 相似文献
45.
Chen Zhou Matthew R. Hermes Dihua Wu Jie J. Bao Riddhish Pandharkar Daniel S. King Dayou Zhang Thais R. Scott Aleksandr O. Lykhin Laura Gagliardi Donald G. Truhlar 《Chemical science》2022,13(26):7685
Strong electron correlation plays an important role in transition-metal and heavy-metal chemistry, magnetic molecules, bond breaking, biradicals, excited states, and many functional materials, but it provides a significant challenge for modern electronic structure theory. The treatment of strongly correlated systems usually requires a multireference method to adequately describe spin densities and near-degeneracy correlation. However, quantitative computation of dynamic correlation with multireference wave functions is often difficult or impractical. Multiconfiguration pair-density functional theory (MC-PDFT) provides a way to blend multiconfiguration wave function theory and density functional theory to quantitatively treat both near-degeneracy correlation and dynamic correlation in strongly correlated systems; it is more affordable than multireference perturbation theory, multireference configuration interaction, or multireference coupled cluster theory and more accurate for many properties than Kohn–Sham density functional theory. This perspective article provides a brief introduction to strongly correlated systems and previously reviewed progress on MC-PDFT followed by a discussion of several recent developments and applications of MC-PDFT and related methods, including localized-active-space MC-PDFT, generalized active-space MC-PDFT, density-matrix-renormalization-group MC-PDFT, hybrid MC-PDFT, multistate MC-PDFT, spin–orbit coupling, analytic gradients, and dipole moments. We also review the more recently introduced multiconfiguration nonclassical-energy functional theory (MC-NEFT), which is like MC-PDFT but allows for other ingredients in the nonclassical-energy functional. We discuss two new kinds of MC-NEFT methods, namely multiconfiguration density coherence functional theory and machine-learned functionals.This feature article overviews recent work on active spaces, matrix product reference states, treatment of quasidegeneracy, hybrid theory, density-coherence functionals, machine-learned functionals, spin–orbit coupling, gradients, and dipole moments. 相似文献
46.
Zhao Meiyu Du Pin Liu Wei Du Kaifa Ma Yongsong Yin Huayi Wang Dihua 《Journal of Solid State Electrochemistry》2022,26(3):791-798
Journal of Solid State Electrochemistry - Making a tantalum carbide (TaC) coating on Ta substrates is an effective way to improve the mechanical and anti-corrosion properties of Ta. However,... 相似文献
47.
准晶的弹性,塑性与位错 总被引:12,自引:0,他引:12
本文较系统地综述了适合准晶的线弹性理论,准品位错的基本理论和实验鉴定,准晶位错的弹性理论,以及准晶高温塑性形变的微观机制。 相似文献
48.
用一种新合成的套索冠醚N,N′-双(乙酰苄胺)-二氮杂-18-冠-6作为固定相,涂渍在弹性石英毛细管内,测其柱效、惰性、热稳定性、平均极性及选择性等性质。实验表明,它具有良好的色谱性能,中等极性,分离选择性高,适用于对醇、卤代烃、芳香烃等各类异构体的分离,并从分子结构和热力学参数等探讨了保留机理。 相似文献
49.
Influence of Gas Components on the Formation of Carbonyl Sulfide over Water-Gas Shift Catalyst B303Q 总被引:1,自引:0,他引:1 下载免费PDF全文
Ju Shangguan Litong Liang Huiling Fan Fang Shen 《天然气化学杂志》2007,16(1):53-59
Water-gas shift reaction catalyst at lower temperature (200—400℃) may improve the conversion of carbon monoxide. But carbonyl sulfide was found to be present over the sulfided cobalt-molybdenum/alumina catalyst for water-gas shift reaction. The influences of temperature, space velocity, and gas components on the formation of carbonyl sulfide over sulfided cobalt-molybdenum/alumina catalyst B303Q at 200—400℃were studied in a tubular fixed-bed quartz-glass reactor under simulated water-gas shift conditions. The experimental results showed that the yield of carbonyl sulfide over B303Q catalyst reached a maximum at 220℃with the increase in temperature, sharply decreased with the increase in space velocity and the content of water vapor, increased with the increase in the content of carbon monoxide and carbon dioxide, and its yield increased and then reached a stable value with the increase in the content of hydrogen and hydrogen sulfide. The formation mechanism of carbonyl sulfide over B303Q catalyst at 200—400℃was discussed on the basis of how these factors influence the formation of COS. The yield of carbonyl sulfide over B303Q catalyst at 200-400℃was the combined result of two reactions, that is, COS was first produced by the reaction of carbon monoxide with hydrogen sulfide, and then the as-produced COS was converted to hydrogen sulfide and carbon dioxide by hydrolysis. The mechanism of COS formation is assumed as follows: sulfur atoms in the Co9S8-MOS2/Al2O3 crystal lattice were easily removed and formed carbonyl sulfide with CO, and then hydrogen sulfide in the water-gas shift gas reacted with the crystal lattice oxygen atoms in CoO-MoO3/Al2O3 to form Co9S8-MoS2/Al2O3. This mechanism for the formation of COS over water-gas shift catalyst B303Q is in accordance with the Mars-Van Krevelen's redox mechanism over metal sulfide. 相似文献
50.
Uniform-sized molecularly imprinted polymer for metsulfuron-methyl by one-step swelling and polymerization method 总被引:1,自引:0,他引:1
Uniform-sized molecularly imprinted polymer (MIP) beads for metsulfuron-methyl (MSM) were firstly prepared by one-step swelling and polymerization method using 4-vinylpyridine (4-VPY) and ethylene glycol dimethacrylate (EDMA) as functional monomer and cross-linker, respectively. The preparation was optimized by varying the ratio of MSM to 4-VPY. The chromatographic behaviors of MSM and other structurally related sulfonylureas (SUs) on the resultant MIP column were evaluated. The imprinted polymer revealed specific affinity to the template and the fair resolution of SUs was also obtained. Furthermore, the uniform-sized MSM-MIP was used as the solid phase extraction (SPE) material to enrich MSM in real water samples before reversed-phase HPLC (RP-HPLC) analysis. The recovery of MSM from 100 mL of drinking water at a 50 ng/L spike level was 99.59% with R.S.D. of 1.13%. The detection limit was about 6.0 ng/L of MSM when enriching a 100 mL water sample. 相似文献