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51.
Dr. Zhen Lei Zong‐Jie Guan Dr. Xiao‐Li Pei Shang‐Fu Yuan Xian‐Kai Wan Jin‐Yuan Zhang Prof.Dr. Quan‐Ming Wang 《Chemistry (Weinheim an der Bergstrasse, Germany)》2016,22(32):11156-11160
A red–near‐IR dual‐emissive nanocluster with the composition [Au10Ag2(2‐py?C≡C)3(dppy)6](BF4)5 ( 1 ; 2‐py?C≡C is 2‐pyridylethynyl, dppy=2‐pyridyldiphenylphosphine) has been synthesized. Single‐crystal X‐ray structural analysis reveals that 1 has a trigonal bipyramidal Au10Ag2 core that contains a planar Au4(2‐py?C≡C)3 unit sandwiched by two Au3Ag(dppy)3 motifs. Cluster 1 shows intense red–NIR dual emission in solution. The visible emission originates from metal‐to‐ligand charge transfer (MLCT) from silver atoms to phosphine ligands in the Au3Ag(dppy)3 motifs, and the intense NIR emission is associated with the participation of 2‐pyridylethynyl in the frontier orbitals of the cluster, which is confirmed by a time‐dependent density functional theory (TD‐DFT) calculation. 相似文献
52.
Xiao Hu An Zeng Ming-Sheng Shang 《The European Physical Journal B - Condensed Matter and Complex Systems》2016,89(2):46
Recommender system is an effective tool to find the most relevant information for onlineusers. By analyzing the historical selection records of users, recommender system predictsthe most likely future links in the user-item network and accordingly constructs apersonalized recommendation list for each user. So far, the recommendation process ismostly investigated in static user-item networks. In this paper, we propose a model whichallows us to examine the performance of the state-of-the-art recommendation algorithms inevolving networks. We find that the recommendation accuracy in general decreases with timeif the evolution of the online network fully depends on the recommendation. Interestingly,some randomness in users’ choice can significantly improve the long-term accuracy of therecommendation algorithm. When a hybrid recommendation algorithm is applied, we find thatthe optimal parameter gradually shifts towards the diversity-favoring recommendationalgorithm, indicating that recommendation diversity is essential to keep a high long-termrecommendation accuracy. Finally, we confirm our conclusions by studying therecommendation on networks with the real evolution data. 相似文献
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54.
采用固相反应法制备了系列样品TixNi1-xFe2O4 (x=0.0, 0.1, 0.2, 0.3, 0.4). 室温下的X射线衍射谱表明样品全部为(A)[B]2O4型单相立方尖晶石结构, 属于空间群Fd3m. 样品的晶格常数随Ti掺杂量的增加而增大. 样品在10 K温度下的比饱和磁化强度σS随着Ti掺杂量x的增加逐渐减小. 研究发现, 当Ti掺杂量x≥ 0.2时, 磁化强度σ随温度T的变化曲线出现两个转变温度TL和TN. 当温度低于TN时, 磁化强度明显减小; 当温度达到TN时, dσ/dT具有最大值. σ-T曲线的这些特征表明, 由于Ti掺杂在样品中出现了附加的反铁磁结构. 这说明样品中的Ti离子不是无磁性的+4价离子, 而是以+2和+3价态存在, 其离子磁矩的方向与Fe和Ni离子的磁矩方向相反. 利用本课题组提出的量子力学方势垒模型拟合样品在10 K温度下的磁矩, 得到了Ti, Fe和Ni三种阳离子在(A)位和[B]位的分布情况, 并发现在所有掺杂样品中, 80%的Ti离子以+2价态占据尖晶石结构的[B]位. 相似文献
55.
56.
以溶胶凝胶法合成的高纯Li_(1.4)Al_(0.4)Ti_(1.6)(PO_4)_3(LATP)纳米晶体粉末为原料,通过流延法成膜,在950℃下煅烧5 h合成LATP固态电解质片;对其进行环氧树脂改性后,能量色散X射线光谱元素图像表明环氧树脂完全浸入LATP内部,可以有效防止水渗透.研究发现流延法合成的LATP固态电解质在25℃?C时电导率高达8.70×10~(-4)S·cm~(-1)、活化能为0.36 eV、相对密度为89.5%.经过环氧树脂改性后电导率仍高达3.35×10-4S·cm-1、活化能为0.34 e V、相对密度为93.0%.高电导隔水的环氧树脂改性LATP固态电解质可作为锂金属保护薄膜用于新型高比容量电池. 相似文献
57.
制备了一系列V,Ag,Ni原子比不同的三元氧化物,应用TPD-MS技术研究了样品表面氧的性质,并测定了甲苯选择性氧化生成苯甲醛的催化活性。实验结果表明,样品表面存在有多种吸附的氧物种。在脱附温度<900℃:当Ni含量对Ag(或V)的原子比为0.25或0.50时,仅在低温处出现有表面的O^-和O^2^-两种氧物种的脱附峰;当Ni含量对Ag(或V)的原子比增高到>0.75时,除有表面的O^-和O^2^ 相似文献
58.
Lemuel B. Wingard James F. Castner Shang J. Yao Sidney K. Wolfson Allan L. Drash Chung C. Liu 《Applied biochemistry and biotechnology》1984,9(1):95-104
Previous work has shown that glucose oxidase can be immobilized on platinum to give an electrode that responds potentiometrically to glucose over the clinically useful range of about 10-250 mg glucose/100 mL. The present studies were carried out with electrochemically pretreated platinum and with gold or porous graphite substituted for the platinum support. The presence of the enzyme gave a significantly enhanced potentiometric response over that obtained with the bare support for both the pretreated platinum and the porous graphite, but not with gold. However, with platinum the potentiometric response became more negative with increasing glucose concentration. With porous graphite, the potential changed in the positive direction as the glucose concentration was increased. Hysteresis was demonstrated for the platinum-enzyme electrode. Mass transfer measurements with a rotating ring-disc electrode (RRDE) showed measurable diffusional resistances to the transport of a model electroactive compound (potassium ferrocyanide) through a matrix of immobilized enzyme attached to the disc of the RRDE. These results are part of a larger study to define the source of the potentiometric response by examining the roles of the support and the mass transfer resistances through the immobilized enzyme matrix. 相似文献
59.
Synthesis, Characterization and Thermal Decomposition Mechanism of Cetyltrimethyl Ammonium Tetrathiotungstate 总被引:2,自引:0,他引:2
Gaojun An Yunqi Liu Yongming Chai Hongyan Shang Chenguang Liu 《天然气化学杂志》2006,15(2):127-133
The synthesis, characterization and thermal decomposition mechanism of cetyltrimethyl ammonium tetrathiotungstate (CTriMATT) were studied herein. The as-synthesized CTriMATT was characterized by Elemental analysis, X-ray diffraction (XRD), Fourier transform infrared (FT-IR), Ultraviolet visible (UV-Vis) spectra. The results showed that the as-synthesized CTriMATT had high purity and good crystallinity. The introduction of alkyl groups induced a shift of the stretching vibration band of W-S bond to lower wavenumber, while it had no influence on the position of WS4^2-. Thermogravimetric analysis (TG), differential thermal analysis (DTA) and in situ XRD characterizations revealed that CTriMATT began to decompose at 423 K in nitrogen and was converted to WS2 eventually. In addition, the decomposition product of CTriMATT at 673 K in nitrogen was characterized by N2 adsorption (BET) and scanning electron microscopy (SEM). The results demonstrated that WS2 with higher specific surface area, and pore volume could be obtained from the thermal decomposition of CTriMATT in nitrogen. 相似文献
60.
The polysiloxane-based alicyclic episulfide resin (PSCER) was synthesized through substitution of oxygen atoms in 1,3-bis[2-(3{7-oxabicyclo[4,1,0]hepyl})ethyl]-tetramethyldisiloxane with sulfur atoms using potassium thiocyanate (KSCN) as the reagent. The product was purified by column chromatography, and the by-products were isolated. It was found by 1H-NMR and 13C-NMR that the by-products were cycloolefins formed by desulfurization of the episulfide groups. PSCER was unstable; desulfurization took place easily, especially at high temperatures. The PSCER resin could not be cured with methylhexahydrophthalic anhydride (MeHPPA). When m-phenylenediamine or isophorondiamine was used as curing agent, PSCER showed a higher reactivity compared with the parent epoxide. However, the reactivity of the alicyclic episulfide was much lower than the polysiloxane based aliphatic episulfide for the steric hindrance of the six member ring. Desulfurization took place upon curing of the alicyclic episulfide resin, therefore the cured resin showed poor mechanical properties. Thermal stability of cured PSCER resin was also poor on account of low bonding energy of C-S and crosslinking density. 相似文献