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51.
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Keqing Han Xiong Zhang Shan Zhan Muhuo Yu 《Journal of Macromolecular Science: Physics》2013,52(2):225-235
A series of polyamide 6/hyperbranched polymers (PA6/HBP) blends with different HBP contents was prepared by melt processing using a twin-screw extruder. The HBP was synthesized on the basis of pentaerythritol and dimethyl terephthalate according to a one-step method. The melt flow behavior, crystallization behavior, morphology, and mechanical properties of the PA6/HBP blends were investigated. The results showed that the melt flow index of the blends was greatly improved by a small amount of HBP. The yield strength, tensile modulus, Izod impact strength, and flexural strength of samples were simultaneously enhanced from 54.6 MPa, 0.5 GPa, 3.8 kJ/m2, 56.9 MPa for pure PA6 to 61.1 MPa, 0.7 GPa, 5.3 kJ/m2, 67.1 MPa for PA6 blends with 2.0 wt% HBP, respectively. The PA6/HBP blends showed the higher content of α-form crystal and a higher degree of crystallinity than those of pure PA6. 相似文献
53.
Shan Liu Shuhao Qin Zhu Luo Jie Yu Jianbing Guo Min He 《Journal of Macromolecular Science: Physics》2013,52(9):1780-1790
The effect on the notched Izod impact strength of poly(butylene terephthalate) (PBT) by blending it with acrylonitrile-styrene-acrylate (ASA) was examined. Epoxy resin (ER) was demonstrated to be an efficient compatibilizer for the partially compatible blends of PBT/ASA. It requires only a very small amount of ER to improve the toughness of the PBT/ASA blends drastically. Furthermore, there exists an optimum proportion of ER added to achieve maximum notched Izod impact strength. Transmission electron microscopy (TEM) observation suggests that the ER in the PBT/ASA/ER blends suppressing the tendency of coalescence of ASA, leading to better dispersion of the ASA particles. Field emission scanning electron microscopy (FESEM) shows that ER enhances the phase dispersion and the interfacial adhesion between the PBT and ASA phases, it improves the compatibility between PBT and ASA. The compositions in the interphase was continuous, which results in multiphase composites with a graded interphase. It is suggested that enhanced interphase adhesion was necessary to obtain improved dispersion, fine phase morphology, and better toughness. 相似文献
54.
In this paper, we model natural gas market volatility using GARCH-class models with long memory and fat-tail distributions. First, we forecast price volatilities of spot and futures prices. Our evidence shows that none of the models can consistently outperform others across different criteria of loss functions. We can obtain greater forecasting accuracy by taking the stylized fact of fat-tail distributions into account. Second, we forecast volatility of basis defined as the price differential between spot and futures. Our evidence shows that nonlinear GARCH-class models with asymmetric effects have the greatest forecasting accuracy. Finally, we investigate the source of forecasting loss of models. Our findings based on a detrending moving average indicate that GARCH models cannot capture multifractality in natural gas markets. This may be the plausible explanation for the source of model forecasting losses. 相似文献
55.
用准经典轨线法研究原子-原子离子反应N+NH+(0,0)→H++N2(v’,j’)。这是一个放能的无阈能反应,且存在平均振动能随初始平动能升高而线性下降的特点。基于对势能面的分析,成功地解释了反应机理。 相似文献
56.
Upgrade of beamline BL08B at Taiwan Light Source from a photon‐BPM to a double‐grating SGM beamline 下载免费PDF全文
Jih‐Young Yuh Shan‐Wei Lin Liang‐Jen Huang Hok‐Sum Fung Long‐Life Lee Yu‐Joung Chen Chiu‐Ping Cheng Yi‐Ying Chin Hong‐Ji Lin 《Journal of synchrotron radiation》2015,22(5):1312-1318
During the last 20 years, beamline BL08B has been upgraded step by step from a photon beam‐position monitor (BPM) to a testing beamline and a single‐grating beamline that enables experiments to record X‐ray photo‐emission spectra (XPS) and X‐ray absorption spectra (XAS) for research in solar physics, organic semiconductor materials and spinel oxides, with soft X‐ray photon energies in the range 300–1000 eV. Demands for photon energy to extend to the extreme ultraviolet region for applications in nano‐fabrication and topological thin films are increasing. The basic spherical‐grating monochromator beamline was again upgraded by adding a second grating that delivers photons of energy from 80 to 420 eV. Four end‐stations were designed for experiments with XPS, XAS, interstellar photoprocess systems (IPS) and extreme‐ultraviolet lithography (EUVL) in the scheduled beam time. The data from these experiments show a large count rate in core levels probed and excellent statistics on background normalization in the L‐edge adsorption spectrum. 相似文献
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Aiming at the poor detection rate of multi-frequency weak signals under a strong background of noise, a novel method based on adaptive stochastic resonance (SR) theory is proposed in this paper. The optimal parameters can be obtained automatically via measurement by establishing an adaptive SR system model and using the reverse location method. After passing through the adaptive SR system, the spectrum values of all eight signals greatly improve, the largest spectrum value gain increases from 12.41 to 2033 when the frequency is 0.01?Hz, which is an improvement of a factor of 162.8, and the signal-to-noise ratio (SNR) gain of the whole system is 10.3134?dB. Under the condition of different input noise intensities and signal amplitudes, the mean SNR of the system increases from –13.1136 to –2.7614?dB, which is a 78.9% increase, and the largest SNR gain is 13.4702?dB when the noise intensity D?=?1.2 and signal amplitude A?=?0.11. Compared to the single optimal spectrum value, when defining multiple optimum spectrum values as the SNR criterion, the detection sensitivity is less than 0.35 when the input noise intensity is between 0.5 and 2.5, and the sensitivity value is 6.29 times higher when D?=?2.5. The system successfully realizes the adaptive detection of twelve weak signals, and the SNR gain is 7.9743?dB, which improves the channel capacity of signal detection. The experimental results demonstrate the high efficiency and strong applicability of the system, improving the signal processing efficiency and speed of signal transmission. 相似文献
59.
本文阐述了在中国原子能科学研究院“天光一号”KrF激光核聚变实验装置上,MOPA系统光学元件加工与镀膜研究工作的进展。实验测量结果表明,加工后的基片表面均方根粗糙度对于K9光学玻璃与熔融石英玻璃来说分别为σrms=1.8±0.5nm,σrms=2.0±0.4nm。镀HfO2/SiO2高反射膜的光学元件的反射率与破坏阈值分别为R>99.5%,Eth=1.30~1.33J/cm2。镀Al2O3/MgF2增透膜的光学元件的透射率与破坏阈值分别为T>99.5%,Eth=1.3~1.97J/cm2。 相似文献
60.