Second-harmonic generation in thermally poled chalcohalide glass

Second-harmonic generation in 60GeS(2)-20Ga(2)S(3)-20KBr chalcohalide glass was investigated by the thermal poling method. A large second-order nonlinear susceptibility, as high as 7.0 pm/V, was obtained in a poled sample by Maker fringe analysis. We believe this to be the first time that a clear second-harmonic wave was observed in chalcohalide glasses containing large amount of alkali ions (6.25 at. %). Such observation is of great potential use in all optical waveguide devices.     

Small amplitude ion-acoustic double layers with cold electron beam and q-nonextensive electrons

Small amplitude ion-acoustic double layers in an unmagnetized and collisionless plasma consisting of cold positive ions, q-nonextensive electrons, and a cold electron beam are investigated. Small amplitude double layer solution is obtained by expanding the Sagdeev potential truncated method. The effects of entropic index q, speed and density of cold electron beam on double layer structures are discussed.     

基于Parzen窗的油液原子光谱数据半监督FCM聚类研究

提出了一种基于Parzen窗的半监督模糊C-均值(Semi-supervised Fuzzy C-Means Based on Parzen window,PSFCM)聚类算法。根据训练样本确定出模糊C-均值(Fuzzy C-Means,FCM)的初始聚类中心;利用Parzen窗法计算出测试样本对各类状态的隶属度后,重新定义了隶属度迭代公式。通过齿轮箱磨损实验台模拟了齿轮箱的2种典型磨损故障并采集了油样。选取实验油样光谱分析数据中代表性元素Fe,Si,B的浓度值作为分析数据集的3维特征量,分别进行了FCM聚类和PSFCM聚类分析。聚类结果为:FCM聚类的正确率为48.9%,而融入了监督信息的PSFCM聚类的正确率为97.4%。实验说明,将PSFCM算法引入到油液原子光谱分析,降低了对人为经验和大量故障数据的依赖,提高了齿轮箱磨损故障诊断的准确度。     

应变对层状锰系锂离子电池正极材料输出电压的影响

利用第一性原理方法系统研究了不同应 变模式对LiMnO₂和Li₂MnO₃输出电压的影响, 建立了输出电压与弹性常数及应变之间的关系. 发现所有应变对输出电压都是降低的, 且应变效应是各向异性的. 大部分的单轴应变5%时对输出电压的降低都小于0.1 V. 由于层状的电极材料层间的键合作用较弱, 且受脱锂后形成的锂空位影响较大, 当从锂层脱出锂时, 垂直于层方向的应变对输出电压影响较大; 而对Li₂MnO₃系统从过渡金属层中脱锂时, 平行于层的应变对输出电压影响更大. Li₂MnO₃骨架支撑的层状固溶体系中, 应变使高电压充电阶段的电压维持在截断电压之下, 并打开过渡金属层中锂的迁移通道, 产生较为持久的充电而可能获得较大的充电容量.     

Distortion of optical feedback signals in microchip Nd:YAG lasers subjected to external multi-beam interference feedback

This paper proposes a theoretical analysis for the characteristics of an external cavity Nd:YAG laser with feedback of multiple-beam interference, which is induced by the multi-reentrance of the light from the external Fabry--Perot cavity. The theoretical model considers the multiple beam interference of the external Fabry--Perot cavity. It is found that the optical feedback signals are distorted to pulse waveforms instead of the sinusoidal ones in conventional feedback. The experimental results are in good agreement with the theoretical analysis. The obtained theoretical and experimental results can advance the development of a laser feedback interferometer.     

Electron-mediated ferromagnetism in Fe-doped InP: Theory and experiment

We report on the electron-mediated ferromagnetism in Fe-doped InP from both first-principles calculations and experiments. Theoretically, based on the spin-polarized density functional theory within the Heyd-Scuseria-Ernzerhof (HSE03) approach, we systematically investigate the magnetic properties of Fe-doped InP and predict the existence of electron-mediated ferromagnetism. Experimentally, by diffusing Fe into the n-type InP wafer with thermal annealing at 800 C, we observe room-temperature ferromagnetism in InP:Fe, which is in agreement with the theoretical prediction.     

Enhanced luminescence of Tb by efficient energy transfer from Ce in Sr2B5O9Cl host

Ce³⁺ and Tb³⁺ co-doped Sr₂B₅O₉Cl phosphors with intense green emission were prepared by the conventional high-temperature solid-state reaction technique. A broad band centered at about 315 nm was found in phosphor Sr₂B₅O₉Cl: Ce³⁺, Tb³⁺ excitation spectrum, which was attributed to the 4f-5d transition of Ce³⁺. The typical sharp line emissions ranging from 450 to 650 nm were originated from the ⁵D₄ → ⁷F_J (J = 6, 5, 4, 3) transitions of Tb³⁺ ions. The photoluminescence (PL) intensity of green emission from Tb³⁺ was enhanced remarkably by co-doping Ce³⁺ in the Tb³⁺ solely doped Sr₂B₅O₉Cl phosphor because of the dipole-dipole mechanism resonant energy transfer from Ce³⁺ to Tb³⁺ ions. The energy transfer process was investigated in detail. In light of the energy transfer principles, the optimal composition of phosphor with the maximum green light output was established to be Sr_1.64Ce_0.08Tb_0.1Li_0.18B₅O₉Cl by the appropriate adjustment of dopant concentrations. The PL intensity of Tb³⁺ in the phosphor was enhanced about 40 times than that of the Tb³⁺ single doped phosphor under the excitation of their optimal excitation wavelengths.     

Evidence for strain glass in the ferroelastic-martensitic system Ti(50-x)Ni(50+x)

We report here "strain glass," a new glassy phenomenon in ferroelastic-martensitic system of Ni-rich intermetallic Ti(50-x)Ni(50+x) (x > 1), where local strain is frozen in disordered configuration below a critical temperature Tg. The ac elastic modulus shows a minimum at Tg, which exhibits logarithmic frequency dependence following Vogel-Fulcher relationship, and the corresponding internal friction shows a frequency-dependent peak located at a lower temperature. In situ high-resolution transmission electron microscopy observations reveal uncorrelated nanoclusters of martensiticlike phase, randomly frozen in the otherwise untransformed parentlike matrix. Being parallel to spin glass and relaxor, strain glass may shed new light on the fundamental physics of glass and lead to the discovery of novel properties.     

Physical states and BRST operators for higher-spin <Emphasis Type="Italic">W</Emphasis> strings

In this paper, we mainly investigate the W _2,s ^M ⊗ W _2,s ^L system, in which the matter and the Liouville subsystems generate the W _2,s ^M and W _2,s ^L algebras, respectively. We first give a brief discussion of the physical states for the corresponding W strings. The lower states are given by freezing the spin-2 and spin-s currents. Then, introducing two pairs of ghost-like fields, we give the realizations of the W _1,2,s algebras. Based on these linear realizations, the BRST operators for the W _2,s algebras are obtained. Finally, we construct new BRST charges of the Liouville system for the W _2,s ^L strings at the specific values of the central charges c: for the W _2,3^L algebra, c=−24 for the W _2,4^L algebra and for the W _2,6^L algebra, at which the corresponding W _2,s ^L algebras are singular.     

丁酮分子内价轨道1a″的电子动量谱学研究

用高分辨率电子动量谱仪进行丁酮分子的结合能谱和内价轨道1a″电子动量谱的实验工作，以及用Hartree-Fock和密度泛函理论方法对1a″轨道电子动量谱的理论研究. 得到了各价轨道的电离能值以及理论计算的总能、偶极矩和1a″轨道的二维密度图. 并比较了内价轨道1a″的电子动量谱的实验和理论计算结果，实验结果与理论计算符合较好.