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11.
The photocatalytic degradation of a herbicide derivative, 2,4-dichlorophenoxy acetic acid (2,4-D, 1), has been investigated in aqueous suspensions of titanium dioxide. The degradation was studied by monitoring the change in substrate concentration employing UV spectroscopic analysis and decrease in Total Organic Carbon (TOC) content as a function of irradiation time in the presence of UV light source. The degradation kinetics was investigated under a variety of conditions, such as different types of TiO2, pH, catalyst and substrate concentrations. Higher photonic efficiencies were observed with Degussa P25 as compared with other photocatalysts. The degradation products were analysed by GC-MS and probable pathways for the formation of different products were proposed. 相似文献
12.
A model of two interacting (chemically different) linear polymer chains is solved exactly using the real-space renormalization
group transformation on a family of Sierpinski gasket type fractals and on a truncated 4-simplex lattice. The members of the
family of the Sierpinski gasket-type fractals are characterized by an integer scale factorb which runs from 2 to ∞. The Hausdorff dimensiond
F of these fractals tends to 2 from below asb → ∞. We calculate the contact exponenty for the transition from the State of segregation to a State in which the two chains are entangled forb = 2-5. Using arguments based on the finite-size scaling theory, we show that forb→∞, y = 2 - v(b) d
F, wherev is the end-toend distance exponent of a chain. For a truncated 4-simplex lattice it is shown that the system of two chains
either remains in a State in which these chains are intermingled in such a way that they cannot be told apart, in the sense
that the chemical difference between the polymer chains completely drop out of the thermodynamics of the system, or in a State
in which they are either zipped or entangled. We show the region of existence of these different phases separated by tricritical
lines. The value of the contact exponenty is calculated at the tricritical points. 相似文献
13.
Applying tight-binding approximation and spin pairing of like charge carriers in a pair of excitons created in a lattice, the possibility of forming a bound exciton-exciton state is studied. It is found that, provided there exists strong exciton-lattice interaction, such a bound state may be formed and its energy may lie within the valence band deforming the material into a crystalline solid with no energy gap. Lowering of the energy is calculated in naphthalene and anthracene crystals where some experimental results are known. The excess energy released after the formation of such bound state can be adequate, depending on the material, to desorb neutral atoms or eject of electrons from surfaces. 相似文献
14.
The object of the present investigation is to introduce a new trigonometric method of summation which is both regular and
Fourier effective and determine its status with reference to other methods of summation (see §2-§4) and also give an application
of this method to determine the degree of approximation in a new Banach space of functions conceived as a generalized Holder
metric (see §5). 相似文献
15.
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17.
Synchronized whistlers recorded at Varanasi 总被引:1,自引:0,他引:1
Some interesting events of synchronized whistlers recorded at low latitude station Varanasi during magnetic storm period of
the year 1977 are presented. The dynamic spectrum analysis shows that the component whistlers are Eckersley whistlers having
dispersion 10 s1/2 and 30 s1/2. An attempt has been made to explain the dynamic spectra using lightning discharge generated from magnetospheric sources 相似文献
18.
C.P. Paul P. Ganesh S.K. Mishra P. Bhargava J. Negi A.K. Nath 《Optics & Laser Technology》2007,39(4):800-805
This paper presents an investigation of laser rapid manufacturing (LRM) for Inconel-625 components. LRM is an upcoming rapid manufacturing technology, it is similar to laser cladding at process level with different end applications. In general, laser-cladding technique is used to deposit materials on the substrate either to improve the surface properties or to refurbish the worn out parts, while LRM is capable of near-net shaping the components by layer-by-layer deposition of the material directly from CAD model. In the present study, a high-power continuous wave (CW) CO2 laser system, integrated with a co-axial powder-feeding system and a three-axis workstation were used. The effect of processing parameters during LRM of Inconel-625 was studied and the optimum set of parameters for the maximum deposition rate was established employing Orthogonal L9 array of Taguchi technique. Results indicated that the powder feed rate and the scan speed contributed about 56% and 26%, respectively to the deposition rate, while the influence of laser power was limited to 10% only. Fabricated components were subjected to non-destructive testing (like—ultrasonic testing, dye-penetrant testing), tensile testing, impact testing, metallographic examinations and micro-hardness measurement. The test results revealed defect-free material deposition with improved mechanical strength without sacrificing the ductility. 相似文献
19.
Shyam K. Singh Oliver S. Fetzer John B. Hynes Thomas C. Williams 《Journal of heterocyclic chemistry》1991,28(5):1459-1461
Nitration of 2-amino-4-oxo-(3H)-5-trifluoromethylquinazoline is shown to occur exclusively at C6 as determined from an analysis of long range 1H and 19F scalar couplings to ring carbons. Nitration of 2-amino-4-oxo-(3H)-5-fluoroquinazoline is found to occur both at C6 and C8 as evident from an analysis of the 19F and 1H couplings of the ring protons. 相似文献
20.
The occurrence of charge on recoil56Mn produced by the (n,γ) reaction in polycrystalline potassium permanganate has been examined using the ‘charge plate technique’.
From considerations of capture gamma ray decay schemes and internal conversion it appears that, in a condensed medium, the
recoil atom develops charge after losing much of its initial kinetic energy which allows collection on charged electrodes.
Preliminary findings were presented at the International Symposium on Radiochemistry and Radiation Chemistry, RC-41 BARC,
Bombay, Feb. 4–6 (1991). 相似文献