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61.
62.
Prins F Shaikh AJ van Esch JH Eelkema R van der Zant HS 《Physical chemistry chemical physics : PCCP》2011,13(32):14297-14301
We present the formation of single-molecule devices based on nanometre-spaced platinum electrodes. The electrodes are fabricated using a self-breaking electromigration method which yields nanogaps with long-term stability at room temperature [Prins et al., APL, 2009, 94, 123108.]. The stability at room temperature allows for detailed comparison of the device electrical properties before and after deposition of the molecules. In this way, conductance as a result of direct tunneling between the electrodes can be distinguished from conductance through the molecule. After molecule deposition, some devices display transport in the strong coupling regime while others are in the weak-coupling Coulomb blockade regime. Gated transport is observed in the latter case. 相似文献
63.
A new series of antibacterial and antifungal isatin bearing sulfonamides and their cobalt (II), copper (II), nickel (II) and zinc (II) metal complexes have been synthesized, characterized and screened for their in vitro antibacterial activity against Bacillus cereus, Corynebacterium diphtheriae, Escherichia coli, Klebsiella pneumoniae, Proteus mirabilis, Pseudomonas aeruginosa, Salmonella typhi, Shigilla dysentriae and Staphylococcus aureus and for in vitro antifungal activity against Trichophyton schoenleinii, Candid glabrata, Pseudallescheria boydii, Candida albicans, Aspergillus niger, Microsporum canis and Trichophyton mentagrophytes. The results of these studies revealed that all compounds showed moderate to significant antibacterial activity. The brine shrimp bioassay was also carried out to study their in vitro cytotoxic properties. Only three compounds, 2, 11 and 22 displayed potent cytotoxic activity as LD50 = 1.56 × 10?7, 1.59 × 10?7 and 1.67 × 10?7 M /ml respectively, against Artemia salina. Copyright © 2006 John Wiley & Sons, Ltd. 相似文献
64.
Tanveer M. Shaikh 《Tetrahedron letters》2005,46(33):5589-5592
NaIO4 oxidizes lithium bromide efficiently under acidic conditions to functionalize alkylbenzenes and alkanes and produce the corresponding bromo and acetoxy derivatives in excellent yields. The protocol also demonstrates the direct conversion of cyclohexane into trans-1,2-dibromocyclohexane in moderate yield. 相似文献
65.
Shaikh A. Matin 《Applied Scientific Research》1966,15(1):137-140
Summary In this note a yield criterion and its associated stress-strain increment relations dependent on isotropic pressure, are presented, for a non-hardening elastic-plastic compressible material. 相似文献
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Novel alpha-hydrazino-alpha,beta-unsaturated nitroalkenes, which exhibit dynamic phenomenon on the NMR time scale, were synthesized in excellent yields via imidazole or DMAP mediated Morita-Baylis-Hillman (MBH) type reaction of nitroalkenes with azodicarboxylates. 相似文献
69.
Dastgeer Shaikh 《Physics letters. A》2010,374(25):2551-2554
We develop a nonlinear two-dimensional fluid model of whistler turbulence that includes effect of electron fluid density perturbations. The latter is coupled nonlinearly with wave magnetic field. This coupling leads essentially to finite compressibility effects in whistler turbulence model. We find from our simulations that despite strong compressibility effects, the density fluctuations follow the evolution of the wave magnetic field fluctuations. In a characteristic regime where large scale whistlers are predominant, the coupled density fluctuations are found to follow a Kolmogorov-like phenomenology in the inertial range turbulence. Consequently, the turbulent energy is dominated by the large scale (compared to electron inertial length) eddies and it follows a Kolmogorov-like k−7/3 spectrum, where k is a characteristic wavenumber. 相似文献
70.
A perturbed hard-sphere equation of state (EOS) has been previously employed to predict pressure–volume–temperature properties
of some ionic liquids (ILs) with phosphonium-, pyridinium-, and pyrrolidinium cations. In this work, we have extended the
considered EOS to another class of ILs in compressed states. This class consists of 14 imidazolium-based ILs. The predicted
densities were compared with those obtained from the experiment, over a broad pressure range from 0.1 to 200 MPa. From 1,122
data points examined for the aforementioned ILs, the total average absolute deviation was found to be 1.05%. 相似文献