Fluorescent zinc(II) complex exhibiting "on-off-on" switching toward Cu2+ and Ag+ ions

Binuclear zinc(II) and copper(II) complexes based on a new Schiff base ligand N,N'-bis(2-hydroxybenzilidene)-2,4,6-trimethylbenzene-1,3-diamine (H(2)L) have been synthesized. The ligand H(2)L and complexes under investigation have been characterized by elemental analyses, spectral (FT-IR, (1)H, (13)C NMR, ESI-MS, electronic absorption, emission), and electrochemical studies. The structures of H(2)L and complexes [{Zn(C(23)H(18)N(2)O(2))}(2)] (1) and [{Cu(C(23)H(18)N(2)O(2))}(2)]·H(2)O (2) have been determined crystallographically. Selective "On-Off-On" switching behavior of the fluorescent complex 1 has been studied. The fluorescence intensity of 1 quenches (turns-off) upon addition of Cu(2+), while enhances (turns-on) in the presence of Ag(+) ions. The mechanisms of "On-Off-On" signaling have been supported by (1)H NMR, ESI-MS, electronic absorption, and emission spectral studies. Job's plot analysis supported 1:1 and 1:2 stoichiometries for Cu(2+) and Ag(+) ions, respectively. Association and quenching constants have been estimated by the Benesi-Hildebrand method and Stern-Volmer plot. Moreover, 1 mimics a molecular keypad lock that follows correct chemical input order to give maximum output signal.     

Adsorption of acid yellow dye on flakes of chitosan prepared from fishery wastes

Chitosan flakes, extracted from prawns and labeo rohita scales, with high adsorption capacity were prepared after chemical treatment and were used to remove acid yellow dye from water. The results showed that adsorption capacity is dependent on pH, initial concentration of dye, BET, Langmuir surface area and pore volume of the adsorbent. In acidic conditions, the polymer amino groups were protonated (positively charged polymer chain), which showed attraction with negative ions of anionic dye. Chitosan from prawns scales showed higher dye adsorption under the same experimental conditions. Adsorption isotherms were developed and equilibrium data fitted well to Langmuir and Freundlich isotherm models.     

Effects of exponential volume fraction law on the natural frequencies of FGM cylindrical shells under various boundary conditions

In the present work, vibration characteristics of thin functionally graded cylindrical shells are studied under the influence of various boundary conditions. Fabrication of FGM cylindrical shell is carried out by using exponential volume fraction law. Strain- and curvature-displacements relationships are taken from Love’s thin shell theory. The frequency equation in the form of eigenvalue problem is obtained by adapting the Rayleigh-Ritz method. Characteristic beam functions are assumed to approximate the axial modal dependence. Effects of exponential volume fraction law on the natural frequencies of the FGM cylindrical shells for various boundary conditions are studied against circumferential wave number, length to radius ratio and thickness to radius ratio for different values of power law exponents. Results evaluated show good agreement with those available in the literature.     

On the unsteady rotational flow of a generalized Maxwell fluid through a circular cylinder

In this paper, the velocity field and the associated tangential stress corresponding to the rotational flow of a generalized Maxwell fluid within an infinite circular cylinder are determined by means of the Laplace and finite Hankel transforms. Initially, the fluid is at rest, and the motion is produced by the rotation of the cylinder about its axis with a unsteady angular velocity. The solutions that have been obtained are presented under series form in terms of the generalized G _a,b,c (, t)-functions. The similar solutions for the ordinary Maxwell and Newtonian fluids, performing the same motion, are obtained as special cases, when β → 1, respectively β → 1 and λ → 0, from general solutions. Finally, the solutions that have been obtained are compared by graphical illustrations, and the influence of the pertinent parameters on the fluid motion is also underlined by graphical illustrations.     

Exact analytical solutions for axial flow of a fractional second grade fluid between two coaxial cylinders

The velocity field and the adequate shear stress corresponding to the longitudinal flow of a fractional second grade fluid, between two infinite coaxial circular cylinders, are determined by applying the Laplace and finite Hankel transforms. Initially the fluid is at rest, and at time t = 0⁺, the inner cylinder suddenly begins to translate along the common axis with constant acceleration. The solutions that have been obtained are presented in terms of generalized G functions. Moreover, these solutions satisfy both the governing differential equations and all imposed initial and boundary conditions. The corresponding solutions for ordinary second grade and Newtonian fluids are obtained as limiting cases of the general solutions. Finally, some characteristics of the motion, as well as the influences of the material and fractional parameters on the fluid motion and a comparison between models, are underlined by graphical illustrations.     

On $$\gamma $$ γ - and local $$\gamma $$ γ -vectors of the interval subdivision

Journal of Algebraic Combinatorics - We show that the $$\gamma $$ -vector of the interval subdivision of a simplicial complex with a nonnegative and symmetric h-vector is nonnegative. In...     

The growth of nanoscale periodic and dot-like structures on the surface of stainless steel with femtosecond laser pulses in the dry and wet ambient environment

The present work deals with growth of nanoscale periodic and dot-like structures on the surface of stainless steel (SS) by the irradiation of femtosecond laser pulses. For this purpose Ti: Sapphire femtosecond laser pulses (wavelength of 800 nm, pulse length of 25 fs and pulse repetition rate of 1 kHz) were employed in a dry (air) and liquid confined (deionized water and ethanol) environments. The targets were exposed to 1000 succeeding pulses for various fluences ranging from 50 to 150 mJ?cm^?2. Nanoscale structures including ripples, and dots were observed by SEM analysis. The growth and dependence of structure-formation on the ambient environment and laser fluence in both central as well as peripheral ablated areas is systematically investigated. The development of nanostructures and nanoripples is correlated with structural analysis carried out by micro Raman spectroscopy.     

Evaluating Parallel Simulated Evolution Strategies for VLSI Cell Placement

Simulated Evolution (SimE) is an evolutionary metaheuristic that has produced results comparable to well established stochastic heuristics such as SA, TS and GA, with shorter runtimes. However, for optimization problems with a very large set of elements, such as in VLSI cell placement and routing, runtimes can still be very large and parallelization is an attractive option for reducing runtimes. Compared to other metaheuristics, parallelization of SimE has not been extensively explored. This paper presents a comprehensive set of parallelization approaches for SimE when applied to multiobjective VLSI cell placement problem. Each of these approaches are evaluated with respect to SimE characteristics and the constraints imposed by the problem instance. Conclusions drawn can be extended to parallelization of SimE when applied to other optimization problems.