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排序方式: 共有175条查询结果,搜索用时 21 毫秒
101.
Karimi Zarchi Mohammad Ali Darbandizadeh Mohammad Abadi Seyed Shahab Addin 《Research on Chemical Intermediates》2019,45(5):2605-2639
Research on Chemical Intermediates - Facile and efficient protocols for some multicomponent coupling reactions such as the Suzuki reaction and synthesis of polyhydroquinoline and... 相似文献
102.
Sarkar D Sullivan S Joudaki S Amblard A Holz DE Cooray A 《Physical review letters》2008,100(24):241302
Our ignorance of dark energy is generally described by a two-parameter equation of state. In these approaches, a particular ad hoc functional form is assumed, and only two independent parameters are incorporated. We propose a model-independent, multiparameter approach to fitting dark energy and show that next-generation surveys will constrain the equation of state in three or more independent redshift bins to better than 10%. Future knowledge of dark energy will surpass two numbers (e.g., [w{0},w{1}] or [w{0},w{a}]), and we propose a more flexible approach to the analysis of present and future data. 相似文献
103.
Derakhshan S Kleinke KM Dashjav E Kleinke H 《Chemical communications (Cambridge, England)》2004,(21):2428-2429
HfMoSb4, isostructural with the isoelectronic NbSb2, exhibits nonmetallic properties, as predicted via electronic structure calculations made before the actual discovery of HfMoSb4. 相似文献
104.
Maryam Ganjikhah Shahab Shariati Elahe Bozorgzadeh 《Journal of the Iranian Chemical Society》2017,14(4):763-769
Formaldehyde is known as a highly toxic compound to humans and identified as a carcinogenic substance. In this study, Hantzsch reaction was utilized for the derivatization of trace amounts of formaldehyde in aqueous samples with acetylacetone in the presence of ammonia to form an extractable colored product named 3,5-diacetyl 1,4-dihydrolutidine (DDL) and its further extraction using two-phase hollow fiber liquid-phase microextraction. The main experimental variables affecting the extraction performance were investigated and optimized. Under the optimum conditions (sample volume 12 mL; reaction temperature 70 °C; ammonium acetate buffer solution 4 mL 0.1 mol L?1; acetylacetone 5 mL 0.15 mol L?1; solvent octanol, salt concentration 20% (w/v) NaCl; pH of donor phase 7.0; stirring speed 400 rpm and extraction time 30 min), the linear dynamic range, limit of detection (LOD as 3S b/m) and relative standard deviation (RSD %) of the proposed method were obtained as 5–250 μg L?1 (r 2 = 0.9979), 3.6 μg L?1 and 2.5%, respectively. Finally, the applicability of the proposed method was examined, and very good results were obtained. The results confirmed the applicability of the proposed method as a versatile, low-cost and sensitive preconcentration method for determination of low concentrations of formaldehyde in aqueous solutions. 相似文献
105.
Spectral,morphological, and antibacterial studies of conducting copolymers,Ppy‐MA,and their nanocomposites,Ag@Ppy‐MA 下载免费PDF全文
Shahab A. A. Nami Mohd. Shoeb Khan Mohammad Arshad Mo Aqib Raza Khan Imran Khan 《先进技术聚合物》2017,28(1):10-19
Pyrrole and methyl anthranilate were copolymerized in different molar ratios in the presence of, H2O2, and FeSO4 at ambient temperature and pressure to obtain efficient conducting copolymers, Ppy‐MA. These conducting copolymers, Ppy‐MA, were in situ reacted with silver nanoparticles to generate nanocomposites, Ag@Ppy‐MA, which exhibit enhanced electrical conductivity. The spectra and morphology of different copolymers, Ppy‐MA, and their nanocomposites, Ag@Ppy‐MA, were analyzed using Fourier transform infrared, SEM, tunneling electron microscopy, X‐ray diffraction, thermogravimetric analysis, and differential thermal analysis. These studies have shown that the nanocomposites, Ag@Ppy‐MA, are thermally more stable and good electrical conductors as compared with their copolymers, Ppy‐MA. The antibacterial activity of the copolymers, Ppy‐MA, prepared from different monomer ratios and their nanocomposites, Ag@Ppy‐MA, has been carried out using disk diffusion method. The copolymers, Ppy‐MA, and its nanocomposites, Ag@Ppy‐MA, were screened against the standard drug Ciprofloxacin. The results clearly suggest that the nanocomposites, Ag@Ppy‐MA, are better antibacterial agent as compared with their copolymers, Ppy‐MA. Copyright © 2016 John Wiley & Sons, Ltd. 相似文献
106.
Pourhojat Faegheh Sohrabi Mahmoodreza Shariati Shahab Mahdavi Hamid Asadpour Leila 《Research on Chemical Intermediates》2017,43(1):297-320
Research on Chemical Intermediates - In this study, for the first time, a biocompatible and non-toxic herbal wound dressing was made by encapsulation of Hypericum perforatum alcoholic extract at... 相似文献
107.
Krishnamurty S Joshi K Zorriasatein S Kanhere DG 《The Journal of chemical physics》2007,127(5):054308
Recent experimental results have reported surprising variations in the shapes of the heat capacity curves and melting temperatures of gallium clusters in the size range of 30-55 atoms [G. A. Breaux et al., J. Am. Chem. Soc. 126, 8628 (2004)]. In the present work, we have carried out an extensive density functional investigation on ten selected clusters in the above mentioned size range. In particular, we have analyzed the ground state geometry and the nature of bonding in these clusters using electron localization function. We demonstrate that the existence or otherwise of a large island of atoms bonded with similar strength (i.e., the local order) in the ground state geometry is responsible for the variation in the shape of the heat capacity curve. We attribute the observed higher melting temperatures of some of the clusters (viz., Ga45-Ga48) to the presence of a distinct core and strong covalent bonds between the core and surface atoms. The present work clearly demonstrates that it is possible to understand the general trends observed in the heat capacity curves across the entire series on the basis of the analysis of their ground state. 相似文献
108.
Warfarin is a widely used oral anticoagulant which is mostly administrated as a racemic mixture containing equal amount of R- and S-enantiomers. The two enantiomers are shown to exhibit significant differences in pharmacokinetics and pharmacodynamics. In this study, a new chiral micellar electrokinetic chromatography-mass spectrometry (MEKC-MS) method has been developed using a polymeric chiral surfactant, polysodium N-undecenoyl-L,L-leucyl-valinate (poly-L,L-SULV), as a pseudostationary phase for the chiral separation of (+/-)-warfarin (WAR) and (+/-)-coumachlor (COU, internal standard). Under optimum MEKC-MS conditions, the enantio-separation of both (+/-)-WAR and (+/-)-COU was achieved within 23 min. Calibration curves were linear (R=0.995 for (R)-WAR and R=0.989 for (S)-WAR) over the concentration range 0.25-5.0 microg/mL. The MS detection was found to be superior over the commonly used UV detection in terms of selectivity and sensitivity with LOD as low as 0.1 microg/mL in human plasma. The method was successfully applied to determine WAR enantiomeric ratio in patients' plasma undergoing warfarin therapy. 相似文献
109.
In this work, simultaneous separation of eight stereoisomers of ephedrine and related compounds ((+/-)-ephedrine, (+/-)-pseudoephedrine, (+/-)-norephedrine and (+/-)-N-methylephedrine) was accomplished using a polymeric chiral surfactant, i.e. polysodium N-undecenoxycarbonyl-L-leucinate (poly-L-SUCL) by chiral (C)MEKC-ESI-MS. The conditions of CMEKC were first investigated. The baseline separation of all eight stereoisomers of ephedrine and related compounds was achieved under optimum CMEKC conditions (35 mM poly-L-SUCL, 15 mM NH(4)OAc, pH 6.0, 30% v/v ACN, 30 kV and 20 degrees C) in less than 30 min. Next, a central composite design for response surface modeling has been described to evaluate the electrospray chamber parameters and the sheath liquid conditions. Optimum mass abundance of stereoisomers of ephedrine and related compounds was observed using the spray chamber parameters, namely 250 degrees C drying gas temperature and 8 L/min drying gas flow rate at a nebulizer pressure of 4 psi. Furthermore, the experimental design indicates that the optimum mass abundance of the stereoisomers of ephedrine and related compounds can be obtained using a sheath liquid containing 80:20 v/v methanol-water, 5 mM NH(4)OAc at pH 8.5 delivered at 5 microL/min. Finally, compared to MEKC-UV, the use of poly-L-SUCL in MEKC-MS provided significantly higher sensitivity for stereoisomers of ephedrine and related compounds. 相似文献
110.
Al-Shawabkeh AF Al-Wahab HA Shahab YA 《Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy》2007,66(3):739-744
Weak molecular homo- and hetero-associations among some ethene derivatives and several common solvents are studied using (1)H NMR spectroscopy. In connection with the aromatic-solvent induced shifts which is a special case of molecular association between aromatic solvents and polar molecules a model for association was suggested that involves the interaction of the positive end of the solute dipole with the aromatic pi-electrons. This model met with certain difficulties. An alternative model for configuration of associated molecules that explains the literature results and the results obtained in this paper is presented. The model is based on interaction of protons of the acceptor molecules with the lone-pair electrons or pi-electrons of the donor molecules. The present model removes the difficulties met with the former model and extends the concept of aromatic-solvent induced shifts to include non-polar molecules besides polar ones. In all cases, the interaction of protons of acceptor molecules with lone-pair electrons of donor molecules gives rise to a deshielding effect, while interaction with aromatic pi-electrons leads to shielding. 相似文献