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151.
S. K. Sharma K. Sudarshan P. Maheshwari D. Dutta P. K. Pujari C. P. Shah M. Kumar P. Bajaj 《The European Physical Journal B - Condensed Matter and Complex Systems》2011,82(3-4):335-340
Poly vinyl alcohol (PVA) capped CdSe nanoparticles having size in the range of 7–17 nm have been synthesized through chemical route and characterized using X-ray diffraction (XRD) and transmission electron microscopy (TEM). Positron coincidence Doppler broadening (CDB) measurements have been carried out in these nanoparticles. It is observed that the electron momentum distributions show a variation in the core electron momentum region with the particle size. In order to examine the influence of defects, first principle calculations of electron momentum distributions in bulk CdSe and in the presence of Cd as well as Se vacancy defects have been performed. Comparison of experimental data with the calculated momentum distribution reveals the presence of Cd vacancy defects, the concentration of which decreases with the increase in the particle size. The present study also indicates possible Se enrichment on the surface of the nanoparticles with the decrease in the particle size. 相似文献
152.
The resolution of electron energy loss spectroscopy (EELS) is limited by delocalization of inelastic electron scattering rather than probe size in an aberration corrected scanning transmission electron microscope (STEM). In this study, we present an experimental quantification of EELS spatial resolution using chemically modulated 2×(LaMnO(3))/2×(SrTiO(3)) and 2×(SrVO(3))/2×(SrTiO(3)) superlattices by measuring the full width at half maxima (FWHM) of integrated Ti M(2,3), Ti L(2,3), V L(2,3), Mn L(2,3), La N(4,5), La N(2,3) La M(4,5) and Sr L(3) edges over the superlattices. The EELS signals recorded using large collection angles are peaked at atomic columns. The FWHM of the EELS profile, obtained by curve-fitting, reveals a systematic trend with the energy loss for the Ti, V, and Mn edges. However, the experimental FWHM of the Sr and La edges deviates significantly from the observed experimental tendency. 相似文献
153.
Waheed S. KhanChuanbao Cao Faheem K. ButtZulfiqar Ali M. SafdarLiqing Pan M. Yasir RafiqueQurrat ul Ain Zahid UsmanGhulam Nabi 《Applied Surface Science》2011,257(16):7314-7319
We report here the evolution of zinc based high purity phases with novel morphologies such as Zn3N2 hollow structures, ZnO nanowires and nanopowders, as well as metallic Zn layered hexagonal microparticles at progressively increased reaction temperature of 600 °C, 700 °C, 800 °C under NH3 gas atmosphere using Zn powder precursor and keeping all other experimental parameters unchanged. Growth mechanism for Zn3N2 obtained by nitridation, ZnO by oxidation and Zn microparticles via thermal evaporation & condensation process are discussed briefly. The as-synthesized products were characterized by X-ray diffraction (XRD), energy dispersive X-ray spectroscopy (EDS) and scanning electron microscopy (SEM). Photoluminescence (PL) studies have revealed very interesting and infrequently observed emission bands at 378 and 661 nm for Zn3N2, 359 and 396 nm for ZnO as well as 389 nm for Zn polyhedral microparticles. 相似文献
154.
CrSiN coatings were deposited on stainless steel (Grade: SA304) and silicon Si(1 0 0) substrates, with varying argon-nitrogen gas proportions and deposition temperature, using reactive magnetron sputtering technique in the present work. The influence of sputtering (Ar) and reactive gas proportions (N2) and temperature on the structural properties of the CrSiN coating was investigated. A small amount of silicon content (3.67 at.% Si) plays a crucial role in addition to the nitrogen content for the formation of different phases in the CrSiN coatings as observed in the present work. For example, the coating with comparatively low nitrogen content, 40% N2, during deposition, formed a crystalline structure consisting of nano-crystalline CrN which is separated by an amorphous SiN phase, as evident from X-ray diffraction (XRD) and transmission electron microscopy (TEM), respectively. The formation of CrN(1 1 1) and Cr2N(1 1 1) phases has occurred at 30% N2 with 3.67% Si content, which transformed in to CrN(1 1 1) and CrN(2 0 0) with increase in N2 content but with same Si content. The surface topography and morphology of the coatings were analyzed by atomic force microscopy (AFM) and field emission scanning electron microscopy (FESEM), respectively. A less columnar growth is observed in CrSiN coatings deposited at low argon content, Ar:N2 (20:80), and with 3.67 at.% Si in the coatings. However, it becomes dense with increase in nitrogen content and temperature. The XRD analysis showed that the intensity of a dominating peak (1 1 1) is decreasing from (80:20) to (60:40) argon:nitrogen environment. With a further increase of nitrogen content, from (60:40), in the sputtering gas mixture, to (40:60) argon-nitrogen, there is a sudden increase in (1 1 1) peak and above (40:60), the peak reduction rate is very slow than the previous one. The (1 1 1) and (2 0 0) peak intensity variations are very limited due to high nitrogen content, above 50%, and considerable amount of Si atoms, 3.67 at.%, present in the CrN coatings. 相似文献
155.
156.
We consider a switched network (i.e. a queueing network in which there are constraints on which queues may be served simultaneously),
in a state of overload. We analyse the behaviour of two scheduling algorithms for multihop switched networks: a generalized
version of max-weight, and the α-fair policy. We show that queue sizes grow linearly with time, under either algorithm, and we characterize the growth rates.
We use this characterization to demonstrate examples of congestion collapse, i.e. cases in which throughput drops as the switched
network becomes more overloaded. We further show that the loss of throughput can be made arbitrarily small by the max-weight
algorithm with weight function f(q)=q
α
as α→0. 相似文献
157.
158.
Muhammad Zaheer Afzal Shah Zareen Akhter Rumana Qureshi Bushra Mirza Misbah Tauseef Michael Bolte 《应用有机金属化学》2011,25(1):61-69
Synthesis of ferrocenyl Schiff bases ( 1–6 ) was carried out by the condensation reaction of 4‐ferrocenyl aniline with different substituted aromatic aldehydes and acetyl acetone. Compounds were characterized by physical measurements, elemental analysis, FT‐IR, 1H‐NMR and 13C‐NMR spectroscopy. Single crystal X‐ray analysis of compound 2 showed the co‐planarity of both aromatic rings connected by a C–N double bond. Compounds demonstrated reversible one‐electron redox behavior and their peak currents were found to increase linearly with the square root of the sweep rate ν1/2. The overall electrode processes were found to be diffusion controlled. Compounds 1 and 4 showed low cytotoxicity and appreciable antifungal, antioxidant and DNA protection activities. Copyright © 2010 John Wiley & Sons, Ltd. 相似文献
159.
160.
Ruchit Shah 《European Journal of Operational Research》2011,211(3):466-479
This study analyzes multiobjective d-dimensional knapsack problems (MOd-KP) within a comparative analysis of three multiobjective evolutionary algorithms (MOEAs): the ε-nondominated sorted genetic algorithm II (ε-NSGAII), the strength Pareto evolutionary algorithm 2 (SPEA2) and the ε-nondominated hierarchical Bayesian optimization algorithm (ε-hBOA). This study contributes new insights into the challenges posed by correlated instances of the MOd-KP that better capture the decision interdependencies often present in real world applications. A statistical performance analysis of the algorithms uses the unary ε-indicator, the hypervolume indicator and success rate plots to demonstrate their relative effectiveness, efficiency, and reliability for the MOd-KP instances analyzed. Our results indicate that the ε-hBOA achieves superior performance relative to ε-NSGAII and SPEA2 with increasing number of objectives, number of decisions, and correlative linkages between the two. Performance of the ε-hBOA suggests that probabilistic model building evolutionary algorithms have significant promise for expanding the size and scope of challenging multiobjective problems that can be explored. 相似文献