EHD kelvin-helmholtz instability in viscous porous medium permeated with suspended particles

The electrohydrodynamic Kelvin-Helmholtz instability of the plane interface between two uniform, superposed viscous and streaming dielectric fluids permeated with suspended particles through porous medium is considered under the influence of a tangential electric field. In the absence of surface tension, it is found that perturbations transverse to the direction of streaming are unaffected by the presence of both streaming and the tangential electric field, if perturbations in the direction of streaming are ignored. For perturbations in all other directions there exists instability for a certain wavenumber range. In the presence of surface tension, it is found that the instability of this system is suppressed by the presence of the tangential electric field. Both the tangential electric field and the surface tension have stabilizing effects and they are able to suppress Kelvin-Helmholtz instability for small wavelength perturbations. The medium porosity reduces the stability range given in terms of a difference in streaming velocities and the electric field effect, while the suspended particles do not affect the above results.     

Water-stable hydrazone-linked porous organic cages

Although porous organic cages (POCs), particularly imine-linked (C N) ones, have advanced significantly over the last few decades, the reversible nature of imine linkages makes them prone to hydrolysis and structural collapse, severely limiting their applications under moist or water conditions. Herein, seven water-stable hydrazone-linked (C N–N) POCs are prepared through a simple coupling of the same supramolecular tetraformylresorcin[4]arene cavitand with different dihydrazide linkers. Their structures are all determined by single-crystal X-ray crystallography, demonstrating rich structural diversity from the [2 + 4] lantern, [3 + 6] triangular prism, and unprecedented [4 + 8] square prism to the extra-large [6 + 12] octahedron. In addition, they respectively exhibit tunable window diameters and cavity volumes ranging from about 5.4 to 11.1 nm and 580 to 6800 ų. Moreover, their application in the water environment for pollutant removal was explored, indicating that they can effectively eliminate various types of contaminants from water, including radionuclide waste, toxic heavy metal ions, and organic micropollutants. This work demonstrates a convenient method for rationally constructing versatile robust POCs and presents their great application potentialities in water medium.

A convenient method for constructing water-stable hydrazone-linked porous organic cages (POCs) with tunable structures has been reported, and such POCs can be used as robust adsorbents for effective removal of various pollutants from water.     

Energy Levels and Transition Rates for Ti XIV

Physics of Particles and Nuclei Letters - Energy levels, wavelengths, oscillator strengths, transition probabilities, line strengths, and lifetimes are calculated for transitions in Ti XIV. The...     

Gold nanoparticles propulsion from surface fueled by absorption of femtosecond laser pulse at their surface plasmon resonance

Femtosecond laser irradiation of assembled nanoprisms on a quartz substrate at their strong absorbing surface plasmon resonance frequency causes their propulsion from the substrate. SEM and AFM show that the particles fly while keeping their prismatic shape, but they decrease in size by an amount that can be calculated assuming atomic sublimation. Several mechanisms are mentioned, but the sublimation mechanism, which rapidly builds up pressure under the particle and propels it away from substrate, is discussed in detail. From the kinetic energy given to the flying nanoparticle, an initial velocity of approximately 160 m/s ( approximately 360 miles/h) is calculated. The dependence of the observed flying mechanism on the rate of energy deposition (i.e., with nanosecond vs femtosecond laser pulses) is discussed.     

Vibration control of helicopter blade flapping via time-delay absorber

In this study, the controller is used to suppress the vibration due to rotor the helicopter blade flapping motion. The objective of this paper is to investigate the effect of time-delay absorber on the vibrating system when subjected to multi-parametric excitation forces. The equations of motion are described by coupled nonlinear differential equations. The averaging method is applied to obtain the frequency response equations near simultaneous sub-harmonic and internal resonance. The stability of the obtained nonlinear solution is studied and solved numerically. Numerical simulations show the steady state response amplitude versus the detuning parameter and the effects of the parameters system and controller. Effectiveness of the absorber E _a is about 2.7×10⁵ of the main system (X).     

Characterization of the mupirocin biosynthesis gene cluster from Pseudomonas fluorescens NCIMB 10586

The polyketide antibiotic mupirocin (pseudomonic acid) produced by Pseudomonas fluorescens NCIMB 10586 competitively inhibits bacterial isoleucyl-tRNA synthase and is useful in controlling Staphylococcus aureus, particularly methicillin-resistant Staphylococcus aureus. The 74 kb mupirocin biosynthesis cluster has been sequenced, and putative enzymatic functions of many of the open reading frames (ORFs) have been identified. The mupirocin cluster is a combination of six larger ORFs (mmpA-F), containing several domains resembling the multifunctional proteins of polyketide synthase and fatty acid synthase type I systems, and individual genes (mupA-X and macpA-E), some of which show similarity to type II systems (mupB, mupD, mupG, and mupS). Gene knockout experiments demonstrated the importance of regions in mupirocin production, and complementation of the disrupted gene confirmed that the phenotypes were not due to polar effects. A model for mupirocin biosynthesis is presented based on the sequence and biochemical evidence.     

Application of surface enhanced Raman spectroscopy to the study of SOFC electrode surfaces

SERS provided by sputtered silver was employed to detect trace amounts of chemical species on SOFC electrodes. Considerable enhancement of Raman signal and lowered detection threshold were shown for coked nickel surfaces, CeO(2) coatings, and cathode materials (LSM and LSCF), suggesting a viable approach to probing electrode degradation and surface catalytic mechanism.     

Cardiovascular magnetic resonance for the assessment of pulmonary arterial hypertension: toward a comprehensive CMR exam

Pulmonary arterial hypertension (PAH) is a progressive disorder characterized by abnormally increased blood pressure of the pulmonary circulation. The clinical course of the untreated PAH involves rapid progression to right ventricular (RV) failure and death. Right heart catheterization is the gold-standard method for confirming PAH. However, the technique's invasiveness and associated risks preclude its use on a regular basis. Different imaging techniques have been implemented for evaluating PAH, including echocardiography, computed tomography and nuclear medicine. However, these techniques have their own limitations. During the past decade, cardiovascular magnetic resonance (CMR) has been increasingly used for the evaluation of different cardiovascular diseases, including PAH, due to its high resolution, high tissue contrast, and the plethora of anatomical and physiological parameters that can be measured with this modality. This article presents an up-to-date review of the implementation of CMR for evaluating PAH. This is achieved by describing a comprehensive CMR protocol that includes several imaging sequences for assessing different cardiovascular parameters pertaining to PAH. In contrast to the previously published articles, the presented CMR protocol evaluates both RV function and pulmonary artery hemodynamics, which are both affected in PAH. Each imaging sequence is explained along with the image analysis steps required for deriving the cardiovascular parameters of interest. Then, based on an extensive literature review, the article illustrates the significance of the derived cardiovascular parameters and their association with PAH. The article concludes with a discussion of the advantages of the proposed CMR exam for better understanding of the disease pathophysiology and treatment planning.     

Onset of electroconvective instability of Oldroydian viscoelastic liquid layer in Brinkman porous medium

The problem of the onset of electrohydrodynamic instability in a horizontal layer of Oldroydian viscoelastic dielectric liquid through Brinkman porous medium under the simultaneous action of a certical ac electric field and a vertical temperature gradient is analyzed. Applying linear stability theory, we derive an equation of eight order. Under somewhat suitable boundary conditions, this equation can be solved exactly to yield the required eigenvalue relationship from which various critical values are determined in detail. Both the cases of stationary and oscillatory instabilities are discussed if the liquid layer is heated from below or above. The effects of the porosity of porous medium, the medium permeability, the Prandtl number, the ratio of retardation time to relaxation time, the elastic number, in the presence or absence of Rayleigh number are shown graphically for both cases. Some of the known results are derived as special cases. The electrical force has been shown to be the sole agency causing instability of the considered system since it is much more important than the buoyancy force even if the medium is porous.     

The Solvent-Like Nature of Silica Particles in Organic Solvents

 Kamlet-Taft’s α (hydrogen bond donor acidity) and π^* (dipolarity/polarizability) values of various silica batches measured in various solvents are presented. The α and π^* parameters for the various solid acids are analyzed by means of Fe(phen)₂(CN)₂ (cis-dicyano-bis-(1,10)-phenanthroline-iron(II), 1), Michler’s ketone (4,4′-bis-(dimethylamino)-benzophenone, 2), and two hydrophilic derivatives of 2, (4-(dimethylamino)-4′-(di-2-hydroxyethyl)-amino-benzophenone (3a) and 4,4′-bis-(di-(2-hydroxyethyl)-amino)-benzophenone (3b) as well as coumarin 153 (4) as solvatochromic surface polarity indicators. Apparent β (hydrogen bond acceptor basicity) parameters for bare silica have been evaluated by means of an aminobenzodifuranone dye (5) as solvatochromic probe. The chemical interpretation of the α and π^* parameters and the nature of the solvent/surface interaction which they reflect are discussed. It can be shown that an increase of the HBA (hydrogen bond accepting) capacity of the solvent significantly decreases the HBD (hydrogen bond donating) capacity of the surface environment, whereas the dipolarity/polarizability value of the silica/solvent interface is a composite of many effects. The classification of the polarity of silica particles in organic solvents compared to pure liquids is outlined.