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51.
Yu. M. Kargin E. I. Gritsenko V. V. Yanilkin V. V. Plemenkov L. K. Dubovik N. I. Maksimyuk B. M. Garifullin Sh. K. Letypov A. V. Il'yasov 《Russian Chemical Bulletin》1992,41(9):1572-1579
The electrochemical reduction of 1,1-dihalo-2-R-2-methylcyclopropanes was studied by polarography and preparative electrolysis. A mixture of stereoisomeric monoboro- and monochlorocyclopropanes was obtained with preparative yield of 60–70% in preparative electroreduction in methanol against a background of 0.1 M LiClO4. In the case of bromine derivatives of cyclopropanes (except when R = CN) an effect was found on the part of the current density on the ratio of cis and trans isomers, which was interpreted as a change, in dependence on current density, of the contributions of the reactions of reduction of the starting compounds (SN2 mechanism) and ionic pairs (SN1 mechanism). The effect of the solvent (CHCl3, DMF, DMSO, MeOH) and background salt (LiClO4, Et4NBr) on the ratio of stereoisomers is in agreement with this interpretation.A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Science Center, Russian Academy of Sciences, Kazan. Translated from Izvestiya Akademii Nauk, Seriya Khimicheskaya, No. 9, pp. 2023–2032, September, 1992. 相似文献
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Ya. Sh. Il'yasov 《Theoretical and Mathematical Physics》1995,105(3):1546-1555
The functions of action and energy are introduced on a manifold of ground states of the Euclidian scalar field functional of action. The differential identity connecting these two functions is proved.Translated from Teoreticheskaya i Matematicheskaya Fizika, Vol. 105, No. 3, pp. 438–449, December, 1995. 相似文献
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Sh.Rezapour 《分析论及其应用》2003,19(2):130-135
We will define and characterize c-weakly Chebyshev subspaces of Banach spaces. We will prove that all closed subspaces of a Banach space X are ε-weakly Chebyshev if and only if X is reflexive. 相似文献
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N.N. Smirnov V.F. Nikitin J. Khadem Sh. Alyari-Shourekhdeli 《Proceedings of the Combustion Institute》2007,31(2):2195-2204
Investigations of detonation onset in pulverized fuel–air mixtures were carried out. Combustion and detonation processes in sprays differ greatly from that in homogeneous mixtures, because not only chemical reactions, but physical processes of combustible mixture formation take place within the combustion zone (droplets atomization and evaporation). The polydispersed character of mixture and non-uniformity of droplet spatial distribution strongly affects spray combustion and detonation onset. The present paper contains the results of theoretical and experimental investigations of detonation onset peculiarities in polydispersed non-uniform hydrocarbon–air mixtures. 相似文献