Negligible absorption of radiofrequency radiation by colloidal gold nanoparticles

We report quantitative measurement of heat generation in Au-nanoparticle colloidal solutions induced by radiofrequency (RF) electromagnetic waves (13.56 MHz; 25 W). The possible role of Au nanoparticles in RF heating was systematically investigated by separating the metal nanoparticles away from the colloidal solutions by centrifugation. Contrary to the previously made assumption in this field, it is found that Au nanoparticles do not contribute to RF energy absorption. The electrical conductivity measurement of the solutions with and without Au nanoparticles reveals that the Joule heating via ionic conduction in the electrolyte solutions is the dominant mechanism of RF-radiation-to-thermal conversion.     

A novel structural form of MIL-53 observed for the scandium analogue and its response to temperature variation and CO2 adsorption

The scandium analogue of the flexible terephthalate MIL-53 yields a novel closed pore structure upon removal of guest molecules which has unusual thermal behaviour and stepwise opening during CO(2) adsorption. By contrast, the nitro-functionalised MIL-53(Sc) cannot fully close and the structure possesses permanent porosity for CO(2).     

Tournament immersion and cutwidth

A (loopless) digraph H is strongly immersed in a digraph G if the vertices of H are mapped to distinct vertices of G, and the edges of H are mapped to directed paths joining the corresponding pairs of vertices of G, in such a way that the paths used are pairwise edge-disjoint, and do not pass through vertices of G that are images of vertices of H. A digraph has cutwidth at most k if its vertices can be ordered {v₁,…,vn} in such a way that for each j, there are at most k edges uv such that u∈{v₁,…,vj−1} and v∈{vj,…,vn}.We prove that for every set S of tournaments, the following are equivalent:

•

there is a digraph H such that H cannot be strongly immersed in any member of S,

•

there exists k such that every member of S has cutwidth at most k,

•

there exists k such that every vertex of every member of S belongs to at most k edge-disjoint directed cycles.

This is a key lemma towards two results that will be presented in later papers: first, that strong immersion is a well-quasi-order for tournaments, and second, that there is a polynomial time algorithm for the k edge-disjoint directed paths problem (for fixed k) in a tournament.     

Heavy quark production in jets

Zeitschrift für Physik C Particles and Fields - We study possible deviations from the Standard Model in the reactione + e ?→Z?, where ? denotes a spinless neutral boson....     

Chiral recognition in solution and the gas phase. Experimental and theoretical studies of aromatic D- and L-amino acid–Cu(II)–chiragen complexes Jennifer L. Seymour František Tureček Andrei V. Malkov Pavel Kočovský Journal of Mass Spectrometry 2004; 39: 1044–1052

The original article to which this Erratum refers was published in Journal of Mass Spectrometry 2004; 39: 1044–1052.     

Site occupancy of ferrous ions in iron garnets

Fe²⁺ site occupancy in iron garnets is investigated by means of optical absorption and magnetic circular dichroism. In particular measurements are carried out on bulk single crystals of yttrium iron garnet (YIG) doped with Si⁴⁺, Nb⁵⁺, Sn⁴⁺, Zr⁴⁺, Ti⁴⁺ and Th⁴⁺. The results are discussed in the light of the recent discovery of tetrahedral Fe²⁺ in Nb-doped YIG. We find that, in general, Fe²⁺ occupies both octahedral and tetrahedral sites, the actual distribution being related to site occupancy of the donor centers. This correlation may be relaxed by photoinduced charge transfer between iron sites, at low temperatures. Contrary to recent attributions, no dodecahedral component is found in the infrared spectra above 1 μm wavelength.     

Effect of hot-drawing conditions on the orientation characteristics of carbon-chain fibers determined by the acoustic method

The orientation characteristics of polypropylene, polyacrylonitrile, and chlorinated PVC fibers, determined by the acoustic method, have been investigated in relation to the fiber drawing conditions (draw ratio, speed, and temperature). It is shown that there is a correlation between the mechanical characteristics and the degree of acoustic anisotropy.Tashkent Institute of the Textile and Light Industries. Translated from Mekhanika Polimerov, No. 3, pp. 552–554, May–June, 1971.     

Calorimetric investigations on mound-building birds

Megapodes, and mound-building birds of the Pacific, incubate their eggs underground where the heat is supplied by organic decomposition, solar radiation, or geothermal sources. The incubation biology of the Australian mound builders has been examined from the standpoints of (1) the energetic requirements of malleefowl (Leipoa ocellata) to construct and maintain incubation mounds and (2) the physics, physiology, and behavior concerning mound thermoregulation of the brush turkey (Alectura lathami).

The energetic cost of mound tending in malleefowl is estimated by indirect calorimetry. The power required for digging into the mound to reach the eggs is approximately 20 W, or 3.8 times the basal metabolic rate of the bird. About 850 kg of sand has to be removed and replaced on the mound every time it is opened, a task requiring about 5 h. The overall energy investment for incubation for the entire 9 month season is 2.5 times that expected in similarly sized birds.

Brush turkey mounds become homeothermic because of (1) the high thermal inertia of their 3–11 t mass and (2) a stable equilibrium that is reached between heat production and heat loss. The mound tends to seek the equilibrium, but the bird adjusts the temperature by subtle manipulation of the mound. At an equilibrium temperature of 33°C, the mound produces about 110 W. Empirical data from natural mounds, set in the context of a numerical model of heat production and heat flux in the mound, indicate that equilibrium temperature is extremely sensitive to ambient temperature and mound size, but not water content. Wet or dry mounds can maintain appropriate incubation temperature, but the dry ones have low thermal conductivity, retain the heat well, and minimize the amount of forest litter collected during the incubation season.     

Solutions to the Navier-Stokes Equations Describing Local Flows of Stratified and Compressible Fluids

A family of exact solutions of the Navier-Stokes equations is used to describe local flows of incompressible stratified and compressible fluids. For some of the flows, the coefficient of viscosity can depend on the temperature. An example of an incompressible stratified flow for which the analysis is applicable is the sheared swirling flow that is produced between two parallel plates that translate with different velocities and rotate with different angular velocities about different, but parallel, axes. The fluid may be stratified in the direction normal to the plates. These generalized von Karman flows are relevant to the study of strong local atmospheric disturbances, such as might be produced by the passage of a tornado. Also, when the coefficient of viscosity depends on the temperature, they can be used to analyze the flow of molten metals between surfaces that are in relative motion. An example of a compressible flow for which the analysis is applicable is that produced by a plane shock wave as it traverses a layer where the fluid is sheared in a direction normal to the shock.