排序方式: 共有102条查询结果,搜索用时 15 毫秒
81.
Sadjadi Samahe Heravi Majid M. Malmir Masoumeh 《Research on Chemical Intermediates》2017,43(11):6701-6717
Research on Chemical Intermediates - A novel hybrid catalyst has been designed and synthesized based on the incorporation of heteropolyacid into creatin-functionalized halloysite clay. The catalyst... 相似文献
82.
Samahe Sadjadi Majid M. Heravi Mansoureh Daraie 《Research on Chemical Intermediates》2017,43(2):843-857
The nanoporous framework of a cyclodextrin nanosponge was used as catalyst for accelerating the one-pot, three-component reaction of dimedone, aldehyde, and phenols for synthesis of xanthene derivatives. Moreover, the nanocavities of cyclodextrin nanosponges were exploited for immobilization of heteropolyacids through the wet impregnation method. This catalyst exhibited superior catalytic performance compared to the bare cyclodextrin nanosponge. Despite the good catalytic activity, the leaching of the catalytic species did not allow efficient recovery and reusability. To circumvent this problem, the cyclodextrin nanosponge was amine-functionalized prior to heteropolyacid immobilization. The results proved that the amine functionalities had an effective role in preserving the catalytic species and improving the reusability through decreasing the leaching time. This catalyst was used for synthesis of a variety of xanthenes in aqueous media. The catalytic amount of catalyst afforded the desired product in excellent yields and with a relatively short reaction time. The results suggested cyclodextrin nanosponge-based catalysts as potential candidates for promoting chemical reactions. 相似文献
83.
Majid M. Heravi Samaheh Sadjadi Sodeh Sadjadi Hossein A. Oskooie Fatemeh F. Bamoharram 《Ultrasonics sonochemistry》2009,16(6):708-710
A new synthesis of 4(3H)-quinazolinone from the reaction of 2-amino-benzamide, and acylchlorides in the presence of catalytic amounts of silica-supported Preyssler nano particles as green, reusable and efficient catalyst under ultra sonic irradiation is reported. 相似文献
84.
We study the parameterized post-Newtonian approximation in teleparallel model of gravity with a scalar field. The scalar field is non-minimally coupled to the scalar torsion as well as to the boundary term introduced in Bahamonde and Wright (Phys Rev D 92:084034 arXiv:1508.06580v4 [gr-qc], 2015). We show that, in contrast to the case where the scalar field is only coupled to the scalar torsion, the presence of the new coupling affects the parameterized post-Newtonian parameters. These parameters for different situations are obtained and discussed. 相似文献
85.
Rahim Hekmatshoar Sodeh Sadjadi Samaheh Sadjadi Majid M. Heravi Yahya S. Beheshtiha Fatemeh F. Bamoharram 《合成通讯》2013,43(11):1708-1716
An efficient synthetic method of six- and five-member nitrogen heterocyclic compounds was developed. Nitrogen heterocyclic compounds were prepared by condensation of the β-dicarbonyl compounds with the corresponding β- or γ-amino alcohols, subsequent cyclization, and spontaneous aromatization in the presence of a catalytic amount of Keggin-type heteropoly acids under very mild conditions. 相似文献
86.
Majid M. Heravi Yahya S. Beheshtiha Zahra Pirnia Samaheh Sadjadi Mina Adibi 《合成通讯》2013,43(20):3663-3667
4H-Pyrans are synthesized through one-pot, three-component reaction of benzaldehyde, malononitrile, and ethyl acetoacetate using Cu(II) oxymetasilicate as an efficient, reusable catalyst. The procedure offers advantages in terms of better yields, short reaction times, mild reaction conditions, and reusability of the catalyst. 相似文献
87.
Rahim Hekmatshoar Ghodsieh Nanva Kenary Sodeh Sadjadi Yahya S. Beheshtiha 《合成通讯》2013,43(13):2007-2013
An efficient method for the synthesis of 4-amino-5-pyrimidinecarbonitriles by three-component reaction of malononitrile, aldehydes, and N-unsubstituted amidines, under aqueous conditions, using ZnO nanoparticles as catalyst is reported. The catalyst exhibited remarkable activity and is recyclable. 相似文献
88.
Mina Iranpour Reza Fazaeli Mirabdullah Seyed Sadjadi Mohammad Yousefi 《Russian Journal of Inorganic Chemistry》2018,63(8):1079-1083
This study investigates solvent effect on several electronic structure features, i.e. structural stability, orbital energies, HOMO-LUMO gaps and hardness of an iron aminoborirene complex [(η5-C5H5)(OC)2Fe{μ- BN(SiH3)2C=C}Ph] (closed-isomer) and its isomer the boryl complex [(η5-C5H5)(OC)2FeBN(SiH3)2C≡CPh] (open-isomer) through polarizable continuum model. Results revealed that the closed isomer is less stable than the open isomer, in solvent. Further, influence of the solvent on the frontier orbitals energies, HOMOLUMO gap, electrophilicity and chemical potential energies of the isomers was studied. Thermochemical analysis was conducted to study closed-open equilibrium and thermochemical parameters (ΔG and ΔH) were computed. 相似文献
89.
Sadjadi FA 《Optics letters》2007,32(3):229-231
The results of experiments in developing a method for extracting three-dimensional information from a scene by means of a polarimetric passive imaging sensor are summarized. This sensor provides a full Stokes vector at each sensor pixel location from which degree and angle of linear polarization are computed. The angle of linear polarization provides the azimuth angle of the surface normal vector. The depression angle of this surface normal vector is obtained in terms of the emitting object's index of refraction from the solution of an equation derived from Fresnel equations, Snell's law, and percent of linear polarization. Results of the application of this approach to simulated infrared polarimetric data are provided. 相似文献
90.
Ab initio calculations indicate that metalation of the exocyclic amino group of cytosine by the elements of Group IA (Li, Na, K, Rb and Cs) induces protonation of a nucleobase ring nitrogen atom, and hence causes a proton shift from an exocyclic to an endocyclic nitrogen atom. Thus, this metal‐assisted process leads to the generation of rare nucleobase tautomers. The calculations suggest that this kind of metalation increases the protonation energies of the aromatic ring of the nucleobase. The present study reports the quantum chemistry analysis of the metal‐assisted tautomerization. The calculations clearly demonstrate that metalation of the exocyclic amino group of the nucleobase significantly increases the protonation energy of the aromatic rings of the nucleobase. Also, absolute anisotropy shift, molecular orbital and natural bond orbital calculations are compatible with these results. Copyright © 2003 John Wiley & Sons, Ltd. 相似文献