Kinetic study of electrochemically induced Michael reactions of o‐benzoquinones with 2‐acetylcyclohexanone and 2‐acetylcyclopentanone

The reaction of electrochemically generated o‐benzoquinones ( 2a‐f ) as Michael acceptors with 2‐acetylcyclohexanone (ACH) and 2‐acetylcyclopentanone (ACP), as nucleophiles has been studied in various pHs using cyclic voltammetry. The results indicate that the participation of o‐benzoquinones ( 2a‐f ) in the Michael reaction with acetylcyclohexanone (ACH) to form the corresponding catechol derivatives ( 4a‐f ). Based on an EC mechanism, the homogeneous rate constants were estimated by comparing the experimental cyclic voltammetric responses with the digital simulated results. Copyright © 2007 John Wiley & Sons, Ltd.     

A Class of Super Dense Stars Models Using Charged Analogues of Hajj-Boutros Type Relativistic Fluid Solutions

We present a spherically symmetric solution of the general relativistic field equations in isotropic coordinates for perfect charged fluid, compatible with a super dense star modeling. The solution is well behaved for all the values of Schwarzschild parameter u lying in the range 0 < u < 0.1727 for the maximum value of charge parameter K = 0.08163. The maximum mass of the fluid distribution is calculated by using stellar surface density as ρ _b = 4.6888×10¹⁴g cm^?3. Corresponding to K = 0.08 and u _max = 0.1732, the resulting well behaved solution has a maximum mass M = 0.9324M _⊙ and radius R = 8.00 and by assuming ρ _b = 2×10¹⁴g cm^?3 the solution results a stellar configuration with maximum mass M = 1.43M _⊙ and radius R _b = 12.25 km. The maximum mass is found increasing with increasing K up to 0.08. The well behaved class of relativistic stellar models obtained in this work might has astrophysical significance in the study of internal structure of compact star such as neutron star or self-bound strange quark star like Her X-1.     

Generalized negative flows in hierarchies of integrable evolution equations

A one-parameter generalization of the hierarchy of negative flows is introduced for integrable hierarchies of evolution equations, which yields a wider (new) class of non-evolutionary integrable nonlinear wave equations. As main results, several integrability properties of these generalized negative flow equation are established, including their symmetry structure, conservation laws, and bi-Hamiltonian formulation. (The results also apply to the hierarchy of ordinary negative flows). The first generalized negative flow equation is worked out explicitly for each of the following integrable equations: Burgers, Korteweg-de Vries, modified Korteweg-de Vries, Sawada-Kotera, Kaup-Kupershmidt, Kupershmidt.     

The effect of anodising time on the electrochemical behaviour of the Ti/TiO<Subscript>2</Subscript> NTs/IrO<Subscript>2</Subscript>-RuO<Subscript>2</Subscript>-Ta<Subscript>2</Subscript>O<Subscript>5</Subscript> anode

Nowadays, mixed metal oxide (MMO) anodes are a superior alternative to lead alloys in electrowinning processes. Passivation of titanium substrate is the most common mechanism of deactivation in these anodes. In this research, titanium oxide nanotubes have been utilised as an interlayer between the substrate and a mixed metal oxide coating in order to improve the anode electrochemical behaviour and life via retardation of titanium passivation. Anodising of the substrate was done in 0.5 wt% hydrofluoric acid for 30, 60 and 240 min. The samples were subsequently coated with a coating composed of IrO₂-RuO₂-Ta₂O₅. The microstructure of different samples was observed by scanning with an electron microscope, and the electrochemical behaviour of the samples was studied by accelerated life test, cyclic voltammetry and electrochemical impedance spectroscopy. The studies showed that formation of titanium oxide nanotubes with anodising times of 60 and 240 min increases the life of the anode through the provision of a compact coating. The life of the anode which was anodised for 240 min lasted about 20% longer than the sample which had a substrate without any anodised layer.     

Effect of frequency on sonochemical reactions. I: Oxidation of iodide

The effect of continuous sonication on the kinetics of iodine formation in aqueous iodide solutions was studied in the presence of air and argon at two frequencies, 20 and 900 kHz. Most workers in this area assume that frequency has a negligible effect on sonochemical reactions. The present results indicate, however, that there is a significant effect in the above solutions. The rate of sonochemical oxidation of iodide in aqueous solution is 3.1 times greater in presence of air than argon at 900 kHz, in contrast to the situation at 20 kHz, where the ratio is 0.9 A 900 kHz apparatus was specially designed to make it possible to measure the absolute acoustic power delivered into the solution. The rate of oxidation per unit power in this new 900 kHz apparatus can be more than 30 times greater than that at 20 kHz for the oxidation of iodide in the presence of air.     

Analysis of the AC electrical data in the Davidson-Cole dielectric representation

The representation of the AC electrical data in the complex plane reveal two major classifications of the relaxation processes known as ideal (Debye) and non-ideal (non-Debye) types. The non-Debye relaxation has been empirically observed via Cole-Cole (C-C), Davidson-Cole (D-C), and Havriliak-Negami (H-N) responses. Each of these non-Debye relaxations is visualized with an equivalent circuit similar to the ideal relaxation. Both ideal and C-C relaxations reveal semicircular behavior in the complex plane while D-C and H-N relaxations deviate from the usual semicircular loci known as skewed behavior. The extracted equivalent circuit elements are essentially non-Debye for both D-C and H-N relaxations possessing complexity in the relaxation time. The analytical method of extracting these elements in conjunction with the empirical parameters of the D-C relaxation is described using conventional (real) domain and complex domain. The curve fitting procedure provided extremely small error for the complex domain analysis. The behavior of the D-C relaxation function and the depression parameter β are also discussed using ωτ=1 and ωτ≠1 corresponding to the maximum of the imaginary part of the impedance (Z^*) or permittivity (ε^*).     

Z-scan measurement for the nonlinear absorption and the nonlinear refraction of poly1,4-diazophenylene-bridged-tris(8-hydroxy-quinoline) aluminum (PDPAlq3)

The nonlinear optical properties of the poly1,4-diazophenylene-bridged-tris(8-hydroxy-quinoline) aluminum (PDPAlq₃) solution were studied using single beam Z-scan technique with a continuous-wave Diode laser radiation at 657.2 nm with 10 Hz repetition rate. The results show that the solution of PDPAlq₃ exhibits large nonlinear refractive index (n₂ = −1.7642 × 10⁻¹² m²/W) and nonlinear absorption coefficient (β = 1.12 × 10⁻⁶ m/W). The negative sign of the nonlinear refractive index n₂ indicates that the material exhibits self-defocusing optical nonlinearity. The evaluation of the figure of merit (W = 1.8) shows that the solution of PDPAlq₃ is sufficient for application in all-optical switching technology. These results show that the solution of PDPAlq₃ have potential application in nonlinear optics.     

Estimates of B-decays into K-resonances and dileptons

Short and long distance contributions to the exclusive B-decays into various K-resonances and dileptons, i.e. $B \to K^i \ell \bar \ell (\ell = e,\mu ,\nu )$ , are examined. The heavy quark effective theory has been used to calculate the hadronic matrix elements. Substantial branching fractions are obtained for the dileptonic B-decays into some higher excited states of K-mesons. The long distance (resonance) contributions to these exclusive rare B-decay modes dominate the short distance contributions mostly by two orders of magnitude. It is pointed out that, excluding the resonance contributions, the P-wave channels are dominant, accounting for about 50% of the inclusiveB??X _s ? ⁺ ? ^? branching fraction.