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91.
    
Grape stilbenes are a well-known family of plant polyphenolics that have been confirmed to have many biological activities in relation to health benefits. In the present study, we investigated the effect of methyl jasmonate (MeJA) elicitor at four different concentrations (25, 50, 100 and 200 μM) in combination or not with high-level light irradiation (10,000 LUX) on a cell line obtained from the pulp of Vitis vinifera cv. Shahani. Our results showed that the stilbene synthesis pathway is inhibited by high-light conditions. A concentration of 50 μM MeJA was optimum for efficient production and high accumulation of total phenolics and total flavonoids as well as total stilbenoids. Furthermore, we showed that there is a significant negative correlation between the production of these metabolites and cell growth. These data provide valuable information for the future scale-up of cell cultures for the production of these very high value compounds in bioreactor system.  相似文献   
92.
93.
    
Song and Mason equation of state (EOS) with a simple modification has been extended to modelling PVT properties of ionic liquids (ILs). The considered ILs are [C1mim][MeSO4], [C1mim][CH3OC2H5SO4], [C1mim][(CH3)2PO4], [C2mim][MeSO4], [C2mim][BF4], [C2mim][SCN], [C2eim][NTf2], [C4mim][C(CN)3], [C4mim][CF3SO3], [C4mim][SCN], [C5mim][NTf2], [C8mim][NTf2], [(C6H13)3P(C14H29)][Cl], [(C6H13)3P(C14H29)][NTf2], [(C6H13)3P(C14H29)][Ac], [C3mpyr][NTf2], [C4mpyr][NTf2] and [Py][C2H5OC2H4SO4]. Three temperature-dependent parameters in the proposed EOS have been scaled as functions of reduced temperature with the use of the law of corresponding states. It is shown that the knowledge of just critical temperature and critical density is sufficient to predict the PVT properties of these ILs. The overall average absolute deviation of calculated densities from literature values for 1347 data points of 18 ILs was found to be 0.58%. The predicted density of ILs from proposed EOS has been compared with those obtained by other literature work. Moreover, we indicate that the Zeno line regularity can well be predicted by proposed model for ILs.  相似文献   
94.
    
To understanding the adsorption mechanism and the induced effects of an anticancer drug, Tegafur molecule, on the surface of Graphene nanosheet (GNS) as a drug delivery system, we have performed density functional theory (DFT) and molecular dynamics (MD) methods. DFT calculations give valuable information on the structure, orientation, adsorption energy and charge transfer of nanosheet-molecule in the equilibrium GNS-Tegafur complexes in the gas phase as well as in the aqueous phase, i.e., water. The optimization of GNS-Tegafur geometries shows that drug molecule tends to adsorb via its six-membered aromatic ring to the hexagonal ring of Graphene nanosheet by π–π stacking interaction at the most stable physisorption configuration. Furthermore, the calculated solvation energy (Esol) represented by a polarizable continuum model show the significant increase in the solubility of GNS after drug adsorption on its surface in the presence of H2O solvent which leading to the possible applications of GNS in the drug delivery systems. MD simulation is also used to determine the effect of drug concentrations on dynamic properties of Tegafur adsorption on the GNS surfaces in the solution phase. Based on the obtained MD results, it is found that by increasing drug concentration, the van der Waals (vdW) interaction energy becomes more negative and the stabilities of the simulated complexes increase.  相似文献   
95.
    
In this study, different types of graphene were synthesized to investigate hydrogen adsorption capacity at different pressures (0–34 bar) at room temperature (298 K). Graphene and nanoporous graphene were prepared by Chemical Vapor Deposition (CVD) method, using methane as a carbon source at a temperature of 900 °C over copper plates and nickel oxide nanocatalyst. The nickel oxide nanocatalyst was prepared by sol–gel method, whereas graphene oxide was prepared through modified Hummer's method. The products were characterized by X‐ray diffraction, field emission‐scanning electron microscopy, energy dispersive spectroscopy, transmission electron microscopy, Fourier transform infrared spectroscopy, Brunauer–Emmett–Teller and Raman spectroscopy. The adsorption of hydrogen was done by volumetric method. High adsorption capacity was achieved in nanoporous graphene because of its high pore volume (2.11 cm3/g) and large specific surface area (850 m2/g). Hydrogen adsorption values for nanoporous graphene, graphene and graphene oxide were determined as 2.56, 1.70 and 0.74 wt%, respectively. In addition, the hydrogen adsorption of graphene nanostructures fitted nicely to the selected two‐parameter and three‐parameter adsorption isotherm models. The adsorption isotherm model coefficients have been found for a 0–34 bar pressure range. The parameter values for all adsorbents showed proper conformity to the model and experimental data. Copyright © 2016 John Wiley & Sons, Ltd.  相似文献   
96.
    
It is known that scalar-tensor gravity models can be studied in Einstein and Jordan frames. In this paper, a model of scalar-tensor gravity in Einstein's frame is considered to calculate the Lifshitz-like black hole solutions with different horizon topologies. Thermodynamic properties and first order van der Waals-like phase transition are studied, and it is found that the Lifshitz parameter affects the phase structure. In addition, thermal stability is investigated by using the behavior of heat capacity and various methods of geometrical thermodynamics.  相似文献   
97.
    
Nanofibrous scaffolds have attracted much attention in bladder reconstruction approaches due to their excellent mechanical properties. In addition, their biological properties can be improved by combination with biological materials. Taking into account the advantages of nanofibrous scaffolds and decellularized extracellular matrix (dECM) in tissue engineering, scaffolds of poly‑L‑lactic acid (PLLA) coated with decellularized human amnion membrane (hAM) or sheep bladder (SB)-derived ECM proteins are developed (amECM-coated PLLA and sbECM-coated PLLA, respectively). The bladder regenerative potential of modified electrospun PLLA scaffolds is investigated in rabbits. The presence of ECM proteins is confirmed on the nanofibers’ surface. Coating the surface of the PLLA nanofibers improves cell adhesion and proliferation. Histological and immunohistochemical evaluations show that rabbits subjected to cystoplasty with a multilayered PLLA scaffold show de novo formation and maturation of the multilayered urothelial layer. However, smooth muscle bundles (myosin heavy chain [MHC] and α-smooth muscle actin [α-SMA] positive) are detected only in ECM-coated PLLA groups. All groups show no evidence of a diverticulumor fistula in the urinary bladder. These results suggest that the biofunctionalization of electrospun PLLA nanofibers with ECM proteins can be a promising option for bladder tissue engineering. Furthermore, hAM can also replace animal-sourced ECM proteins in bladder tissue regeneration approaches.  相似文献   
98.
Magnetic nanofluids, ferrofluids, are a special category of smart nanomaterials, consisting of stable dispersion of magnetic nanoparticles in different fluids. In this study, magnetic nanoparticles of hematite, α-Fe2O3, were prepared by solvothermal method using Fe(NO3)3 as a starting material. The nanoparticles were characterized by X-ray diffraction (XRD) and transmission electronic microscope (TEM).To the best of our knowledge, this is the first research on the rheological properties of nanofluids of α-Fe2O3 nanoparticles and glycerol. The experimental results showed that the viscosity of α-Fe2O3-glycerol nanofluids increases with increasing the particle volume fraction and decreases with increasing temperature. Our results clearly showed that the α-Fe2O3-glycerol nanofluids are non-Newtonian shear-thinning and their shear viscosity depends strongly on temperature. The experimental data were compared with some theoretical models. The measured values of the effective viscosity of nanofluids are underestimated by the theoretical models.  相似文献   
99.
The electromagnetic wave scattering from a metallic two-walled carbon nanotube is studied. The system is assumed to be illuminated by either a transverse magnetic or a transverse electric wave. Boundary-value method is used to evaluate the scattering characteristics of the system. Electronic excitations of each wall of nanotube are modeled as an infinitesimally thin cylindrical layer of the free-electron gas described previously by means of the linearized fluid theory. The computed results include the evaluation of the normalized scattering width of both transverse magnetic and transverse electric uniform plane wave by system at normal incidences.  相似文献   
100.
Using survey data, public awareness of and attitudes toward nanotechnology are examined in Iran (N = 759). Iran is a developing country with a national nanotechnology action plan for a ten year period starting from 2003 and has been active in the field of research and development of nanotechnology meanwhile. First, the results show that majority of people are still not familiar with nanotechnology and perceived risks posed by this technology are not considered to be a lot and most people feel its benefits outweigh the risks. The emotions toward this technology are of a hopeful and positive nature and this technology is looked upon favorably in Iran. In particular, our results reveals that although the level of trust is high specially in scientists to communicate the risks with the public, there are a great number who just have some trust not quite a lot of it. Knowing that it is a hard and time-consuming effort to manage a nation’s view on nanotechnology, extensive research as well as collaboration with other countries is needed to effectively communicate the risks in time.  相似文献   
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