全文获取类型
收费全文 | 2527篇 |
免费 | 135篇 |
国内免费 | 7篇 |
专业分类
化学 | 2111篇 |
晶体学 | 18篇 |
力学 | 64篇 |
数学 | 110篇 |
物理学 | 366篇 |
出版年
2023年 | 13篇 |
2022年 | 49篇 |
2021年 | 53篇 |
2020年 | 53篇 |
2019年 | 61篇 |
2018年 | 41篇 |
2017年 | 37篇 |
2016年 | 100篇 |
2015年 | 74篇 |
2014年 | 113篇 |
2013年 | 190篇 |
2012年 | 227篇 |
2011年 | 266篇 |
2010年 | 154篇 |
2009年 | 107篇 |
2008年 | 178篇 |
2007年 | 163篇 |
2006年 | 148篇 |
2005年 | 139篇 |
2004年 | 109篇 |
2003年 | 101篇 |
2002年 | 112篇 |
2001年 | 36篇 |
2000年 | 33篇 |
1999年 | 23篇 |
1998年 | 23篇 |
1997年 | 16篇 |
1996年 | 7篇 |
1995年 | 7篇 |
1994年 | 5篇 |
1993年 | 8篇 |
1992年 | 2篇 |
1991年 | 1篇 |
1990年 | 3篇 |
1989年 | 4篇 |
1988年 | 2篇 |
1987年 | 2篇 |
1986年 | 1篇 |
1985年 | 1篇 |
1984年 | 2篇 |
1979年 | 2篇 |
1978年 | 1篇 |
1973年 | 1篇 |
1967年 | 1篇 |
排序方式: 共有2669条查询结果,搜索用时 15 毫秒
81.
Mubashir Hassan Balasaheb D. Vanjare Kyou-Yeong Sim Hussain Raza Ki Hwan Lee Saba Shahzadi Andrzej Kloczkowski 《Molecules (Basel, Switzerland)》2022,27(5)
A series of nine novel 1,2,4-triazole based compounds were synthesized through a multistep reaction pathway and their structures were scrutinized by using spectral methods such as FTIR, LC-MS, 1H NMR, and 13C NMR. The synthesized derivatives were screened for inhibitory activity against the mushroom tyrosinase and we found that all the synthesized compounds demonstrated decent inhibitory activity against tyrosinase. However, among the series of compounds, N-(4-fluorophenyl)-2-(5-(2-fluorophenyl)-4-(4-fluorophenyl)-4H-1,2,4-triazol-3-ylthio) acetamide exhibited more prominent activity when accompanied with the standard drug kojic acid. Furthermore, the molecular docking studies identified the interaction profile of all synthesized derivatives at the active site of tyrosinase. Based on these results, N-(4-fluorophenyl)-2-(5-(2-fluorophenyl)-4-(4-fluorophenyl)-4H-1,2,4-triazol-3-ylthio) acetamide could be used as a novel scaffold to design some new drugs against melanogenesis. 相似文献
82.
We propose the remote multiplexing of holograms with random patterns from a multimode fiber bundle used as the reference beams. The random pattern reference beam is characterized by the superposition and concatenation of propagation modes of multimode fiber and free space. For angle, shift, and wavelength remote multiplexing we compare two methods of laser coupling to the fiber bundle, i.e., direct coupling and lens coupling. A theoretical discussion that uses mode orthogonality is provided to describe multiplexing characteristics, and the theory is verified by experimental results. These remote-multiplexing methods can be applied to general multimode waveguide arrays for construction of compact and integrated optical systems in which multiplexing can be controlled remotely. 相似文献
83.
Takaaki Kakitsuka Shinji Matsuo Seok–Hwan Jeong Toru Segawa Hiroshi Okamoto Yoshihiro Kawaguchi Yasuhiro Kondo Yuzo Yoshikuni Hiroyuki Suzuki 《Optical and Quantum Electronics》2006,38(12-14):1053-1060
We theoretically investigated a digitally tunable laser with a chirped ladder filter and a ring resonator to obtain a wide wavelength tuning range covering the whole C- or L- band. The clear relation between the tuning range and laser structure, especially the ladder filter, is described analytically. The introduction of a chirped structure into a ladder filter is effective in achieving both wide tunability and a stable lasing mode. A numerical simulation based on multimode rate equations shows that a tuning range of over 40 nm and a mode suppression ratio over 40 dB can be achieved by introducing a chirped ladder filter. 相似文献
84.
Jung A. Jung Young Baek Kim Young A. Kim Seung Bum Ryu Veronica Kim 《Journal of nanoparticle research》2011,13(6):2361-2374
Functional spherical solid and hollow particles of polysilsesquioxanes (PSQs) containing amine, thiol, and vinyl groups were
prepared by polymerizing organotrialkoxysilanes (OTASs) containing corresponding chemical groups. Fluorescent PSQ particles
were prepared by physically entrapping Rhodamine 6G, Coumarin 7, and Fluoresceine sodium salts. The intensity of fluorescent
light increased initially with increasing amount of entrapped fluorophores and then leveled off or decreased slightly after
reaching a maximum value. PSQ particles containing gold nanoparticles (GNPs), both inside and on the surface, were prepared
by the in situ reduction of gold ions by the PSQ particles. When the reduction reaction was carried out for extended periods
of time, the GNP that had formed inside the poly(3-mercaptopropyl)silsesquioxane (PMPSQ) and polyvinylsilsesequioxane (PVSQ)
particles underwent interesting morphological changes. PSQ particles containing amine and thiol groups fixed the GNPs on the
surface, which could be utilized further in binding amine-modified oligo-DNA strands. The aggregation of PSQ/GNP particles
combined with complementary oligo-DNA strands was examined to demonstrate that these particles could be applied to DNA assays
and isolation. The particles were characterized by scanning electron microscopy, transmission electron microscopy, solid state
nuclear magnetic resonance spectroscopy, ultraviolet/visible spectroscopy, and fluorescence microscopy. 相似文献
85.
We have synthesized cone-like GeO2 structures via thermal heating of Ge powders. We have investigated the effects of substrate temperature on the sample morphology, revealing that cone-shaped structures are preferentially obtained at higher temperature. The cone-shaped structures, which gradually become thinner to form a sharp tip, appear to be a single-crystalline, hexagonal structure of GeO2. Room-temperature photoluminescence measurement revealed two emission peaks, at about 2.78 and 3.04 eV. 相似文献
86.
Seung U. Lee Mun Heum Park Jin Won Kim Hyeun Kyung Jo Won-Jeong Kim 《Applied Surface Science》2007,254(5):1493-1497
Ferroelectric BiFeO3 thin films with Nd-Cr (or Sm-Cr) co-substitution (denoted by BNdFCr and BSmFCr, respectively) were deposited on the Pt(2 0 0)/TiO2/SiO2/Si(1 0 0) substrates by a chemical solution deposition method. X-ray diffraction patterns revealed the formation of BNdFCr and BSmFCr thin films without any secondary phases. The co-substituted BNdFCr (or BSmFCr) thin films, which were annealed at 550 °C for 30 min in N2 atmosphere, exhibited enhanced electrical properties compared to BFO thin films with the remanent polarization (2Pr) and coercive electric field (2Ec) of 196, 188 μC/cm2 and 600, 570 kV/cm with the electric field of 800 kV/cm, respectively. The leakage current densities of BNdFCr and BSmFCr thin films measured at room temperature were approximately three orders of magnitude lower than that of BFO thin film, and the leakage current at room temperature of the thin films exhibited three distinctive conduction behaviors. Furthermore, the values of pulse polarizations [i.e., +(P*-P^) or −(P*-P^)] of BNdFCr and BSmFCr thin films were reasonably unchanged up to 1.4 × 1010 switching cycles. 相似文献
87.
Kim Gun Gyun Lee Jun Young Choi Pyeong Seok Vyas Chirag K. Yang Seung Dae Hur Min Gu Park Jeong Hoon 《Journal of Radioanalytical and Nuclear Chemistry》2018,316(3):1099-1106
Journal of Radioanalytical and Nuclear Chemistry - Accumulation of triphenylphosphonium (TPP) is normally observed in the mitochondria from the extracellular spaces due to the high difference in... 相似文献
88.
Santosh Kumar Sejy Lee Reju George Thomas Seung‐Jea Lee Hong‐Joon Lee In‐Kyu Park Yong Yeon Jeong Tae‐Ho Yoon Dong‐Chan Shin Jae‐Suk Lee 《Journal of polymer science. Part A, Polymer chemistry》2019,57(11):1165-1172
Self‐emulsion polymerization (SEP), a green route developed by us for the polymerization of amphiphilic monomers, does not require any emulsifier or an organic solvent except that the water‐soluble initiators such as 2,2′‐azobis[2‐(2‐imidazolin‐2‐yl)propane]dihydrochloride (VA‐044) and potassium persulfate (KPS) are only used. We report here the polymer nanoscaffolds from a number of amphiphilic monomers, which can be used for in situ encapsulation of a variety of nanoparticles. As a demonstration of the efficacy of these nanoscaffolds, the synthesis of a biocompatible hybrid nanoparticle (nanohybrid), prepared by encapsulating Fe3O4 magnetic nanoparticle (Fe3O4 MNPs) in poly(2‐hydroxyethyl methacrylate) in water, for MRI application is presented. The nanohybrid prepared following the SEP in the form of an emulsion does not involve the use of any stabilizing agent, crosslinker, polymeric emulsifier, or surfactant. This water‐soluble, spherical, and stable nanohybrid containing Fe3O4 MNPs of average size 10 ± 2 nm has a zeta potential value of ?41.89 mV under physiological conditions. Magnetic measurement confirmed that the nanohybrid shows typical magnetic behavior having a saturation magnetization (Ms) value of 32.3 emu/g and a transverse relaxivity (r2) value of 29.97 mM?1 s?1, which signifies that it can be used as a T2 contrast agent in MRI. © 2019 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2019 相似文献
89.
Seung Hyun Sung William B. Farnham Heidi E. Burch Yefim Brun Kai Qi Thomas H. Epps 《Journal of Polymer Science.Polymer Physics》2019,57(24):1663-1672
We demonstrate the directional alignment of perpendicular‐lamellae domains in fluorinated three‐armed star block polymer (BP) thin films using solvent vapor annealing with shear stress. The control of orientation and alignment was accomplished without any substrate surface modification. Additionally, three‐armed star poly(methyl methacrylate‐block‐styrene) [PMMA‐PS] and poly(octafluoropentyl methacrylate‐block‐styrene) were compared to their linear analogues to examine the impact of fluorine content and star architecture on self‐assembled BP feature sizes and interdomain density profiles. X‐ray reflectometry results indicated that the star BP molecular architecture increased the effective polymer segregation strength and could possibly facilitate reduced polymer domain spacings, which are useful in next‐generation nanolithographic applications. © 2019 Wiley Periodicals, Inc. J. Polym. Sci., Part B: Polym. Phys. 2019 , 57, 1663–1672 相似文献
90.
Lifen Wang Lei Liu Ji Chen Ali Mohsin Jung Hwan Yum Todd W. Hudnall Christopher W. Bielawski Tijana Rajh Xuedong Bai Shang-Peng Gao Gong Gu 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2020,132(36):15864-15870
Using high-resolution transmission electron microscopy and electron energy-loss spectroscopy, we show that beryllium oxide crystallizes in the planar hexagonal structure in a graphene liquid cell by a wet-chemistry approach. These liquid cells can feature van-der-Waals pressures up to 1 GPa, producing a miniaturized high-pressure container for the crystallization in solution. The thickness of as-received crystals is beyond the thermodynamic ultra-thin limit above which the wurtzite phase is energetically more favorable according to the theoretical prediction. The crystallization of the planar phase is ascribed to the near-free-standing condition afforded by the graphene surface. Our calculations show that the energy barrier of the phase transition is responsible for the observed thickness beyond the previously predicted limit. These findings open a new door for exploring aqueous-solution approaches of more metal-oxide semiconductors with exotic phase structures and properties in graphene-encapsulated confined cells. 相似文献